Adsorption of Rhodamine B from Simulated Waste Water onto Kaolin-Bentonite Composites
Abstract
:1. Introduction
2. Materials and Methods
2.1. Preparation of Adsorbents
2.2. Characterization of Adsorbents
2.3. Batch Adsorption Test
3. Results and Discussion
3.1. Characterization of Adsorbents
3.2. Effect of Adsorption Time on Removal of Rhodamine B by Different Adsorbents
3.3. Effect of Initial Concentration of Rhodamine B Solution on Removal of Rhodamine B by Different Adsorbents
3.4. Effect of Temperature on Removal of Rhodamine B by Different Adsorbents
3.5. Effects of Adsorbent Dosage and pH on Removal of Rhodamine B by Kaolin-Organic Bentonite
3.6. Adsorption Isotherm
3.7. Adsorption Kinetics
3.8. Thermodynamic Study
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Adsorbent | Rhodamine B Solution Concentration (mg/L) | Adsorption Time (min) | Adsorption Temperature (℃) | pH Value | Adsorbent Dosage (g) |
---|---|---|---|---|---|
kaolin, kaolin-sodium bentonite, kaolin-organic bentonite | 50, 100, 150, 200, 250, 300, 350, 400 | 360 | 25 | 9.1 | 0.25 |
kaolin, kaolin-sodium bentonite, kaolin-organic bentonite | 50, 100, 150, 200 | 10, 20, 45, 90, 180, 360 | 25 | 9.1 | 0.25 |
kaolin, kaolin-sodium bentonite, kaolin-organic bentonite | 50 | 360 | 20, 30, 40, 50, 60 | 9.1 | 0.25 |
kaolin-organic bentonite | 50 | 360 | 25 | 2.0, 2.6, 3.0, 4.7, 7.2, 9.1, 10.2, 11.8 | 0.25 |
kaolin-organic bentonite | 50 | 360 | 25 | 9.1 | 0.25, 0.5, 1.0, 1.5, 2.0, 2.5, 3.0 |
Adsorption Isotherm Equation | Parameter | Kaolin | Kaolin-Sodium Bentonite | Kaolin-Organic Bentonite |
---|---|---|---|---|
Langmuir | qm (mg/g) | 8.23477 | 11.96847 | 13.31723 |
KL (L/mg) | 0.01522 | 0.03542 | 0.05512 | |
R2 | 0.88 | 0.97452 | 0.945 | |
Freundlich | KF (L/g) | 0.60793 | 1.30457 | 1.77013 |
n | 2.26767 | 2.32162 | 2.35557 | |
R2 | 0.77507 | 0.87509 | 0.97686 |
Adsorbent Concentration (mg/L) | 50 | |||
---|---|---|---|---|
Adsorbent Type | Kaolin | Kaolin-Sodium Bentonite | Kaolin-Organic Bentonite | |
Pseudo-first order kinetic equation | qe (mg/g) | 5.1152 | 6.57354 | 6.90133 |
K1 | 0.26364 | 0.15821 | 0.30208 | |
R2 | 0.83987 | 0.84537 | 0.80484 | |
Pseudo-second order kinetic equation | qe (mg/g) | 5.1649 | 7.02359 | 6.82869 |
K2 | 0.20192 | 0.04874 | 0.22165 | |
R2 | 0.99994 | 0.98391 | 0.99967 |
Temperature/(℃) | 20 | 30 | 40 | 50 | 60 | |
---|---|---|---|---|---|---|
Kaolin | ΔH0/(kJ mol−1) | 5.780 | ||||
ΔS0/(kJ mol−1K−1) | 0.053 | |||||
ΔG0/(kJ mol−1) | −9.700 | −10.340 | −11.090 | −11.450 | −11.810 | |
R2 | 0.970 | |||||
Kaolin-sodium bentonite | ΔH0/(kJ mol−1) | 4.990 | ||||
ΔS0/(kJ mol−1K−1) | 0.053 | |||||
ΔG0/(kJ mol−1) | −10.680 | −11.400 | −12.040 | −12.460 | −12.840 | |
R2 | 0.872 | |||||
Kaolin-organic bentonite | ΔH0/(kJ mol−1) | 4.060 | ||||
ΔS0/(kJ mol−1K−1) | 0.051 | |||||
ΔG0/(kJ mol−1) | −10.980 | −11.550 | −12.210 | −12.620 | −13.030 | |
R2 | 0.906 |
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He, H.; Chai, K.; Wu, T.; Qiu, Z.; Wang, S.; Hong, J. Adsorption of Rhodamine B from Simulated Waste Water onto Kaolin-Bentonite Composites. Materials 2022, 15, 4058. https://doi.org/10.3390/ma15124058
He H, Chai K, Wu T, Qiu Z, Wang S, Hong J. Adsorption of Rhodamine B from Simulated Waste Water onto Kaolin-Bentonite Composites. Materials. 2022; 15(12):4058. https://doi.org/10.3390/ma15124058
Chicago/Turabian StyleHe, Haijie, Kuan Chai, Tao Wu, Zhanhong Qiu, Shifang Wang, and Jie Hong. 2022. "Adsorption of Rhodamine B from Simulated Waste Water onto Kaolin-Bentonite Composites" Materials 15, no. 12: 4058. https://doi.org/10.3390/ma15124058