Hydration Behavior Study of Imidazolium Based ILs in Water

Bhajan Lal

doi:10.4028/www.scientific.net/AMM.625.553

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 625Hydration Behavior Study of Imidazolium Based ILs...

Hydration Behavior Study of Imidazolium Based ILs in Water

Abstract:

These ILs were chosen to provide an understanding of the influence of the cation alkyl chain length, and the anion influence on the volumetric properties. Densities for aqueous solutions of ionic liquids having 1-butyl-3-methylimidazolium as cation and chloride, bromide, iodide and acetate as anions were accurately measured at various concentrations and temperature, (288.15, 293.15, 298.15, 303.15 and 308.15) K. The results have been discussed in terms of hydrophobic hydration, hydrophobic interactions, and water structural changes in aqueous medium. The data were used in evaluating thermodynamic properties as apparent molar volumes, and apparent molar expansions. Apparent molar volumes were found to increase with temperature.

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Periodical:

Applied Mechanics and Materials (Volume 625)

Pages:

553-556

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.625.553

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Online since:

September 2014

Authors:

Bhajan Lal*

Keywords:

Apparent Molar Isobaric Expansions, Density, Ionic Liquid (IL), Molar Volume

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* - Corresponding Author

References

[1] Heintz, C. Wertz, Ionic liquids: A most promising research field in solution chemistry and thermodynamics, Pure Appl. Chem. 78 (2006) 1587–1593.

DOI: 10.1351/pac200678081587

Google Scholar

[2] R. L. Gardas, D. H. Dagade, J. A. P. Coutinho, K. J. Patil, Thermodynamic studies of ionic interactions in aqueous solutions of imidazolium-based ionic liquids [Emim][Br] and [Bmim][Cl], J. Phys. Chem. 112 (2008) 3380-3389.

DOI: 10.1021/jp710351q

Google Scholar

[3] P. Bonhote, A. P. Dias, N. Papargeorgiou, K. Kalyanasundaram, M. Gratzel, Hydrophobic, highly conductive ambient-temperature molten salts, Inorg. Chem. 35 (1996) 1168–1178.

DOI: 10.1021/ic951325x

Google Scholar

[4] J. H. Davis Jr., Task specific ionic liquids, Chem. Lett. 33 (2004) 1072–1077.

DOI: 10.1246/cl.2004.1072

Google Scholar

[5] Y. Shim, M. Y. Choi, H. J. Kim, A Molecular dynamics computer simulation study of room-temperature ionic liquids. I. Equilibrium Solvation Structure and Free Energetics, J. Chem. Phys. 122 (2005) 044510–044512.

DOI: 10.1063/1.1819317

Google Scholar

[6] J. Klomfar, M. Souckova, J. Patek, Temperature dependence measurements of the density at 0. 1 MPa for 1-Alkyl-3-methylimidazolium-Based Ionic Liquids with the Trifluoromethanesulfonate and Tetrafluoroborate Anion, J. Chem. Eng. Data 55 (2010).

DOI: 10.1021/je100185e

Google Scholar

[7] A. Chandran, K. Prakash, S. Senapati, Structure and dynamics of acetate anion-based ionic liquids from molecular dynamics study, Chem. Phys. 374 (2010) 46–54.

DOI: 10.1016/j.chemphys.2010.06.011

Google Scholar

[8] F. J. Millero, in: R. A. Horne (Ed. ), Structure and Transport Process in Water and Aqueous Solutions, John Wiley, NY, 1972, p.519–564 (Chapter 13).

Google Scholar

[9] O. Redlich, D. M. Meyer, The Molal Volumes of Electrolytes, Chem. Rev. 64 (1964) 221-227.

DOI: 10.1021/cr60229a001

Google Scholar

[10] H. S. Harned, B. B. Owen, The Physical Chemistry of Electrolyte Solutions, ACS, New York, (1958).

Google Scholar