A Novel Paper-Based Reagentless Dual Functional Soil Test to Instantly Detect Phosphate Infield
Abstract
:1. Introduction
2. Materials and Methods
2.1. Extraction–Reaction Reagent, P Standards, and Interfering Solutions
2.2. Impregnated Filters Preparation
2.3. Physical Characterization of ERR IFP
2.4. Recovery of Reagents from ERR IFP
2.5. Stability of ERR IFP
2.6. Soil P Extraction
2.7. Soil Sample Collection and Laboratory Analysis
2.8. Soil P Data Mapping
2.9. CV Electrochemical P Detection
2.10. Data Analysis
3. Results and Discussion
3.1. Chemical and Physical Characterization of Extraction–Reaction Reagent Impregnated Filter Paper
3.2. CV Response Characteristics
3.3. Silicate Interference
3.4. Soil Samples Analysis
3.5. Soil P Test Interpretation
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Filter Name | Filter Material | Uses | Thickness (µm) | Pore Size (µm) | Basis Weight (g/m2) | Recovery (%) ± |
---|---|---|---|---|---|---|
Whatman 41 | Cellulose | Fast quantitative air pollution analysis as a paper tape for impregnation | 220 | 20–25 | 85 | 59.47 ± 0.24 a |
Whatman 42 | Cellulose | Slow quantitative analysis for filtering extremely small particles | 200 | 2.5 | 100 | 53.13 ± 0.25 b |
Whatman 934-AH | Binder-free glass microfiber | Fast and high loading capacity filtration | 435 | 1.5 | 64 | 51.17 ± 0.69 c |
Millipore AP2512450 | Hydrophilic glass fiber with binder resin | Prefiltration for heavily contaminated liquids | 1200 | 2 | NA | 0.21 ± 0.02 d |
Recovery (%) ± | ||
---|---|---|
Day | ERR w/o AA + NA IFP | ERR IFP |
1 | 60.62 ± 0.80 a | 59.44 ± 1.26 a |
2 | 59.55 ± 1.20 a | 60.43 ± 0.78 a |
3 | 57.03 ± 2.01 a | 58.62 ± 0.56 a |
6 | 57.19 ± 1.34 a | 58.71 ± 0.07 a |
Extraction Time (min) | Predicted P Concentration (mg·L−1) | Recovery (%) |
---|---|---|
1 | 1.75 ± 0.15 | 42.02 ± 3.68 b |
2 | 4.35 ± 0.23 | 104.31 ± 4.75 a |
5 | 4.39 ± 0.29 | 105.23 ± 6.15 a |
10 | 4.43 ± 0.18 | 106.22 ± 3.79 a |
Method | Extracting Solution | Solution pH | Extraction Time | Soil-to-Solution Ratio | Method of Detection | Ref. |
---|---|---|---|---|---|---|
HCl | 0.5 M HCl | <1 | 2 h | 1:10 | ICP | [13,38] |
LiCl | 0.4 M LiCl | unbuffered | 2 × 2 h | 1:1.8–1:4.0 | ICP | [13] |
CAE * | Distilled water | unbuffered | 16 h | 1:40 | photometer | [13] |
CAL * | 0.05 M C6H10CaO6, 0.05 M (CH3COO)2Ca | 4.0 | 2 h | 1:20 | photometer | [13] |
CaCl2 | 0.01 M CaCl2 | unbuffered | 2 h | 1:10 | photometer | [13,39] |
H2O | Distilled water | unbuffered | 12 h | 1:0.3–1:1.2 | photometer | [13] |
FeO IFP * | 0.01 M CaCl2 | unbuffered | 16 h | 1:40 | photometer | [13,40] |
Olsen | 0.5 M NaHCO3 | 8.5 | 30 min | 1:20 | Photometer/ICP | [13,19] |
Mehlich-3 | 0.015 M NH4F, 0.013 M HNO3, 0.001 M EDTA, 0.25 M NH4NO3 0.3 M CH3COOH | 2.5 | 5 min | 1:10 | Photometer/ICP | [13,18] |
ERR IFP * | DI water | Unbuffered | 2 min | 1:10 | Cyclic voltammetry | This work |
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Zeitoun, R.; Adamchuk, V.; Biswas, A. A Novel Paper-Based Reagentless Dual Functional Soil Test to Instantly Detect Phosphate Infield. Sensors 2022, 22, 8803. https://doi.org/10.3390/s22228803
Zeitoun R, Adamchuk V, Biswas A. A Novel Paper-Based Reagentless Dual Functional Soil Test to Instantly Detect Phosphate Infield. Sensors. 2022; 22(22):8803. https://doi.org/10.3390/s22228803
Chicago/Turabian StyleZeitoun, Reem, Viacheslav Adamchuk, and Asim Biswas. 2022. "A Novel Paper-Based Reagentless Dual Functional Soil Test to Instantly Detect Phosphate Infield" Sensors 22, no. 22: 8803. https://doi.org/10.3390/s22228803