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Article

Enhanced Corrosion Resistance of Layered Double Hydroxide Films on Mg Alloy: The Key Role of Cationic Surfactant

by
Qiuxiang Yang
1,
Mohammad Tabish
1,
Jingbao Wang
1 and
Jingmao Zhao
1,2,*
1
School of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
2
Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing 100029, China
*
Author to whom correspondence should be addressed.
Materials 2022, 15(6), 2028; https://doi.org/10.3390/ma15062028
Submission received: 27 January 2022 / Revised: 22 February 2022 / Accepted: 28 February 2022 / Published: 9 March 2022
Browse Figures
Versions Notes

Abstract

:
In this study, dense anticorrosion magnesium–aluminum layered double hydroxide (MgAl-LDH) films were prepared for the first time by introducing a cationic surfactant tetradecyltrimethyl ammonium bromide (TTAB) in the process of in situ hydrothermal synthesis of Mg-Al LDH films on an AZ31 magnesium alloy. Results of XRD, FTIR, and SEM confirmed that TTAB forms the MgAl-LDH-TTAB, although TTAB cannot enter into LDH layers, and MgAl-LDH-TTAB powders are much smaller and more homogenous than MgAl-CO32−-LDH powders. Results of SEM, EDS, mapping, and XPS confirmed that TTAB forms the MgAl-LDH-TTAB films and endows LDH films with denser structure, which provides films with better shielding efficiency. Results of potentiodynamic polarization curves (PDP) and electrochemical impedance spectroscopy (EIS) confirmed that MgAl-LDH-TTABx g films have better corrosion resistance than an MgAl-CO32−-LDH film. The corrosion current density (icorr) of the MgAl-LDH-TTAB0.35 g film in 3.5 wt.% NaCl solution was reduced to 1.09 × 10−8 A.cm−2 and the |Z|f = 0.05 Hz value was increased to 4.48 × 105 Ω·cm2. Moreover, the increasing concentration of TTAB in MgAl-LDH-TTABx g (x = 0.025, 0.05, 0.1, 0.2 and 0.35) provided denser outer layer LDH films and thereby increased the corrosion resistance of the AZ31 Mg alloy. Additionally, the |Z|f = 0.05 Hz values of the MgAl-LDH-TTAB0.35 g film still remained at 105 Ω·cm2 after being immersed in 3.5 wt.% NaCl solution for 168 h, implying the good long-term corrosion resistance of MgAl-LDH-TTABx g films. Therefore, introducing cationic surfactant in the process of in situ hydrothermal synthesis can be seen as a novel approach to creating efficient anticorrosion LDH films for Mg alloys.

1. Introduction

Magnesium and its alloys have gained a lot of interest over the years owing to their many advantages, such as high specific strength, high thermal conductivity, excellent machinability, and ease of recycling. They are, nevertheless, extremely caustic, particularly in corrosive environments containing Cl−. Because of their low corrosion resistance, they are severely limited in their uses in aerospace, biomedical engineering, automotive, and a variety of other areas. Several anticorrosion approaches for Mg alloys have been established so far, including organic coating [1,2], chemical conversion coating [3,4], surface chemical modification [5,6], micro-arc oxidation (MAO) [7,8], as well as an inhibitor [9,10]. In situ generated layered double hydroxide (LDH) coatings on Mg alloys have recently piqued the interest of many researchers owing to its outstanding anticorrosion performance and strong adherence to the substrate [11]. LDH films have high corrosion resistance due to three factors: (i) the LDH film acts as a strong physical barrier to corrosive media such as water molecules and aggressive anions, (ii) LDH can capture aggressive anions, such as Cl−, due to their unique interlayer anion exchangeability, and (iii) LDH with corrosion inhibitor intercalation can release an inhibitor [12,13,14,15].
In the past years, a variety of treatment techniques have been used to improve the corrosion resistance of the LDH film. Several researchers developed LDH films with corrosion inhibitor intercalation to enhance their corrosion resistance, such as aspartic acid [12], 8-hydroxyquinoline [16], and phenylphosphonic acid [17]. Some researchers also utilized low surface energy substances, such as aliphatic carboxylic acid [13] and fluoroalkyl silane [18], to obtain superhydrophobic LDH films with improved corrosion resistance. Additionally, the formation of dense LDH films on the Mg alloy surface is another effective method for obtaining LDH films with a high corrosion resistance. Li [19] used a thiophene derivative to produce highly corrosion-resistant LDH coatings with no big holes or fractures on the surface of a magnesium alloy. Ahsan Iqbal [20] proposed that more compact and dense LDH films can be prepared at 100 °C for an 18 h reaction time with improved corrosion resistance. Zhou [21] created a ZnAl-LDHs film with a finer and denser structure on the surface of Al alloys by adding lanthanum ions, and the denser nanosheets of ZnLaAl-LDH contributed to the improvement of anticorrosion performance.
In order to synthesize nanostructured LDH, different surfactants, including both anionic surfactant (sodium dodecyl sulfate, SDS) [22,23] and cationic surfactant (cetyltrimethylammonium bromide, CTAB) [22,24], have been used as soft and self-assembled templates to control the size and shape of nanoparticles. The MgAl-LDH-CTAB platelet has been found to be much smaller than the MgAl-CO3-LDH platelet [22]. Many studies have shown that surfactants may significantly enhance the characteristics of electrodeposited nanocomposite coatings on metal surfaces by contributing to the formation of a homogeneous and dense coating [25,26]. However, no studies have been reported to create in situ synthesis anticorrosion LDH films on metal surfaces with a surfactant. Therefore, it is essential to explore the effect of surfactants on the synthesis of LDH corrosion-resistant films. It is also important to explore the effect of surfactants on the synthesis of LDH corrosion-resistant coatings. Anionic surfactants may penetrate an LDH layer and modify the LDH laminate spacing through an ion exchange [22], but cationic surfactants will not have such effects [22]; only the cationic surfactant was used in this study. In addition, according to previous studies, the metal ions can release from the Mg substrate in hydrothermal synthesis and participate in the in situ formation of LDH film, which led to the high adhesion between the LDH film and the substrate [27,28].
In this study, high corrosion resistant MgAl-LDH films were produced on AZ31 Mg alloys via an in situ hydrothermal method with the cationic surfactant tetradecyltrimethyl bromide (TTAB, CH3(CH2)13N(Br)(CH3)3) to further enhance the protection ability of LDH films and provide a better corrosion resistance to the Mg substrate against an aggressive electrolyte. Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD) examined the impact of TTAB on the microstructure and chemistry of LDH particles. The findings have shown the success of the synthesis of MgAl-LDH-TTAB, and of the smaller and more homogeneous particles of MgAl-CO32−-LDH particles. LDH films were investigated using X-ray photoelectron spectroscopy (XPS) and SEM to evaluate the chemical compositions and surface morphology. The findings indicated that the films of MgAl -LDH-TTABx g are more consistent and compact than the MgAl-CO32−-LDH film. The corrosion resistance of LDH films was studied by electrochemical methods (PDP and EIS). A change in coating morphology is primarily attributable to the excellent resistance to corrosion in MgAl-LDH-TTABxg films. The corrosion current density of the Mg alloy was decreased to 1 × 10−8A·cm−2. Therefore, utilization of cationic surfactant to synthesis the LDH films improves corrosion efficiency.

2. Materials and Methods

2.1. Materials and Chemicals

AZ31 Mg alloy (3 wt.% Al, 1 wt.% Zn, 0.4 wt.% Mn, balance Mg) sheets with a dimension of 25 × 25 × 2 mm were chosen in this study. All chemicals, including sodium carbonate, magnesium nitrate, aluminum nitrate, tetradecyltrimethylammonium bromide (TTAB), sodium chloride, and sodium hydroxide, were obtained from Sinopharm Chemical Reagent Co. Ltd., Beijing, China. with analytical grade. Deionized water (DI) was utilized to prepare all of the solutions.

2.2. In Situ Fabrications of MgAl-LDH-TTABx g and MgAl-CO32−-LDH Films

According to reported methods, MgAl-LDH-TTABx g films were prepared via in situ hydrothermal synthesis with surfactant TTAB [29]. The in situ preparation refers to putting AZ31 substrate and LDH precursor solution into the autoclave (Yuze Industrial Technology Co., Ltd., Jining, China), and when they make contact, metal ions are released from the Mg substrate and participate in the formation of LDH film on the surface of the Mg alloy. As shown in Figure 1, the detailed synthesis process can be divided into the following steps. In step 1 (S1), the surface of the AZ31 plates was polished with 800, 1200, 1500, and 2000# grit SiC abrasive sheets (Kuangyu Metal Co., Ltd., Dongguan, China), cleaned in ethanol ultrasonically and dried with warm air. In step 2 (S2), solution A with a Mg2+/Al3+ molar ratio of 3.0 was obtained by dissolving 6 g magnesium nitrate and 3 g aluminum nitrate dissolved in 120 mL of DI water in a three-neck flask, and solution B was separately obtained by dissolving 0.025/0.05/0.1/0.2/0.35 g TTAB and 2 g NaOH in 80 mL DI water at 40 °C. In Step 3 (S3), the precursor solution was made by the progressive addition of solution B to solution A at 80 °C with continuous stirring, and the pH of the precursor solution was adjusted to 10.5 with NaOH solution (2 mol/L). In step 4 (S4), the combined solution was allowed to react for 30 min under continuous stirring. In step 5 (S5), the polished AZ31 plates were put into the Teflon-lined autoclave with the combined solution prepared in S4. In step 6 (S6), the autoclave was heated for the hydrothermal reaction at 126 °C for 12 h in an oven (Dute Scientific Instrument Co., Ltd., Shanghai, China) [13]. In step 7 (S7), the Teflon-lined autoclave (Yuze Industrial Technology Co., Ltd., Jining, China) was taken out from the oven and then cooled down to room temperature. In step 8 (S8), AZ31 samples were taken out from the Teflon-lined autoclave, washed with DI water and dried with warm air. Finally, AZ31 samples coated with MgAl-LDH-TTABx g films were obtained. Steps 2, 3 and 4 were carried out in the N2 environment in order to prevent carbonate ions from entering LDH interlayers. LDH powder from the LDH precipitates was acquired once the hydrothermal process was completed.
Similarly, AZ31 samples coated with MgAl-CO32−-LDH films were synthesized with the major difference in solution B (Step 2), which was obtained from NaOH and Na2CO3 (the molar ratios of [NaOH]:[Mg2++Al3+] = 1.6 and [CO32−]:[Al3+] = 2.0) dissolved in DI water. Additionally, this experiment was performed in the air instead of N2.
The acronyms and the difference of the samples obtained in this section are displayed in Table 1.

2.3. Characterization

The crystalline structure of LDH powders from the LDH precipitates after hydrothermal reaction was identified by X-ray diffraction (XRD, Ultima IV, Rigaku-6000, Tokyo, Japan) with K-beta filter Cu Kα radiation (0.15406 nm, 40 kV, 40 mA). A scanning speed of 10deg/min was applied to record the XRD patterns in the 2θ-range degree of 5–90°. FTIR (Bruker, TENSOR-27, Karlsruhe, Germany) spectra with a resolution of 4 cm−1 and a scanning range from 4000 to 600 cm−1 were acquired to observe the presence of organic functional groups. Scanning electron microscope (SEM, FEI Quanta 200 F, Den Haag, The Netherlands) operating at 30 kV was utilized to examine the morphologies of LDH powders and films. Electron dispersive spectroscopy (EDS, FEI, Den Haag, The Netherlands) coupled to the SEM facility was used to determine the elemental composition of the LDH film. X-ray photoelectron spectroscopy (XPS, Al Kα X-rays, hv = 1486.6 eV, Thermo Scientific K-Alpha, Dreieich, Germany) was used to examine the surface chemical compositions of the MgAl-CO32−-LDH and MgAl-LDH-TTAB films. All XPS data were fitted with the XPS peak 4.1 software and the background subtraction was carried out by the Tougaard background method. Binding energies were corrected based on the adventitious carbon signal at 284.8 eV in the C 1s spectrum.
The adhesion test of MgAl-LDH-TTAB film on the AZ31 substrate was conducted by a cross-cut tester (QFH-HG600, Shenzhen, China) with tempered steel rule graduated in 1 mm and a 25 mm wide semitransparent pressure-sensitive c provided by the supplier. The experiment was completed according to the experimental method described in the Annual Book of ASTM Standards in accordance with standard ASTM D3359-97 [30]. Optical microscopy (JT-1600B, Shenzhen, China) was used to observe the morphology of the film before and after tape peeling.

2.4. Electrochemical Tests

The corrosion behavior of the AZ31 samples covered with various LDH films was evaluated electrochemically with PDP and EIS. All the experiments were conducted on a three-electrode setup with a platinum counter electrode, a saturated calomel reference electrode, and a 0.786 cm2 exposed area working electrode. All electrochemical experiments were conducted at room temperature in a 3.5 wt.% NaCl solution. A steady open circuit potential (OCP) was achieved through 30 min of sample immersion before the electrochemical tests. The EIS test was performed at frequencies ranging from 100 kHz to 5 mHz with AC perturbation of 10 mV vs OCP. PDP curves were produced from scanning potential between −500 mV to +500 mV (OCP) with a scanning rate of 0.5 mV·s−1.

3. Results and Discussion

3.1. Characterization of MgAl-CO32−-LDH and MgAl-LDH-TTAB Powders by XRD, FTIR and SEM

As shown in Figure 2a, the main diffraction peaks of MgAl-CO32−-LDH powders were located at 2θ = 11.5, 23.1, 34.8, 39.2, 46.7, 60.6, and 62.1, corresponding to the (003), (006), (009), (012), (015), (018), (110), and (113) planes of a layered hydrotalcite-like material, respectively, and the (009) reflection overlaps with the (012) [31,32]. According to Figure 2a, MgAl-LDH-TTAB powders have similar XRD patterns with MgAl-CO32−-LDH powders and the main diffraction peaks were located at 2θ = 11.3, 22.6, 34.4, 39.1, 45.3, 60.3, and 61.5, corresponding to the (003), (006), (009), (012), (015), (018), (110), and (113) planes. The results suggested that MgAl-LDH-TTAB and MgAl-CO32−-LDH with hexagonal LDH crystal structure have been successfully synthesized and the cationic surfactant TTAB cannot intercalate the interlayer of the LDH or alter the interlayer spacing of LDH laminates. In the FT-IR spectra of MgAl-CO32−-LDH powders and MgAl-LDH-TTAB powders (Figure 2b), the peaks around 3430 cm−1 were associated with the –OH stretching band and the peaks around 2850 cm−1 and 2917 cm−1 were due to carbon–hydrogen (C–H) stretching [33,34,35]. The peaks at the lower wavenumber are associated with bonds between metal and oxygen [36]. Furthermore, the peak of MgAl-LDH-TTAB at 1050 cm−1 is ascribed to the C–N bond from TTAB [37,38]. The results substantiate that TTAB forms the MgAl-LDH-TTAB.
Figure 3 shows SEM images of the MgAl-CO32−-LDH and MgAl-LDH-TTAB powders with characteristic plate-like and hexagonal LDHs [17,39]. As shown in Figure 3, MgAl-LDH-TTAB powders with a mean particle size of 100–200 nm are much smaller and more homogenous than MgAl-CO32−-LDH powders with an average size of 2–4 μm. The results suggest that fine and uniform LDH can be produced by adding cationic surfactant during the process of in situ hydrothermal synthesis.

3.2. Characterizations of MgAl-CO32−-LDH and MgAl-LDH-TTABx g Films by SEM, EDS, Mapping, and XPS

Figure 4 shows the micrographs of MgAl-CO32−-LDH and MgAl-LDH-TTABx g films with different magnifications. MgAl-CO32−-LDH film has a typical blade-like structure, indicating that the metal hydroxide is successfully bound to the interior ions with excellent crystallinity of LDH film [16]. However, as shown in Figure 4a,b, the MgAl-CO32−-LDH film has numerous visible pores, resulting in a poor shielding performance of the film. As shown in Figure 4c, the surface morphology of the MgAl-LDH-TTABx g films becomes much more compact with fewer pores than that of the MgAl-CO32−-LDH films, indicating that the MgAl-LDH-TTABx g films have better shielding performance than the MgAl-CO32−-LDH films. Figure 4c,d shows that LDH nanosheets are intersecting perpendicular to the substrate and part of the lamellar LDHs combine to create a floral shape, which is consistent with previously published literature [13,40]. It can readily be observed that the concentration of TTAB has a significant impact on the shape of the resulting film. As shown in Figure 4c,e, at the lower concentrations of TTAB, MgAl-LDH-TTAB0.025 g/0.05 g films still have numerous visible pores. When the concentration of TTAB is increased, as shown in Figure 4g,i,k, MgAl-LDH-TTAB0.1 g/0.2 g/0.35 g films are more compact with fewer pores. Additionally, it is easy to observe in the enlarged views of MgAl-LDH-TTABx g film that the floral LDH nanosheets were slowly covered by small LDH nanosheets with the increase of TTAB concentration. As a result, MgAl-LDH-TTABx g films have better shielding performance with the increase of TTAB concentration.
Cross-sectional SEM images of AZ31 coated with MgAl-CO32−-LDH and MgAl-LDH-TTAB film are shown in Figure 5(a1,b1), respectively. The MgAl-CO32−-LDH film and the MgAl-LDH-TTAB film were approximately 4.20 μm and 4.43 μm in thickness, respectively. The cross-section of the MgAl-LDH-TTAB film revealed a compact hierarchical composite coating structure. EDS spectra of the surface of AZ31 coated with MgAl-CO32−-LDH film (a2) and MgAl-LDH-TTAB film (b2) are shown in Figure 5(a2,b2), respectively. The C element of MgAl-CO32−-LDH film and MgAl-LDH-TTAB film were from sodium carbonate and TTAB, respectively. Metal cations were from magnesium nitrate, aluminum nitrate, and AZ31 substrate. Results further confirmed that TTAB formed the MgAl-LDH-TTAB. Figure 6 depicts the EDS mapping of the Mg, Al, C, O, and N element in the surface of the MgAl-LDH-TTAB film. These elements uniformly distributed in the MgAl-LDH-TTAB film and confirmed the homogeneity of the MgAl-LDH-TTAB film.
Figure 7 shows the XPS spectra of the surface of the AZ31 Mg substrate coated with MgAl-CO32−-LDH film and MgAl-LDH-TTAB film. Figure 7a shows the survey spectra of two LDH-TTAB films. Binding energy peaks of Mg 1s, Al 2p, C 1s, and O 1s was detected from two LDH films, and N 1s was detected from the MgAl-LDH-TTAB film. Figure 7b,c,e,f shows the high-resolution spectra of C1s and O1s of the MgAl-CO32−-LDH and MgAl-LDH-TTAB films, respectively. As shown in Figure 7b, the binding energies of 284.4 eV may be HCO3− in the interlayer of the LDH [41], and the peak at 289.8 eV represents CO32− of MgAl-CO32−-LDH film [16]. The binding energies of 284.9 eV [42] and 288.2 eV [37] illustrated in Figure 7e reflects the C–C/C–H and C–N bond of TTAB in the MgAl-LDH-TTAB film. The peaks at 530.8 eV, 531.7 eV, and 532.7 eV can be ascribed to O–M, CO32−, and O–H of the MgAl-CO32−-LDH film (Figure 7f), respectively [13,16]. The O–M bond comes from O–Mg or O–Al, and the O–H bond comes from hydroxyl on the LDH and the adsorbed water molecules. The peaks at 530.4 eV, 531.2 eV, and 532.0 eV represent O–M, O–N, and O–H of the MgAl-LDH-TTAB film (Figure 7f), respectively [43]. The N–O bond corresponds to the NO3− in LDH [44]. Figure 7d shows N1s spectra of the MgAl-LDH-TTAB film. The peak at 403.1 eV represents -N+(CH3)3 in the TTAB and the peak at 399.1 eV can be attributed to NO3− in LDH [45,46]. The results are consistent with the results of EDS and mapping and evince that TTAB successfully formed the MgAl-LDH-TTAB film.

3.3. Adhesion Test of MgAl-LDH-TTAB Films

Figure 8a,b shows the optical microscope pictures of MgAl-LDH-TTAB film before and after tape peeling. Inspecting the grid area for the removal of coating from the substrate or from a previous coating using the magnifier and the adhesion of coating can be rated in accordance with the detached area. It should be noted that the edges of the cuts are completely the same and no small flakes of the coating are detached at intersections of the squares of the grid area, indicating that the MgAl-LDH-TTAB film has not peeled away from the corners of the substrate or scratch area after tape peeling. Therefore, the MgAl-LDH-TTAB film can be granted by 5A according to the standard of ASTM D3359-97, indicating the superior mechanical adhesion of the film [47].

3.4. Corrosion Behaviour of the Studied Samples Determined by PDP

Figure 9a shows PDP curves of Mg alloys coated with MgAl-CO32−-LDH and MgAl-LDH-TTABx g films in the 3.5 wt.% NaCl solution. The electrochemical parameters obtained from PDP curves are listed in Table 2, where Ecorr signifies the corrosion potential, icorr represents the corrosion current density, and the lower icorr represents better corrosion resistance.
The Ecorr of the MgAl-CO32−-LDH film was −1.52 V, whereas the Ecorr of the MgAl-LDH-TTAB0.35 g films increased to −0.92 V. The icorr of the MgAl-CO32−-LDH film was 1.29 × 10−5 A·cm−2 whereas the icorr of the MgAl-LDH-TTAB0.35 g film was as low as 1.09 × 10−8 A·cm−2. The more positive Ecorr and the lower icorr of the MgAl-LDH-TTAB film indicated their superior corrosion resistance compared to the MgAl-CO32−-LDH film. Additionally, the concentration of TTAB had a great influence on the corrosion performance of MgAl-LDH-TTABx g films. With the increase of TTAB concentration, the Ecorr of the MgAl-LDH-TTABx g films shifted to the direction of positive potential and the icorr was decreased. Results illustrated that the corrosion resistance of the MgAl-LDH-TTABx g films increased with the increase of TTAB concentration. As shown in Table 3, the icorr of the MgAl-LDH-TTAB film was lower than that of the LDH films previously reported, indicating that LDH films with excellent corrosion resistance can be produced by introducing a surfactant in the process of in situ hydrothermal synthesis.

3.5. Corrosion Behaviour of the Studied Samples Determined by EIS

As shown in Figure 10a, in the Nyquist plots of the MgAl-CO32−-LDH film, there is a single impedance semicircle and inductance frequency response behavior. The impedance semicircles represent the coating with medium interface reaction characteristics. The existence of inductance indicates the metal matrix is corroded and the poor MgAl-CO32−-LDH film cannot effectively protect the AZ31 substrate submerged in a 3.5 wt.% NaCl solution [50]. As shown in Figure 10a, the semicircle radius in the Nyquist plots of MgAl-LDH-TTABx g films are much greater than that of the MgAl-CO32−-LDH film, indicating that the MgAl-LDH-TTABx g films have significantly better corrosion resistance than the MgAl-CO32−-LDH film. A larger impedance modulus in the low-frequency band in the Bode graphs indicates greater corrosion resistance for an anticorrosion coating [40]. As shown in Figure 10b,d, the |Z|f = 0.05 Hz value of the MgAl-CO32−-LDH film is only 7.70 × 102 Ω·cm2, which is much lower than that of the MgAl-LDH-TTAB0.025 g film (4.13 × 105 Ω·cm2), the MgAl-LDH-TTAB0.05 g film (4.18 × 105 Ω·cm2), the MgAl-LDH-TTAB0.1 g film (4.26 × 105 Ω·cm2), the MgAl-LDH-TTAB0.2 g film (4.44 × 105 Ω·cm2), and the MgAl-LDH-TTAB0.35 g film (4.48 × 105 Ω·cm2). These results further confirm that LDH films with excellent corrosion resistance can be produced through the in situ hydrothermal method with the cationic surfactant. Additionally, as shown in Figure 10a,b,d, the semicircle radius in the Nyquist plots and the impedance modulus in the low-frequency of the MgAl-LDH-TTABx g films increased with the increase of TTAB concentration, which were consistent with the results from polarization curve fitting.
With a longer time of immersion, the evolution of EIS results was obtained to further indicate the protection performance of the MgAl-LDH-TTAB film on the alloy surface. For the MgAl-LDH-TTAB0.35 g film, the electrochemical behavior underwent a series of variations during the immersion period of 168 h (Figure 11). As shown in Figure 11a, semicircle radius in the Nyquist plots of the MgAl-LDH-TTAB0.35 g film after immersion for 0.5 h were much greater than others, indicating degradation in the protective properties after a long time immersion. Additionally, with the increase of immersion time, the impedance modulus in the low frequency tends to reduce. As shown in Figure 11c,d, |Z|f = 0.05 Hz values of the MgAl-LDH-TTAB0.35 g film were 4.48 × 105 Ω·cm2, 2.27 × 105 Ω·cm2, 2.07 × 105 Ω·cm2, 1.81 × 105 Ω·cm2, 1.53 × 105 Ω·cm2, 1.54 × 105 Ω·cm2, 1.17 × 105 Ω·cm2, and 1.16 × 105 Ω·cm2, respectively. Reduction of the impedance modulus in the low-frequency band in the Bode graphs indicated the reduction of corrosion resistance for an anticorrosion coating. Although the |Z|f = 0.05 Hz value decreased with the increase of immersion time, it decreased slowly and always maintained a |Z|f = 0.05 Hz value > 105 Ω·cm2. These results show that the MgAl-LDH-TTAB0.35 g film still can provide an effective protective effect to the AZ31 substrate after being immersed in 3.5 wt.% NaCl solution for 168 h. Consequently, it is considered that the MgAl-LDH-TTABx g films produced through the in situ hydrothermal method with a cationic surfactant have good long-term corrosion resistance.

3.6. Corrosion Inhibition Mechanism

Comparing with MgAl-CO32−-LDH film, the icorr of the MgAl-LDH-TTABx g film in 3.5 wt.% NaCl solution were reduced 3 order of magnitude (10−5 A.cm−2 to 10−8 A.cm−2), and the |Z|f = 0.05 Hz value was increased 3 order of magnitude (102 Ω·cm2 to 105 Ω·cm2), respectively. Figure 12 presents the schematic illustration of the structure of the MgAl-LDH-TTAB films for understanding its corrosion protection mechanism. As shown in Figure 12, combined with the results of electrochemical tests and structure characterizations, the high corrosion resistance of the MgAl-LDH-TTAB films on AZ31 is mainly attributed to the following factors: (i) when the AZ31 substrate is soaked in 3.5 wt.% NaCl solution, MgAl-LDH-TTAB films with compact structure can provide an efficient physical barrier to the corrosive medium and avoid direct contact between chloride ions and metal substrates; (ii) MgAl-LDH-TTAB films can intercept Cl− through anion exchange, which minimizes the corrosion of the Mg alloy. Additionally, the better corrosion resistance of the MgAl-LDH-TTABx g films with the increase of TTAB concentration can be attributed to the denser outer LDH film with the increase of TTAB concentration.

4. Conclusions

In this work, MgAl-LDH-TTAB films with high corrosion resistance were produced for the first time using an in situ hydrothermal method with the cationic surfactant TTAB, and the influence of the concentration of TTAB was investigated. The results can be summarized as follows:
(1)
MgAl-LDH-TTAB was successfully synthesized in the presence of TTAB, and TTAB was unable to penetrate the LDH layers.
(2)
MgAl-LDH-TTAB powders having an average particle size of 100–200 nm were found to be more homogeneous and smaller in particle size than MgAl-CO32−-LDH powders.
(3)
MgAl-LDH-TTAB films with compact structure, uniform distribution, and superior mechanical adhesion could provide excellent physical shielding from corrosive media. Therefore, MgAl-LDH-TTAB films protected the AZ31 substrate more effectively than the MgAl-CO32−-LDH film. The icorr of the MgAl-LDH-TTAB film was decreased to 1 × 10−8 A cm−2.
(4)
The concentration of TTAB had a significant impact on the morphology and corrosion resistance of LDHs films. With the increase of TTAB concentration, the outer layer LDH films became denser and provided better corrosion resistance for the MgAl-LDH-TTAB films.
(5)
After being immersed in 3.5 wt.% NaCl solution for 168 h, the |Z|f = 0.05 Hz values of the AZ31 substrate coated with MgAl-LDH-TTAB0.35 g film still remained at 105 Ω·cm2, implying the good long-term corrosion resistance of MgAl-LDH-TTABx g films.
As a result of this research, adding cationic surfactant in the process of in situ hydrothermal method is considered to be a novel design approach for the production of extremely effective anticorrosion coatings for magnesium alloys.

Author Contributions

Conceptualization, Q.Y. and J.Z.; methodology, Q.Y.; software, Q.Y.; validation, Q.Y., M.T. and J.W.; formal analysis, Q.Y. and J.W.; resources, J.W.; data curation, Q.Y. and M.T.; writing—original draft preparation, Q.Y.; writing—review and editing, J.Z. and M.T.; supervision, J.Z. All authors have read and agreed to the published version of the manuscript.

Funding

This research received no external funding.

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

The data presented in this study are available on reasonable request from the corresponding author.

Acknowledgments

The author acknowledges the college of New Energy and Materials at the University of China University of Petroleum (Beijing) for the SEM facilities used for this study.

Conflicts of Interest

The authors declare no conflict of interests.

References

  1. Feng, X.; Zhu, C.; Lu, X.; Yiji, Z.; Wu, T.; Zuo, Y.; Zhao, X.; Dun, Y.; Wang, M. The influence of hydrofluoric acid doped polyaniline on the protective performance of a mg-rich epoxy coating on AZ91D magnesium alloy. Prog. Org. Coat. 2020, 141, 105550. [Google Scholar] [CrossRef]
  2. Toorani, M.; Aliofkhazraei, M.; Mahdavian, M.; Naderi, R. Effective PEO/Silane pretreatment of epoxy coating applied on AZ31B Mg alloy for corrosion protection. Corros. Sci. 2020, 169, 108608. [Google Scholar] [CrossRef]
  3. Jayaraj, J.; Rajesh, K.R.; Raj, S.A.; Srinivasan, A.; Ananthakumar, S.; Dhaipule, N.G.K.; Kalpathy, S.K.; Pillai, U.T.S.; Mudali, U.K. Investigation on the corrosion behavior of lanthanum phosphate coatings on AZ31 Mg alloy obtained through chemical conversion technique. J. Alloys Compd. 2019, 784, 1162–1174. [Google Scholar] [CrossRef]
  4. Cai, Y.; Wang, X.; Wan, L.; Yang, J.; Gao, Y. Preparation of Antimony-doped Stannate Chemical Conversion Coating on AZ31B Mg Alloy. Trans. Indian Inst. Met. 2020, 73, 1891–1898. [Google Scholar] [CrossRef]
  5. Li, Y.; Li, H.; Xiong, Q.; Wu, X.; Zhou, J.; Wu, J.; Wu, X.; Qin, W. Multipurpose surface functionalization on AZ31 magnesium alloys by atomic layer deposition: Tailoring the corrosion resistance and electrical performance. Nanoscale 2017, 9, 8591–8599. [Google Scholar] [CrossRef]
  6. Wang, L.; Zong, Q.; Sun, W.; Yang, Z.; Liu, G. Chemical modification of hydrotalcite coating for enhanced corrosion resistance. Corros. Sci. 2015, 93, 256–266. [Google Scholar] [CrossRef]
  7. Salami, B.; Afshar, A.; Mazaheri, A. The effect of sodium silicate concentration on microstructure and corrosion properties of MAO-coated magnesium alloy AZ31 in simulated body fluid. J. Magnes. Alloy. 2014, 2, 72–77. [Google Scholar] [CrossRef] [Green Version]
  8. Toorani, M.; Aliofkhazraei, M.; Naderi, R. Ceria-embedded MAO process as pretreatment for corrosion protection of epoxy films applied on AZ31-magnesium alloy. J. Alloys Compd. 2019, 785, 669–683. [Google Scholar] [CrossRef]
  9. Dang, N.; Wei, Y.H.; Hou, L.F.; Li, Y.G.; Guo, C.L. Investigation of the inhibition effect of the environmentally friendly inhibitor sodium alginate on magnesium alloy in sodium chloride solution. Mater. Corros. 2015, 66, 1354–1362. [Google Scholar] [CrossRef]
  10. Umoren, S.A.; Solomon, M.M.; Madhankumar, A.; Obot, I.B. Exploration of natural polymers for use as green corrosion inhibitors for AZ31 magnesium alloy in saline environment. Carbohydr. Polym. 2020, 230, 115466. [Google Scholar] [CrossRef]
  11. Guo, L.; Wu, W.; Zhou, Y.; Zhang, F.; Zeng, R.; Zeng, J. Layered double hydroxide coatings on magnesium alloys: A review. J. Mater. Sci. Technol. 2018, 34, 1455–1466. [Google Scholar] [CrossRef]
  12. Chen, J.; Fang, L.; Wu, F.; Xie, J.; Hu, J.; Jiang, B.; Luo, H. Corrosion resistance of a self-healing rose-like MgAl-LDH coating intercalated with aspartic acid on AZ31 Mg alloy. Prog. Org. Coat. 2019, 136, 105234. [Google Scholar] [CrossRef]
  13. Cao, Y.; Zheng, D.; Li, X.; Lin, J.; Wang, C.; Dong, S.; Lin, C. Enhanced Corrosion Resistance of Superhydrophobic Layered Double Hydroxide Films with Long-Term Stability on Al Substrate. ACS Appl. Mater. Interfaces 2018, 10, 15150–15162. [Google Scholar] [CrossRef] [PubMed]
  14. Anjum, M.J.; Zhao, J.; Ali, H.; Tabish, M.; Murtaza, H.; Yasin, G.; Malik, M.U.; Khan, W.Q. A Review on Self-Healing Coatings Applied to Mg Alloys and Their Electrochemical Evaluation Techniques. Int. J. Electrochem. Sci. 2020, 15, 3040–3053. [Google Scholar] [CrossRef]
  15. Anjum, M.J.; Zhao, J.-M.; Asl, V.Z.; Malik, M.U.; Yasin, G.; Khan, W.Q. Green corrosion inhibitors intercalated Mg:Al layered double hydroxide coatings to protect Mg alloy. Rare Met. 2021, 40, 2254–2265. [Google Scholar] [CrossRef]
  16. Anjum, M.J.; Zhao, J.; Asl, V.Z.; Yasin, G.; Wang, W.; Wei, S.; Zhao, Z.; Khan, W.Q. In-situ intercalation of 8-hydroxyquinoline in Mg-Al LDH coating to improve the corrosion resistance of AZ31. Corros. Sci. 2019, 164, 108331. [Google Scholar] [CrossRef]
  17. Wen, T.; Yan, R.; Wang, N.; Li, Y.; Chen, T.; Ma, H. PPA-containing layered double hydroxide (LDH) films for corrosion protection of a magnesium alloy. Surf. Coat. Technol. 2020, 383, 125255. [Google Scholar] [CrossRef]
  18. Zhang, Y.; Liu, J.; Li, Y.; Yu, M.; Li, S.; Xue, B. A facile approach to superhydrophobic LiAl-layered double hydroxide film on Al–Li alloy substrate. J. Coat. Technol. Res. 2015, 12, 595–601. [Google Scholar] [CrossRef]
  19. Li, L.-X.; Xie, Z.-H.; Fernandez, C.; Wu, L.; Cheng, D.; Jiang, X.-H.; Zhong, C.-J. Development of a thiophene derivative modified LDH coating for Mg alloy corrosion protection. Electrochim. Acta 2020, 330, 135186. [Google Scholar] [CrossRef]
  20. Iqbal, M.A.; Fedel, M. Effect of Synthesis Conditions on the Controlled Growth of MgAl–LDH Corrosion Resistance Film: Structure and Corrosion Resistance Properties. Coatings 2019, 9, 30. [Google Scholar] [CrossRef] [Green Version]
  21. Zhou, B.; Wei, X.; Wang, Y.; Huang, Q.; Hong, B.; Wei, Y. Effect of lanthanum addition on microstructures and corrosion behavior of ZnAl-LDHs film of 6061 aluminum alloys. Surf. Coat. Technol. 2019, 379, 125056. [Google Scholar] [CrossRef]
  22. Zhang, J.; Xie, X.; Li, C.; Wang, H.; Wang, L. The role of soft colloidal templates in the shape evolution of flower-like MgAl-LDH hierarchical microstructures. RSC Adv. 2015, 5, 29757–29765. [Google Scholar] [CrossRef]
  23. Liu, J.; Han, E.; He, Y.; Yang, X.; Qiao, S.; Tong, X.; Tian, Y.; Gao, L. Effect of soft template on NiMn-LDH grown on nickel foam for battery-type electrode materials. Ionics 2021, 27, 1451–1463. [Google Scholar] [CrossRef]
  24. Manjula Rani, K.; Palanisamy, P.N. Synthesis and Characterization of Mesoporous, Nanostructured Zinc Aluminium Carbonate Layered Double Hydroxides (ZAC-LDHs) and Its Calcined Product (CZA-LDH). J. Inorg. Organomet. Polym. Mater. 2018, 28, 1127–1135. [Google Scholar] [CrossRef]
  25. Yasin, G.; Arif, M.; Nizam, M.N.; Shakeel, M.; Khan, M.A.; Khan, W.Q.; Hassan, T.M.; Abbas, Z.; Farahbakhsh, I.; Zuo, Y. Effect of surfactant concentration in electrolyte on the fabrication and properties of nickel-graphene nanocomposite coating synthesized by electrochemical co-deposition. RSC Adv. 2018, 8, 20039–20047. [Google Scholar] [CrossRef] [Green Version]
  26. Tamilarasan, T.R.; Rajendran, R.; Rajagopal, G.; Sudagar, J. Effect of surfactants on the coating properties and corrosion behaviour of Ni–P–nano-TiO2 coatings. Surf. Coat. Technol. 2015, 276, 320–326. [Google Scholar] [CrossRef]
  27. Lin, J.; Hsia, C.; Uan, J. Characterization of Mg,Al-hydrotalcite conversion film on Mg alloy and Cl− and CO32−—Anion-exchangeability of the film in a corrosive environment. Scr. Mater. 2008, 56, 927–930. [Google Scholar] [CrossRef]
  28. Lin, J.; Uan, J. Formation of Mg, Al-hydrotalcite conversion coating on Mg alloy in aqueous HCO3−/CO32− and corresponding protection against corrosion by the coating. Corros. Sci. 2009, 51, 1181–1188. [Google Scholar] [CrossRef]
  29. Jung, K.-W.; Lee, S.Y.; Choi, J.-W.; Hwang, M.-J.; Shim, W.G. Synthesis of Mg–Al layered double hydroxides-functionalized hydrochar composite via an in situ one-pot hydrothermal method for arsenate and phosphate removal: Structural characterization and adsorption performance. Chem. Eng. J. 2021, 420, 129775. [Google Scholar] [CrossRef]
  30. ASTM International. Annual Book of ASTM Standards 2010; ASTM: West Conshohocken, PA, USA, 2010; p. 642. [Google Scholar]
  31. Djebbi, M.A.; Braiek, M.; Namour, P.; Amara, A.B.H.; Jaffrezic-Renault, N. Layered double hydroxide materials coated carbon electrode: New challenge to future electrochemical power devices. Appl. Surf. Sci. 2016, 386, 352–363. [Google Scholar] [CrossRef]
  32. Hu, M.; Yan, X.; Hu, X.; Feng, R.; Zhou, M. High-capacity adsorption of benzotriazole from aqueous solution by calcined Zn-Al layered double hydroxides. Colloids Surf. A Physicochem. Eng. Asp. 2018, 540, 207–214. [Google Scholar] [CrossRef]
  33. Fitaroni, L.B.; Venâncio, T.; Tanaka, F.H.; Gimenez, J.C.F.; Costa, J.A.S.; Cruz, S.A. Organically modified sepiolite: Thermal treatment and chemical and morphological properties. Appl. Clay Sci. 2019, 179, 105149. [Google Scholar] [CrossRef]
  34. Javadian, S.; Darbasizadeh, B.; Yousefi, A.; Ektefa, F.; Dalir, N.; Kakemam, J. Dye-surfactant aggregates as corrosion inhibitor for mild steel in NaCl medium: Experimental and theoretical studies. J. Taiwan Inst. Chem. Eng. 2017, 71, 344–354. [Google Scholar] [CrossRef]
  35. Mohammadi-Moghadam, F.; Khodabakhshi, A.; Farhadkhani, M.; Hemati, S.; Masoudipour, N.; Shahgholian, F.; Nourmoradi, H. Removal of Trichloroethylene by Clay Modified with Cationic Surfactant in Aqueous Solutions: Equilibrium, Kinetic, and Thermodynamic Study. J. Surfactants Deterg. 2020, 23, 1099–1109. [Google Scholar] [CrossRef]
  36. Ye, X.; Jiang, Z.; Li, L.; Xie, Z. In-situ growth of NiAl-layered double hydroxide on AZ31 Mg alloy towards enhanced corrosion protection. Nanomaterials 2018, 8, 411. [Google Scholar] [CrossRef] [Green Version]
  37. An, X.; Zhang, L.; He, Y.; Zhu, W.; Luo, Y. Kinetic, isotherm, and thermodynamic studies of Cr (VI) removal from aqueous solution using mesoporous silica materials prepared by fly ash. Can. J. Chem. Eng. 2020, 98, 1825–1834. [Google Scholar] [CrossRef]
  38. Banjare, R.K.; Banjare, M.K.; Panda, S. Effect of Acetonitrile on the Colloidal Behavior of Conventional Cationic Surfactants: A Combined Conductivity, Surface Tension, Fluorescence and FTIR Study. J. Solut. Chem. 2020, 49, 34–51. [Google Scholar] [CrossRef]
  39. Hang, T.T.X.; Truc, T.A.; Duong, N.T.; Vu, P.G.; Hoang, T. Preparation and characterization of nanocontainers of corrosion inhibitor based on layered double hydroxides. Appl. Clay Sci. 2012, 67, 18–25. [Google Scholar] [CrossRef]
  40. Wang, X.; Jing, C.; Chen, Y.; Wang, X.; Zhao, G.; Zhang, X.; Wu, L.; Liu, X.; Dong, B.; Zhang, Y. Active corrosion protection of super-hydrophobic corrosion inhibitor intercalated Mg–Al layered double hydroxide coating on AZ31 magnesium alloy. J. Magnes. Alloy. 2020, 8, 291–300. [Google Scholar] [CrossRef]
  41. Lyu, F.; Yu, H.; Hou, T.; Yan, L.; Zhang, X.; Du, B. Efficient and fast removal of Pb2+ and Cd2+ from an aqueous solution using a chitosan/Mg-Al-layered double hydroxide nanocomposite. J. Colloid Interface Sci. 2019, 539, 184–193. [Google Scholar] [CrossRef]
  42. Geng, X.; Lv, L.; Zhang, T.; Tang, S. The regulating mechanism of MgCO3·3H2O whisker growth orientation with the presence of SDS. J. CO2 Util. 2020, 42, 101307. [Google Scholar] [CrossRef]
  43. Cao, Y.; Jin, S.; Zheng, D.; Lin, C. Facile fabrication of ZnAl layered double hydroxide film co-intercalated with vanadates and laurates by one-step post modification. Colloid Interface Sci. Commun. 2021, 40, 100351. [Google Scholar] [CrossRef]
  44. Chen, J.L.; Liang, F.A.N.G.; Fang, W.U.; Zeng, X.G.; Jia, H.U.; Zhang, S.F.; Jiang, B.; Luo, H.J. Comparison of corrosion resistance of MgAl-LDH and ZnAl-LDH films intercalated with organic anions ASP on AZ31 Mg alloys. Trans. Nonferr. Met. Soc. China 2020, 30, 2424–2434. [Google Scholar] [CrossRef]
  45. Zhang, C.; Zhao, J. Synergistic inhibition effects of octadecylamine and tetradecyl trimethyl ammonium bromide on carbon steel corrosion in the H2S and CO2 brine solution. Corros. Sci. 2017, 126, 247–254. [Google Scholar] [CrossRef]
  46. Song, Y.; Wang, H.; Liu, Q.; Li, G.; Wang, S.; Zhu, X. Sodium dodecyl sulfate (SDS) intercalated Mg Al layered double hydroxides film to enhance the corrosion resistance of AZ31 magnesium alloy. Surf. Coat. Technol. 2021, 422, 127524. [Google Scholar] [CrossRef]
  47. ASTM International. D3359-97; Standard Test Methods for Measuring Adhesion by Tape Test. ASTM: West Conshohocken, PA, USA, 1997.
  48. Ding, C.; Tai, Y.; Wang, D.; Tan, L.; Fu, J. Superhydrophobic composite coating with active corrosion resistance for AZ31B magnesium alloy protection. Chem. Eng. J. 2019, 357, 518–532. [Google Scholar] [CrossRef]
  49. Song, Y.; Tang, Y.; Fang, L.; Wu, F.; Zeng, X.; Hu, J.; Zhang, S.F.; Jiang, B.; Luo, H. Enhancement of corrosion resistance of AZ31 Mg alloys by one-step in situ synthesis of ZnAl-LDH films intercalated with organic anions (ASP, La). J. Magnes. Alloy. 2021, 9, 658–667. [Google Scholar] [CrossRef]
  50. Zhao, W.; Wang, Y.; Xue, J.; Wu, K.Y. EIS study of the corrosion failure process of steel coated by nickel base alloy. Acta Metall. Sin. Chin. Ed. 2005, 41, 178–184. [Google Scholar]
Materials 15 02028 g001 550
Figure 1. Schematic illustration of the preparation of MgAl-LDH-TTAB films.
Figure 1. Schematic illustration of the preparation of MgAl-LDH-TTAB films.
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Materials 15 02028 g002 550
Figure 2. XRD patterns (a) and FTIR spectra (b) of MgAl-CO32−-LDH powders and MgAl-LDH-TTAB powders.
Figure 2. XRD patterns (a) and FTIR spectra (b) of MgAl-CO32−-LDH powders and MgAl-LDH-TTAB powders.
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Materials 15 02028 g003 550
Figure 3. SEM images of (a) MgAl-CO32−-LDH powders and (b) MgAl-LDH-TTAB powders.
Figure 3. SEM images of (a) MgAl-CO32−-LDH powders and (b) MgAl-LDH-TTAB powders.
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Materials 15 02028 g004 550
Figure 4. SEM images of LDH films, (a,b) MgAl-CO32−-LDH film, (c,d) MgAl-LDH-TTAB0.025 g film, (e,f) MgAl-LDH-TTAB0.05 g film, (g,h) MgAl-LDH-TTAB0.1 g film, (i,j) MgAl-LDH-TTAB0.2 g film, (k,l) MgAl-LDH-TTAB0.35 g film. (b,d,f,h,j,l) are enlarged views of areas marked with red boxes in (a,c,e,g,i,k), respectively.
Figure 4. SEM images of LDH films, (a,b) MgAl-CO32−-LDH film, (c,d) MgAl-LDH-TTAB0.025 g film, (e,f) MgAl-LDH-TTAB0.05 g film, (g,h) MgAl-LDH-TTAB0.1 g film, (i,j) MgAl-LDH-TTAB0.2 g film, (k,l) MgAl-LDH-TTAB0.35 g film. (b,d,f,h,j,l) are enlarged views of areas marked with red boxes in (a,c,e,g,i,k), respectively.
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Materials 15 02028 g005 550
Figure 5. Cross-sections of AZ31 coated with MgAl-CO32−-LDH film (a1) and MgAl-LDH-TTAB film, (b1), and EDS spectra of the surface of AZ31 coated with MgAl-CO32−-LDH film (a2) and MgAl-LDH-TTAB film (b2).
Figure 5. Cross-sections of AZ31 coated with MgAl-CO32−-LDH film (a1) and MgAl-LDH-TTAB film, (b1), and EDS spectra of the surface of AZ31 coated with MgAl-CO32−-LDH film (a2) and MgAl-LDH-TTAB film (b2).
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Materials 15 02028 g006 550
Figure 6. Elemental mappings of the surface of AZ31 coated with MgAl-LDH-TTAB film.
Figure 6. Elemental mappings of the surface of AZ31 coated with MgAl-LDH-TTAB film.
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Materials 15 02028 g007 550
Figure 7. XPS spectra of LDH film, including survey spectra (a), C1s and O1s high-resolution spectra (b,c) of MgAl-CO32−-LDH film, and N1s, C1s and O1s high-resolution spectra (d–f) of MgAl-LDH-TTAB film.
Figure 7. XPS spectra of LDH film, including survey spectra (a), C1s and O1s high-resolution spectra (b,c) of MgAl-CO32−-LDH film, and N1s, C1s and O1s high-resolution spectra (d–f) of MgAl-LDH-TTAB film.
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Figure 8. Adhesion test of MgAl-LDH-TTAB film (a) before and (b) after tape peeling.
Figure 8. Adhesion test of MgAl-LDH-TTAB film (a) before and (b) after tape peeling.
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Figure 9. (a) PDP curves of MgAl-CO32−-LDH film and MgAl-LDH-TTABx g films in a 3.5 wt.% NaCl solution, (b) the corresponding corrosion current density columns.
Figure 9. (a) PDP curves of MgAl-CO32−-LDH film and MgAl-LDH-TTABx g films in a 3.5 wt.% NaCl solution, (b) the corresponding corrosion current density columns.
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Figure 10. (a) Nyquist plots and (b,c) Bode plots of EIS curves of the MgAl-CO32−LDH film and the MgAl-LDH-TTABx g films, enlarged view (d) of the illustration in (b).
Figure 10. (a) Nyquist plots and (b,c) Bode plots of EIS curves of the MgAl-CO32−LDH film and the MgAl-LDH-TTABx g films, enlarged view (d) of the illustration in (b).
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Figure 11. (a) Nyquist plots and (b,c) Bode plots of EIS curves of AZ31 coated with MgAl-LDH-TTAB0.35 g film after different immersion times in 3.5 wt.% NaCl solution, enlarged view (d) of the illustration in (c).
Figure 11. (a) Nyquist plots and (b,c) Bode plots of EIS curves of AZ31 coated with MgAl-LDH-TTAB0.35 g film after different immersion times in 3.5 wt.% NaCl solution, enlarged view (d) of the illustration in (c).
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Figure 12. Schematic illustration of the corrosion protection mechanism of MgAl-LDH-TTAB films.
Figure 12. Schematic illustration of the corrosion protection mechanism of MgAl-LDH-TTAB films.
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Table
Table 1. The acronyms and the difference of the studied samples.
Table 1. The acronyms and the difference of the studied samples.
SampleDifference
MgAl-CO32−-LDHobtained from NaOH, Na2CO3, magnesium nitrate, and aluminum nitrate
MgAl-LDH-TTAB0.025 gobtained from NaOH, TTAB, magnesium nitrate, and aluminum nitrate in the N2 environment0.025 g TTAB
MgAl-LDH-TTAB0.05 g0.05 g TTAB
MgAl-LDH-TTAB0.1 g0.1 g TTAB
MgAl-LDH-TTAB0.2 g0.2 g TTAB
MgAl-LDH-TTAB0.35 g0.35 g TTAB
Table
Table 2. Electrochemical parameters of AZ31 coated with MgAl-CO32−-LDH film and MgAl-LDH-TTABx g films estimated from the polarization data.
Table 2. Electrochemical parameters of AZ31 coated with MgAl-CO32−-LDH film and MgAl-LDH-TTABx g films estimated from the polarization data.
SampleEcorr (V/SCE)icorr (A·cm−2)
MgAl-CO32−-LDH−1.521.29 × 10−5
MgAl-LDH-TTAB0.025 g−1.234.26 × 10−8
MgAl-LDH-TTAB0.05 g−1.023.74 × 10−8
MgAl-LDH-TTAB0.1 g−0.982.66 × 10−8
MgAl-LDH-TTAB0.2 g−0.931.54 × 10−8
MgAl-LDH-TTAB0.35 g−0.921.09 × 10−8
Table
Table 3. Comparison of corrosion resistance of various LDH composite films on the surface of AZ31 (electrolyte: 3.5 wt.% NaCl).
Table 3. Comparison of corrosion resistance of various LDH composite films on the surface of AZ31 (electrolyte: 3.5 wt.% NaCl).
SampleEcorr (V/SCE)icorr (A·cm−2)Reference
MgAl-LDH-TTAB0.35 g−0.921.09 × 10−8This study
MgAl-WO42−-LDHs −1.267.44 × 10−6[48]
MgAl−8HQ-LDHs−0.771.70 × 10−7[16]
MgAl-ASP-LDHs0.122.24 × 10−8[12]
MgAl-PPA-LDHs−1.162.47 × 10−9[17]
MgAl-NO3−-LDHs−1.533.10 × 10−7[40]
ZnAl-La-LDHs−1.072.77 × 10−7[49]
ZnAl-ASP-LDHs−1.503.93 × 10−7[49]
ZnAl-MoO42−-LDHs−0.983.42 × 10−6[49]
ZnAl-VO43−-LDHs−0.883.03 × 10−7[49]
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Yang, Q.; Tabish, M.; Wang, J.; Zhao, J. Enhanced Corrosion Resistance of Layered Double Hydroxide Films on Mg Alloy: The Key Role of Cationic Surfactant. Materials 2022, 15, 2028. https://doi.org/10.3390/ma15062028

AMA Style

Yang Q, Tabish M, Wang J, Zhao J. Enhanced Corrosion Resistance of Layered Double Hydroxide Films on Mg Alloy: The Key Role of Cationic Surfactant. Materials. 2022; 15(6):2028. https://doi.org/10.3390/ma15062028

Chicago/Turabian Style

Yang, Qiuxiang, Mohammad Tabish, Jingbao Wang, and Jingmao Zhao. 2022. "Enhanced Corrosion Resistance of Layered Double Hydroxide Films on Mg Alloy: The Key Role of Cationic Surfactant" Materials 15, no. 6: 2028. https://doi.org/10.3390/ma15062028

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