Faience Waste for the Production of Wall Products
Abstract
:1. Introduction
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- the use of computer modeling tools for designing the structure of a composite material, taking into account the chaotic nature of the distribution of structural elements in the volume of the material.
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- finding the packing density of elements, which is necessary to determine the physical, mechanical, rheological and other properties.
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- development and research of gypsum wall products based on faience production waste.
2. Materials and Methods
2.1. Materials
2.2. Mix Design
2.3. Methods
2.3.1. Raw Material Properties
2.3.2. Strength Properties of Concrete
3. Results and Discussion
3.1. Selection of the Optimal Grain Composition
3.2. Influence of Optimal Packaging on the Physical and Mechanical Properties of the Composite
3.3. Physical and Mechanical Characteristics of Gypsum Building Products
4. Conclusions
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- In gypsum powders, the formation of fractals at different levels of dispersion is possible due to the adhesion of small particles to large ones. An important point here is the similarity of material structures at scale levels, the so-called fractal nature of the structure, which in turn fragments the optimization problem and expands the range of structure optimality parameters.
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- Formation based on a bidispersed system of non-hydration hardening of aggregates or clusters with stirring and moistening simplifies the pressing process. The rational binder system is formed by mixing powders of dihydrate technogenic gypsum from a faience factory of coarse and fine grinding with average particle diameters of 3.473 μm and 3.065 μm in a percentage ratio of 30:70, respectively.
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- Optimization of the system as a result of the formation of a significant number of gaps and slots with a negative curvature of the surface contributes to an increase in its solubility and strength, the efficiency of processes during non-hydration hardening of gypsum dispersed systems. The studies carried out show that the solubility of dispersed systems of dihydrate gypsum of technogenic genesis depends on the fineness of grinding. With an increase in the specific surface of the powders from 667 to 987 m2/kg, the solubility increases. With a further increase in the specific surface area to 1006 m2/kg, the solubility decreases, which is due to a decrease in the number of defects on the particle surface
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- The most decisive factor in the formation of a dispersed structure is the ordering of particles, that is, the packing of material grains at all scale levels, the most important of which is the morphology of particles (size, shape, etc.).
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- It was revealed that a brick based on waste of dihydrate gypsum from earthenware production has 2.5–5 times better characteristics of compressive strength than traditional building wall products based on natural gypsum. At the same time, the strength immediately after molding is more than 3 times higher than that of traditional gypsum products. Even higher rates are achieved when adding microcalcite in addition to the waste of earthenware production, in this case, the compressive strength is 3–6 times higher, and the strength immediately after molding is almost 3 times higher than that of traditional gypsum products.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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SiO2 | Al2O3 | TiO2 | Fe2O3 | CaO | MgO | SO3 | Na2O | K2O | P2O5 | F |
---|---|---|---|---|---|---|---|---|---|---|
0.8 | traces | traces | – | 37.52 | 0.10 | 53.78 | 0.05 | 0.007 | – | – |
Mix ID | Description | Mixture Composition,% (by Dry Matter) | Water–Solid Ratio | ||||
---|---|---|---|---|---|---|---|
Dihydrate Gypsum (25% Coarse: 75% Fine) | CEM III 32.5 | Micro-Calcite | SP | Ammonium Alum | |||
1 | Brick based on waste of dihydrate gypsum from faience production | 100 | - | - | - | - | 0.06 |
2 | Brick based on wastes of dihydrate gypsum from faience production with ammonium alum | 71 | 28.5 | - | - | 0.5 | 0.28 |
3 | Brick based on wastes of dihydrate gypsum from faience production with the microcalcite | 90 | - | 10 | - | - | 0.12 |
4 | Brick based on wastes of dihydrate gypsum from faience production with CEM III 32.5 and SP | 86 | 9 | - | 5 | - | 0.1 |
5 | Brick based on wastes of dihydrate gypsum from faience production with the microcalcite, CEM III 32.5 and SP | 76 | 9 | 10 | 5 | - | 0.08 |
Properties | Units of Measurement | Values |
---|---|---|
Average density | kg/m3 | 1900 |
Flexural strength | MPa | 3.83 |
Compressive strength | Mpa | 68.0 |
Water resistance | - | 0.6 |
Properties | 1 | 2 | 3 | 4 | 5 |
---|---|---|---|---|---|
Average density, kg/m3 | 1960 | 1650 | 1140 | 1050 | 1520 |
Compressive strength, MPa | 25 | 10.5 | 5.3 | 10.0 | 36 |
Compressive strength immediately after pressing, MPa | 3.6 | 1.1 | 1.1 | 0.9 | 5.0 |
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Petropavlovskii, K.; Novichenkova, T.; Petropavlovskaya, V.; Sulman, M.; Fediuk, R.; Amran, M. Faience Waste for the Production of Wall Products. Materials 2021, 14, 6677. https://doi.org/10.3390/ma14216677
Petropavlovskii K, Novichenkova T, Petropavlovskaya V, Sulman M, Fediuk R, Amran M. Faience Waste for the Production of Wall Products. Materials. 2021; 14(21):6677. https://doi.org/10.3390/ma14216677
Chicago/Turabian StylePetropavlovskii, Kirill, Tatiana Novichenkova, Victoria Petropavlovskaya, Mikhail Sulman, Roman Fediuk, and Mugahed Amran. 2021. "Faience Waste for the Production of Wall Products" Materials 14, no. 21: 6677. https://doi.org/10.3390/ma14216677