Conference article

The Effect of A Boron Oxide Layer on Hydrogen Production by Boron Hydrolysis

Tareq Abu Hamed
The Dead Sea and Arava Science Center, Tamar Regional Council, Israel \ Arava Institute for Environmental Studies, Hevel Eilot, Israel

Bara Wahbeh
Ben-Gurion University of the Negev, Sde-Boqer, Israel

Roni Kasher
Ben-Gurion University of the Negev, Sde-Boqer, Israel

M. Imroz Sohel
Scion, Te Papa Tipu Innovation Park, Rotorua, New Zealand

Mathieu Sellier
Department of Mechanical Engineering, University of Canterbury, Christchurch, New Zealand

Susan Krumdieck
Department of Mechanical Engineering, University of Canterbury, Christchurch, New Zealand

Yingjian Li
College of Chemistry & Chemical Engineering, Shenzhen University, Shenzhen, China

Qi Qiu
College of Chemistry & Chemical Engineering, Shenzhen University, Shenzhen, China

Xiangzhu He
Hunan Energy Conservation Center, Changsha, China

Jiezhi Li
Ecole centrale de Lyon, Lyon, France

Ilknur Erlalelitepe
Izmir Institute of Technology, Department of Architecture, Izmir, Turkey

Kenan Evren Ekmen
Izmir Institute of Technology, Energy Engineering Program, Izmir, Turkey

Cihan Turhan
Izmir Institute of Technology, Energy Engineering Program, Izmir, Turkey

Manolya Akdemir
Izmir Institute of Technology, Energy Engineering Program, Izmir, Turkey

Gülden Akkurt Gökcen
Izmir Institute of Technology, Department of Mechanical Engineering, Izmir, Turkey

Tugce Kazanasmaz
Izmir Institute of Technology, Department of Architecture, Izmir, Turkey

Gregorio Iglesias
University of Santiago de Compostela, Spain

Hernán Fernándes
University of Santiago de Compostela, Spain

Rodrigo Carballo
University of Santiago de Compostela, Spain

Alberte Castro
University of Santiago de Compostela, Spain

Francisco Taveira-Pinto
Faculty of Engineering, University of Porto, Portugal

Alan C. Brent
Centre for Renewable and Sustainable Energy Studies, School of Public Leadership, Stellenbosch University, Stellenbosch, South Africa

Wildri D. Peach
Sustainable Energy Futures, Natural Resources and the Environment, Council for Scientific and Industrial Research, Pretoria, South Africa \ Graduate School of Technology Management, University of Pretoria, Pretoria, South Africa

William Stafford
Sustainable Energy Futures, Natural Resources and the Environment, Council for Scientific and Industrial Research, Pretoria, South Africa

Ruben Laleman
Ghent University, Faculty of Economics and Business administration, Ghent, Belgium

Johan Albrecht
Ghent University, Faculty of Economics and Business administration, Ghent, Belgium

Oleg P. Dimitriev
V.Lashkaryov Institute of Semiconductor Physics, Kiev, Ukraine

P. Zhang
Institute of Refrigeration and Cryogenics, Shanghai Jiao Tong University, China

L. Xia
Institute of Refrigeration and Cryogenics, Shanghai Jiao Tong University, China

R. Z. Wang
Institute of Refrigeration and Cryogenics, Shanghai Jiao Tong University, China

Mehdi Reiszadeh
Islamic Azad University, Shahreza Branch, Shahreza, Iran

Sadegh Motahar
Department of Mechanical Engineering, Isfahan University of Technology, Isfahan, Iran

Daniel Wright
Aston University, Birmingham, UK

Prasanta Dey
Aston University, Birmingham, UK

John Brammer
Aston University, Birmingham, UK

Phil Hunt
Enco Energy Limited, UK

Guilherme A. Caxaria
Electrical and Computer Engineering Department, Instituto Superior Tåcnico, Technical University of Lisbon, Lisbon, Portugal

Duarte de Mesquita e Sousa
Electrical and Computer Engineering Department and CIE3, Instituto Superior Tåcnico, Technical University of Lisbon, Lisbon, Portugal

Helena M. Ramos
Civil Engineering Department and CEHIDRO, Instituto Superior Tåcnico, Technical University of Lisbon, Lisbon, Portugal

X. B. Lastra Bravo
University of Almería, Almería, Spain

T. Steenberghen
Katholieke Universiteit Leuven, Leuven, Belgium

A. Tolón Becerra
University of Almería, Almería, Spain

B. Debecker
Katholieke Universiteit Leuven, Leuven, Belgium

Göran Finnveden
KTH Royal Institute of Technology , Sweden

Jonas Åkerman
KTH Royal Institute of Technology , Sweden

Alexis de Laborderie
Transånergie, Ecully, France

Clément Puech
Transånergie, Ecully, France

Nadine Adra
Transånergie, Ecully, France

Isabelle Blanc
MINES ParisTech, Sophia Antipolis, France

Didier Beloin-Saint-Pierre
MINES ParisTech, Sophia Antipolis, France

Pierryves Padey
MINES ParisTech, Sophia Antipolis, France

Jérôme Payet
Cycleco, Ambårieu, France

Marion Sie
Cycleco, Ambårieu, France

Philippe Jacquin
PHK Consultants, Ecully, France

Download articlehttp://dx.doi.org/10.3384/ecp110571143

Published in: World Renewable Energy Congress - Sweden; 8-13 May; 2011; Linköping; Sweden

Linköping Electronic Conference Proceedings 57:2, p. 1143-1149

Show more +

Published: 2011-11-03

ISBN: 978-91-7393-070-3

ISSN: 1650-3686 (print), 1650-3740 (online)

Abstract

Hydrolysis of boron is investigated as a part of a boron/boron oxide solar; water-splitting; thermochemical cycle. Boron was hydrolysed and boron oxide was gasified with steam in a tubular reactor. The influence of the reactor temperature and time on hydrogen conversion was measured at furnace set point temperatures of 873; 973 and 1073 K. The hydrogen production rate was measured by inline gas chromatography. The products were analyzed by X-ray diffraction. The average hydrogen production efficiency of 92% was obtained for both 973 and 1073 K. The formation of a boric acid layer on the reactor walls was attributed to the gasification of the boron oxide. The X-ray analysis shows 100% conversion of the boron to boron oxide and boric acid.

Keywords

Hydrogen; thermochemical cycle; boron; oxide layer removal

References

[1] G. Karim; Hydrogen as a spark ignition engine fuel; International Journal of Hydrogen Energy 28; 2003; pp. 569-577. doi: 10.1016/S0360-3199(02)00150-7.

[2] M. Epstein; Solar induced solid fuels for transportation; Proceedings of the 12th International Symposium on Solar Power and Chemical Energy System; 2004; Oaxaca; Mexico; paper No. 302.

[3] T. Abu Hamed; J. Karni; M. Epstein; The use of boron for thermochemical storage and distribution of solar energy; Solar Energy 81; 2007; pp. 93-101. doi: 10.1016/j.solener.2006.06.012.

[4] C. L. Yeh; K. K. Kio; Ignition and combustion of boron particles; Progress in Energy and Combustion Science 22; 1996; pp. 511-541. doi: 10.1016/S0360-1285(96)00012-3.

[5] C. C. Li; F. A. Williams; Ignition and combustion of boron particles in Combustion of boron-based solid propellants and solid fuels; Kuo; K. K.; and Pein; R.; Eds.; Begell House Publishing Co. and CRC Press; Inc.; 1993; pp. 248–271.

[6] S. C. Li; F. A. Williams; Ignition and combustion of boron in wet and dry atmospheres; Proceeding of the 23rd Symposium on Combustion; 1990; pp. 1147–1154.

[7] M. K. King; Boron ignition and combustion in air-augmented rocket afterburners; Combustion Science and Technology; 1972; pp. 155–164. doi: 10.1080/00102207208952516.

[8] W. Zhou; R. A. Yetter; F. L. Dryer;H. Rabitz; R. C. Brown; C. E. Kolb. Comprehensive physical and numerical model of boron particle ignition. Proceeding of the 26th International Symposium on Combustion; 1996 pp. 1909–1917.

[9] R. C. Brown; C. E. Kolb; S. Y. Cho; R. A. Yetter; H. Rabitz; F. L. Dryer; Kinetic model for hydrocarbon-assisted particulate boron combustion; International Journal of Chemical Kinetics 26; 1994; pp. 319–332. doi: 10.1002/kin.550260302.

[10] J. Smolanoff; M. Sowa–Resat; A. Lapicki; L. Hanley; S. Ruatta; P. Hintz; S. L. Anderson; Kinetic parameters for heterogeneous boron combustion reactions via the cluster beam approach; Combustion and Flame 105; 1996; pp. 68–79. doi: 10.1016/0010-2180(95)00155-7.

[11] H. Krier; R. L. Burton; S. R. Pirman; M. J. Spalding; Shock initiation of crystalline boron in oxygen and fluorine compounds. Proceeding of the 30th American Institute of Aereonautics and Astronautics Thermophysics Conference; 1995; paper No. 2095-2120. doi: 10.2514/6.1995-2120.

[12] Y. A. Vovchuk; A. N. Zolotko; L. A. Klyachko; D. I. Polishchuk; V. G. Shevchuk; Gasification of boron oxide; Fizika Goreniya i Vzryva 10; 1972; pp. 615-618.

[13] R. Sontgen; A. Freidrich; A simple model of the oxidation kinetics of boron in a medium containing water vapor; in Combustion of Boron Based Propellant and Solid Fuels; K. K. Kuo and R. Pein; Eds.; Begell House Publishing Co. and CRC Press; Inc.; 1993; pp. 211-217.

[14] V. Rosenband; A. Gany; Y.M. Timnat; Magnesium and boron combustion in hot steam atmosphere; Defense Science Journal 48; 1998; pp. 309-315.

[15] I. Vishnevetsky; M. Epstein; T. Abu-Hamed; J. Karni; Boron hydrolysis at moderate temperatures – First step to solar fuel cycle for transportation; Journal of Solar Energy Engineering 130; 2008; pp. 14506-14511. doi: 10.1115/1.2807215.

[16] R. J. Weiss; H. C. Ly; K. Wegner; S. E. Pratsinis; A. Steinfeld; H2 production by Zn hydrolysis in a hot-wall aerosol reactor; AIChE Journal 51; 2005; pp. 1966–1970. doi: 10.1002/aic.10437.

Citations in Crossref