Achievement of High Strength and Ductility in Al–Si–Cu–Mg Alloys by Intermediate Phase Optimization in As-Cast and Heat Treatment Conditions
Abstract
:1. Introduction
2. Materials and Methods
2.1. Optimization of the Base Alloy with the Best Matches of Cu and Mg
2.2. Modification of Insoluble Phases
2.3. Optimization of Artificial Ageing Processes
3. Results and Discussion
3.1. Optimization of the Base Alloy with the Best Matches of Cu and Mg
3.1.1. Effect of Cu and Mg Contents on Soluble Phases in Al–Si–Cu–Mg Alloy
3.1.2. Effect of Cu and Mg Contents on the Mechanical Properties of Al–Si–Cu–Mg Alloy
3.2. Modification of Insoluble Phases by Zn in the Al–9Si–1.2Cu–0.4Mg-Based Alloy
3.2.1. Effect of Zn Content on Insoluble Phases of Al–Si–Cu–Mg-Based Alloy in As-Cast Conditions
3.2.2. Effect of Zn Content on the Insoluble Phases of Al–Si–Cu–Mg Alloy in the Heat Treatment
3.2.3. Effect of Zn Content on the Mechanical Properties of Al–Si–Cu–Mg Alloy during Heat Treatment
3.3. Optimization of Artificial Ageing Processes in Base Alloy and 0.6 wt% Zn Modified Alloy
3.3.1. Effect of Zn on the Ageing Curve of Al–Si–Cu–Mg Alloy
3.3.2. Effect of Artificial Ageing Processes on Mechanical Properties of Base Alloy and 0.6 wt% Zn Modified Alloy
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
- Fan, K.L.; He, G.Q. Tensile and fatigue properties of gravity casting aluminum alloys for engine cylinder heads. Mater. Sci. Eng. A 2013, 586, 78–85. [Google Scholar] [CrossRef]
- Yu, Z.W.; Xu, X.L. Failure analysis of diesel engine cylinder head bolts. Eng. Fail. Anal. 2006, 13, 826–834. [Google Scholar] [CrossRef]
- Nadir, Y.; Alpaslan, A. Experimental evaluation of a diesel engine running on the blends of diesel and pentanol as a next generation higher alcohol. Fuel 2017, 210, 75–82. [Google Scholar] [CrossRef]
- Sadeghi, I.; Mary, A.W. Effect of particle shape and size distribution on the dissolution behavior of Al2Cu particles during homogenization in aluminum casting alloy Al–Si–Cu–Mg. J. Mater. Process. Technol. 2018, 251, 232–240. [Google Scholar] [CrossRef]
- Ma, Z.E.; Mohamed, A.M. Parameters controlling the microstructure of Al–11Si–2.5Cu–Mg alloys. Mater. Des. 2010, 31, 902–912. [Google Scholar] [CrossRef]
- Lombardi, A.; Ravindran, C. Optimization of the solution heat treatment process to improve mechanical properties of 319 Al alloy engine blocks using the billet casting method. Mater. Sci. Eng. A 2015, 633, 125–135. [Google Scholar] [CrossRef]
- Mohamed, A.M.; Samuel, F.H. Influence of Mg and solution heat treatment on the occurrence of incipient melting in Al–Si–Cu–Mg cast alloys. Mater. Sci. Eng. A 2012, 543, 22–34. [Google Scholar] [CrossRef]
- Sjölander, E.; Seifeddine, S. Artificial ageing of Al–Si–Cu–Mg casting alloys. Mater. Sci. Eng. A 2011, 528, 7402–7409. [Google Scholar] [CrossRef]
- Taylor, J.A.; St John, D.H. Influence of Mg content on the microstructure and solid solution chemistry of Al–7%Si–Mg casting alloys during solution treatment. Mater. Sci. Forum Mater. Lett. 2000, 51, 331–337. [Google Scholar] [CrossRef]
- Sauvage, X.; Lee, S. Origin of the influence of Cu or Ag micro-additions on the age hardening behavior of ultrafine-grained Al-Mg-Si alloys. J. Alloy. Compd. 2017, 710, 99–204. [Google Scholar] [CrossRef]
- Hwang, J.Y.; Banerjee, H.W. The effect of Mg on the structure and properties of type 319 aluminum casting alloys. Acta Mater 2009, 57, 1308–1317. [Google Scholar] [CrossRef]
- Hwang, J.Y.; Doty, H.W. The effects of Mn additions on the microstructure and mechanical properties of Al–Si–Cu casting alloys. Mater. Sci. Eng. A 2008, 488, 496–504. [Google Scholar] [CrossRef]
- Choi, S.W.; Kim, Y.M. The effects of cooling rate and heat treatment on mechanical and thermal characteristics of Al–Si–Cu–Mg foundry alloys. J. Alloy. Compd. 2014, 617, 654–659. [Google Scholar] [CrossRef]
- Saïd, B.L.; Zakaria, B.G. Effects of heat treatment and addition of small amounts of Cu and Mg on the microstructure and mechanical properties of Al–Si-Cu and Al–Si-Mg cast alloys. J. Alloy. Compd. 2019, 784, 1026–1035. [Google Scholar] [CrossRef]
- Sjölander, E.M.; Seifeddine, S.M. The heat treatment of Al–Si–Cu–Mg casting alloys. J. Mater. Process. Technol. 2010, 210, 1249–1259. [Google Scholar] [CrossRef] [Green Version]
- Samuel, A.M.; Doty, H.W. Optimizing the tensile properties of Al–Si–Cu–Mg 319-type alloys: Role of solution heat treatment. Mater. Des. 2014, 58, 426–438. [Google Scholar] [CrossRef]
- Li, J.H.; Barrirero, J.M. Nucleation and Growth of Eutectic Si in Al–Si Alloys with Na Addition. Metall. Mater. Trans. A 2015, 41A, 1300–1311. [Google Scholar] [CrossRef]
- Li, J.H.; Zarif, M.Z. Nucleation kinetics of entrained eutectic Si in Al–5Si alloys. Acta Mater. 2014, 72, 80–98. [Google Scholar] [CrossRef]
- Liu, X.R.; Zhang, Y.D. Heat-treatment induced defect formation in a-Al matrix in Sr-modified eutectic Al–Si alloy. J. Alloy. Compd. 2018, 730, 208–218. [Google Scholar] [CrossRef]
- Lin, Y.C.; Luo, S.C. Effects of solution treatment on microstructures and micro-hardness of a Sr-modified Al–Si-Mg alloy. Mater. Sci. Eng. A 2018, 725, 530–540. [Google Scholar] [CrossRef]
- Basak, C.B.; Babu, N.H. Morphological changes and segregation of β-Al5FeSi phase: A perspective from better recyclability of cast Al–Si alloys. Mater. Des. 2016, 108, 277–288. [Google Scholar] [CrossRef] [Green Version]
- Zhou, L.; Abhishek, M. Microstructure, precipitates and hardness of selectively laser melted AlSi10Mg alloy before and after heat treatment. Mater. Charact. 2018, 143, 5–17. [Google Scholar] [CrossRef]
- Gao, T.; Li, Z.Q. Evolution of Fe–rich phases in Mg melt and a novel method for separating Al and Fe from Al–Si–Fe alloys. Mater. Des. 2017, 134, 71–80. [Google Scholar] [CrossRef]
- Yao, J.Y.; Taylor, J.A. Characterisation of intermetallic particles formed during solution treatment of an Al–7Si–0.4Mg–0.12Fe alloy. J. Alloy. Compd. 2012, 519, 60–66. [Google Scholar] [CrossRef]
- Li, R.X.; Li, R.D. Age-hardening behavior of cast Al–Si base alloy. Mater. Lett. 2004, 58, 2096–2101. [Google Scholar] [CrossRef]
- Li, Y.J.; Brusethaug, O.N. Influence of Cu on the mechanical properties and precipitation behavior AlSi7Mg0.5 alloy during aging treatment. Scr. Mater. 2006, 54, 99–103. [Google Scholar] [CrossRef]
- Mondolfo, L.F. Aluminum Alloys: Structure and Properties; Butterworths: London, UK, 1976; pp. 644–647. [Google Scholar]
- Aniruddha, B.A.; Siegel, D.J. Compositional evolution of Q-phase precipitates in an aluminum alloy. Acta Mater. 2014, 75, 322–336. [Google Scholar] [CrossRef]
- Sjölander, E.A.; Seifeddine, S.M. Optimization of Solution Treatment of Cast Al-7Si-0.3Mg and Al-8Si-3Cu-0.5Mg Alloys. Mater. Sci. Eng. A 2014, 45, 1916–1927. [Google Scholar] [CrossRef]
- Wu, Y.; Xi, Z.H. Formation of Si wells and pyramids on (100) surface as a result of Zn–Si interaction. Mater. Sci. Semicond. Process. 2011, 14, 302–305. [Google Scholar] [CrossRef]
- Park, S.W.; Sugahara, T.N. High-strength Si wafer bonding by self-regulated eutectic reaction with pure Zn. Scripta. Mater. 2013, 68, 591–594. [Google Scholar] [CrossRef]
- Guo, M.X.; Li, G.J. Influence of Zn on the distribution and composition of heterogeneous solute-rich features in peak aged Al–Mg–Si–Cu alloys. Scr. Mater 2019, 159, 5–8. [Google Scholar] [CrossRef]
- Guo, M.X.; Zhang, Y.D. Solute clustering in Al–Mg–Si–Cu-(Zn) alloys during aging. J. Alloy. Compd. 2019, 774, 347–363. [Google Scholar] [CrossRef]
- Guo, M.X.; Cao, L.Y. Enhanced bake-hardening response of an Al–Mg–Si–Cu alloy with Zn addition. Mater. Chem. Phys. 2015, 162, 15–19. [Google Scholar] [CrossRef]
- Guo, M.X.; Zhang, X.K. Non-isothermal precipitation behaviors of Al–Mg–Si–Cu alloys with different Zn contents. Mater. Sci. Eng. A 2016, 669, 20–32. [Google Scholar] [CrossRef]
Alloy | Si | Cu | Mg | Fe | Ti | Sr | Al |
---|---|---|---|---|---|---|---|
M1 | 8.8 | Change | 0.21 | 0.16 | 0.16 | 0.0054 | Bal. |
M2 | 9.1 | Change | 0.38 | 0.15 | 0.17 | 0.0061 | Bal. |
M3 | 8.9 | Change | 0.57 | 0.18 | 0.15 | 0.0046 | Bal. |
Alloy | Change in Cu Content (%) | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
M1 | 0.03 | 0.31 | 0.61 | 0.94 | 1.21 | 1.51 | 1.81 | 2.11 | 2.41 | 2.69 | 3.01 |
M2 | 0.01 | 0.29 | 0.61 | 0.93 | 1.17 | 1.51 | 1.83 | 2.07 | 2.41 | 2.71 | 3.03 |
M3 | 0.04 | 0.28 | 0.63 | 0.94 | 1.19 | 1.52 | 1.81 | 2.09 | 2.39 | 2.72 | 2.98 |
Alloy | Si | Cu | Mg | Zn | Fe | Ti | Sr | Al |
---|---|---|---|---|---|---|---|---|
Al–9Si–1.2Cu–0.4Mg (0.005 Sr) | 8.7 | 0.93 | 0.41 | - | 0.14 | 0.14 | 0.0050 | Bal. |
Al–9Si–1.2Cu–0.4Mg (0.3 Zn + 0.005 Sr) | 8.8 | 0.95 | 0.39 | 0.29 | 0.15 | 0.16 | 0.0052 | Bal. |
Al–9Si–1.2Cu–0.4Mg (0.6 Zn + 0.005 Sr) | 9.1 | 0.94 | 0.38 | 0.61 | 0.15 | 0.15 | 0.0056 | Bal. |
Al–9Si–1.2Cu–0.4Mg (0.9 Zn + 0.005 Sr) | 8.9 | 0.92 | 0.42 | 0.88 | 0.16 | 0.15 | 0.0054 | Bal. |
Peak | Reaction | Temperature |
---|---|---|
Endothermic peak A | Eutectic Al2Cu→liquid | 507 °C |
Endothermic peak B | Blocky Al2Cu→liquid | 520 °C |
Endothermic peak C | Al5Cu2Mg8Si6→liquid | 534 °C |
Endothermic peak D | Mg2Si→liquid | 554 °C |
Endothermic peak E | Eutectic Si→liquid | 569 °C |
Area of Peak | Peak A | Peak B | Peak C | Peak D | |||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Mg | 0.2 Mg | 0.4 Mg | 0.6 Mg | 0.2 Mg | 0.4 Mg | 0.6 Mg | 0.2 Mg | 0.4 Mg | 0.6 Mg | 0.2 Mg | 0.4 Mg | 0.6 Mg | |
Cu | |||||||||||||
0 Cu | - | - | - | - | - | - | - | - | - | 1.43 | 1.64 | 1.75 | |
0.6 Cu | 0.76 | 0.38 | 0.31 | - | - | - | 0.53 | 0.41 | 0.51 | - | 0.78 | 0.96 | |
1.2 Cu | 2.32 | 2.21 | 2.11 | 0.73 | 0.89 | 0.87 | 0.96 | 1.08 | 1.33 | - | - | - | |
1.8 Cu | 6.14 | 4.53 | 4.02 | 1.91 | 2.95 | 3.02 | - | - | - | - | - | - | |
2.4 Cu | 16.71 | 9.54 | 8.99 | 2.97 | 5.61 | 7.72 | - | - | - | -- | - | ||
3 Cu | 21.45 | 17.54 | 16.98 | 4.12 | 7.17 | 8.31 | - | - | - | - | - | - |
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Zhang, B.; Zhang, L.; Wang, Z.; Gao, A. Achievement of High Strength and Ductility in Al–Si–Cu–Mg Alloys by Intermediate Phase Optimization in As-Cast and Heat Treatment Conditions. Materials 2020, 13, 647. https://doi.org/10.3390/ma13030647
Zhang B, Zhang L, Wang Z, Gao A. Achievement of High Strength and Ductility in Al–Si–Cu–Mg Alloys by Intermediate Phase Optimization in As-Cast and Heat Treatment Conditions. Materials. 2020; 13(3):647. https://doi.org/10.3390/ma13030647
Chicago/Turabian StyleZhang, Bingrong, Lingkun Zhang, Zhiming Wang, and Anjiang Gao. 2020. "Achievement of High Strength and Ductility in Al–Si–Cu–Mg Alloys by Intermediate Phase Optimization in As-Cast and Heat Treatment Conditions" Materials 13, no. 3: 647. https://doi.org/10.3390/ma13030647