Role of Organically-Modified Zn-Ti Layered Double Hydroxides in Poly(Butylene Succinate-Co-Adipate) Composites: Enhanced Material Properties and Photodegradation Protection
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Synthesis and Modification of m-LDH
2.3. PBSA/LDH Composites Preparation
2.4. Artificial Photodegradation Test
2.5. Characterization
3. Results and Discussion
3.1. Characterization of m-LDH
3.2. Characterization of PBSA and Its Composites
3.3. Characterization of PBSA/m-LDH Composites after Irradiation
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Appendix A
Sample Name | 10 wt% Loss Temperature (°C) | Char Yield at 600 °C (wt%) |
---|---|---|
Zn-Ti LDH | 269.2 | 75.0 |
m-LDH | 292.0 | 46.9 |
stearic acid | 218.7 | 0.5 |
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Sample Name | ′ (Gpa) | ′ (Gpa) | Tc (°C) | Tm (°C) | ΔHf (J/g) | Xc (%) |
---|---|---|---|---|---|---|
PBSA | 4.04 | 0.43 | 44.3 | 87.1 | 32.1 | 27.4 |
PBSA/m-LDH-1 | 4.42 | 0.46 | 52.9 | 74.0/87.4 | 36.3 | 31 |
PBSA/m-LDH-3 | 5.19 | 0.5 | 50.4 | 74.3/86.9 | 34.6 | 29.5 |
PBSA/m-LDH-5 | 6.16 | 0.63 | 48.8 | 73.3/87.1 | 33.5 | 28.6 |
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Wang, J.-M.; Wang, H.; Chen, E.-C.; Chen, Y.-J.; Wu, T.-M. Role of Organically-Modified Zn-Ti Layered Double Hydroxides in Poly(Butylene Succinate-Co-Adipate) Composites: Enhanced Material Properties and Photodegradation Protection. Polymers 2021, 13, 2181. https://doi.org/10.3390/polym13132181
Wang J-M, Wang H, Chen E-C, Chen Y-J, Wu T-M. Role of Organically-Modified Zn-Ti Layered Double Hydroxides in Poly(Butylene Succinate-Co-Adipate) Composites: Enhanced Material Properties and Photodegradation Protection. Polymers. 2021; 13(13):2181. https://doi.org/10.3390/polym13132181
Chicago/Turabian StyleWang, Jie-Mao, Hao Wang, Erh-Chiang Chen, Yun-Ju Chen, and Tzong-Ming Wu. 2021. "Role of Organically-Modified Zn-Ti Layered Double Hydroxides in Poly(Butylene Succinate-Co-Adipate) Composites: Enhanced Material Properties and Photodegradation Protection" Polymers 13, no. 13: 2181. https://doi.org/10.3390/polym13132181