Abstract
The conversion luminescence of a phosphor from the ultraviolet region to the visible region can enhance the light harvesting in dye-sensitized solar cells (DSSCs), because many dyes can only absorb visible light. To explore the influence of phosphor additives on the conversion efficiency of DSSC, we introduce the nanocrystalline YAG:Eu phosphors into TiO2 photoelectrodes. The photoluminescence measurement showed that a broad solar spectrum including the ultraviolet region could be reabsorbed by the dye N-719 via conversion luminescence due to the phosphor. With the introduction of the phosphor, both the photocurrent and the photovoltage of the DSSC could be improved due to the enhanced light harvesting and the elevated energy levels of the oxides. With the optimal concentration of phosphor doping in the electrode, the cells light-to-electricity conversion efficiency could be improved by a factor of 1.14 compared to that for a cell without phosphor doping.
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References
M. Gratzel, J. Photochem. Photobiol. A 164, 3 (2004).
B. O’Regan and M. Gratzel, Nature 353, 737 (2004).
S. Chappel, S. G. Chen and A. Zaban, Langmuir 18, 3336 (2002).
I. Bedja, P. V. Kamat, X. Hua, A. G. Lappin and S. Hotchandani, Langmuir 13, 2398 (1997).
K. Keis, C. Bauer, G. Boschloo, A. Hagfeldt, K. Westermark, H. Rensmo and H. Siegbahn, J. Photochem. Photobiol. Chem. 148, 57 (2002).
S. Chappel and A. Zaban, Sol. Energy Mater. Sol. Cells 71, 141 (2002).
P. Guo and M. A. Aegerter, Thin Solid Films 351, 290 (1999).
J. Xia, N. Masaki, K. Jiang, Y. Wada and S. Yanagida, Chem. Lett. 35, 252 (2006).
M. Gratzel, Inorg. Chem. 44, 6841 (2005).
T. W. Hamann, R. A. Jensen, A. B. F. Martinson, H. V. Ryswyk and J. T. Hupp, Energ. Environ. Sci. 1, 66 (2008).
F. T. Kong, S.-Y. Dai and K. J. Wang, Adv. Opto. Elect, 75384 (2007).
T. Prakash, Electron. Mater. Lett. 8, 231 (2012).
P. Huh and S. C. Kim, Electron. Mater. Lett. 8, 131 (2012).
K. Hara, Y. Tachibana, Y. Ohga, A. Shinpo, S. Suga, K. Sayama, H. Sugihara and H. Arakawa, Sol. Energy Mater. Sol. Cells 77, 89 (2003).
H. Matsui, K. Okada and T. Kawashima, et al., J. Photochem. Photobiol. A-Chem. 164, 129 (2004).
S. S. Kim, Y. C. Nah, Y. Y. Noh, J. Jo and D. Y. Kim, Electrochim. Acta 51, 3814 (2006).
P. Oelhafen and A. Schuler, Sol. Energy 79, 110 (2005).
G. Yang, J. Zhang, P. Wang, Q. Sun, J. Zheng and Y. Zhu, Curr. Appl. Phys. 11, 376 (2011).
Y. Wang, E. Chen, H. Lai, B. Lu, Z. Hu, X. Qin, W. Shi and G. Du, Ceram. Int. 39, 5407 (2013).
M. Gratzel, Nature 414, 338 (2001).
H. Shen, X. Li, J. Li, W. Wang and H. Lin, Electrochim. Acta 97, 160 (2013).
M. Gratzel, Acc. Chem. Res. 42, 1788 (2009).
J. Su, Q. L. Zhang, S. F. Shao, W. P. Liu, S. M. Wan and S. T. Yin, J. Alloy. Compd. 470, 306 (2009).
I. Yu, Mater. Res. Bull. 41, 1403 (2006).
S. H. Shin, J. H. kang, D. Y. Jeon and D. S. Zang, J. Solid State Chem. 178, 2205 (2005).
J. G. Li, X. D. Li, X. D. Sun and T. Ishigaki, J. Phys. Chem. C 112, 11707 (2008).
Q. Su, J. Lin and B. Li, J. Alloys Compd. 225, 120 (1995).
C. K. Jogensen and B. R. Judd, Mol. Phys. 8, 281 (1964).
R. D. Peacock, Struct. Bonding 22, 83 (1975).
C. C. Yang, H. Q. Zhang and Y. R. Zheng, Curr. Appl. Phys. 11, S147 (2011).
F. Fabregat-Santiago, J. Bisquert, E. Palomares, L. Otero, D. Kuang, S. M. Zakeeruddin and M. Grätzel, J. Phys. Chem. C 111, 6550 (2007).
R. Kern, R. Sastrawan, J. Ferber, R. Stangl and J. Luther, Electrochim. Acta 47, 4213 (2002).
S. Gagliardi, L. Giorgi, R. Giorgi, N. Lisi, Th. D. Makris, E. Salernitano and A. Rufoloni, Superlattices and Microstructures 46, 205 (2009).
K. Ko, Y. Lee and Y. Jung, J. Colloid Interface Sci. 283, 482 (2005).
C. S. Chou, M. G. Guo, K. H. Liu and Y. S. Chen, Appl. Energy 92, 224 (2012).
K. Guo, M. Li, X. Fang, M. Luoshan, L. Bai and X. Zhao, J. Power Sources 249, 72 (2014)
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Shin, S.G., Kim, K.H., Bark, C.W. et al. Preparation of a Phosphor/TiO2 nanoparticle composite layer for applications in dye-sensitized solar cells. Journal of the Korean Physical Society 65, 387–391 (2014). https://doi.org/10.3938/jkps.65.387
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DOI: https://doi.org/10.3938/jkps.65.387