Structural and Morphological Properties of Ultrathin HfO2 Dielectrics on 4H-SiC (0001)

Article Preview

Abstract:

The material properties of HfO2 thin films were studied to evaluate their potential as a high-κ gate dielectric in 4H-SiC power metal-oxide-semiconductor field effect transistors. Stoichiometric HfO2 films were deposited on n-type 4H-SiC (0001) by atomic layer deposition (ALD) at substrate temperatures of 250-450°C. No significant interfacial layer formation was observed by in-situ X-ray photoelectron spectroscopy (XPS) and an abrupt interface was confirmed by high-resolution transmission electron microscopy (HRTEM). A temperature-dependent transition from amorphous layer-by-layer growth to crystalline three-dimensional island growth was identified by in-situ reflection high-energy electron diffraction (RHEED) and ex-situ atomic force microscopy (AFM). X-ray diffraction (XRD) confirmed the presence of monoclinic HfO2 domains in crystallized films.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volumes 527-529)

Pages:

1075-1078

Citation:

Online since:

October 2006

Export:

Price:

[1] J. Cooper, M. R. Melloch, R. Singh, A. Agarwal and J. W. Palmour: IEEE Trans. Electron Devices Vol. 49 (2002), p.658.

DOI: 10.1109/16.992876

Google Scholar

[2] M. K. Das: Mat. Sci. Forum Vols. 457-460 (2004), p.1275.

Google Scholar

[3] V. V. Afanas'ev, A. Stesmans, F. Chen, S. A. Campbell and R. Smith: Appl. Phys. Lett. Vol. 82 (2003), p.922.

Google Scholar

[4] J. Aarik, A. Aidla, H. Mandar, V. Sammelselg and T. Uustare: J. Cryst. Growth Vol. 220 (2000), p.105.

Google Scholar

[5] R. Puthenkovilakam, Y. -S. Lin, J. Choi, J. Lu, H. -O. Blom, P. Pianetta, D. Devine, M. Sendler and J. P. Chang: J. Appl. Phys. Vol. 97 (2005), p.023704.

DOI: 10.1063/1.1831543

Google Scholar

[6] H. G. Tompkins and W. A. McGahan: Spectroscopic Ellipsometry and Reflectometry (John Wiley & Sons, Inc., New York 1999).

Google Scholar

[7] J. M. M. de Nijs and A. van Silfhout: J. Opt. Soc. Am. A Vol. 5 (1988), p.773.

Google Scholar

[8] L. -S. Johansson, F. Owman, P. Martensson, C. Persson and U. Lindefelt: Phys. Rev. B Vol. 53 (1996).

Google Scholar