Skip to main content
Log in

Carbon Black as a Support in Palladium Catalysts for Hydrogenation of Organic Compounds

  • Published:
Solid Fuel Chemistry Aims and scope Submit manuscript

Abstract

The possibility of using carbon black (CB) as a support of palladium catalysts for the selective hydrogenation of organic compounds is considered. The advantages of Pd/CB catalysts are demonstrated by examples of liquid-phase hydrogenation of aromatic aldehydes and nitro compounds. The combination of high catalytic parameters (activity, selectivity, and stability) achieved by these catalysts in hydrogenation reactions indicates that they are promising for use on an industrial scale, in particular in the syntheses of fine chemicals.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Stiles, A.B., Catalyst Supports and Supported Catalysts: Theoretical and Applied Concepts, Boston: Butterworths, 1987, ch. 5.

    Google Scholar 

  2. Serp, P. and Machado, B., Nanostructured Carbon Materials for Catalysis, Cambridge: The Royal Society of Chemistry, 2015, ch. 1. https://doi.org/10.1039/9781782622567-00001

    Book  Google Scholar 

  3. Rase, H.F., Handbook of Commercial Catalysts: Heterogeneous Catalysts, Boca Raton, FL: CRC Press, 2000, ch. 12. https://doi.org/10.1201/b21367

    Book  Google Scholar 

  4. Oosthuizen, R.S. and Nyamori, V.O., Platinum Metals Rev., 2011, vol. 55, no. 3, p. 154. https://doi.org/10.1595/147106711X577274

    Article  CAS  Google Scholar 

  5. Nishimura, S., Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis, New York: Wiley, 2001, ch. 1.

    Google Scholar 

  6. Likholobov, V.A., Surovikin, V.F., Plaksin, G.V., Tse-khanovich, M.S., Surovikin, Yu.V., and Baklanova, O.N., Catal. Ind., 2009, vol. 1, no 1, p. 11. https://doi.org/10.1134/S2070050409010024

    Article  Google Scholar 

  7. Zhu, J., Holmen, A., and Chen, D., ChemCatChem, 2013, vol. 5, no. 2, p. 378. https://doi.org/10.1002/cctc.201200471

  8. van Vaerenbergh, B., Lauwaert, J., Vermeir, P., De Clercq, J., and Thybaut, J.W., Adv. Catal., 2019, vol. 65, p. 1. https://doi.org/10.1016/bs.acat.2019.10.001

    Article  CAS  Google Scholar 

  9. Gyul'misaryan, T.G. and Levenberg, I.P., Tekhnol. Nefti Gaza, 2018, no. 3, p. 3.

  10. Arunajatesan, V., Chen, B., Möbus, K., Ostgard, D.J., Tacke, T., and Wolf, D., Carbon Materials for Catalysis, Hoboken: Wiley, 2009, p. 535. https://doi.org/10.1002/9780470403709.ch15

    Book  Google Scholar 

  11. Voll, M. and Kleinschmit, P., Ullmann’s Encyclopedia of Industrial Chemistry, Weinheim: Wiley-VCH, 2012. https://doi.org/10.1002/14356007.n05_n05

    Book  Google Scholar 

  12. Suh, D.J., Park, T.-J., and Ihm, S.-K., Ind. Eng. Chem. Res., 1992, vol. 31, no. 8, p. 1849. https://doi.org/10.1021/ie00008a003

    Article  CAS  Google Scholar 

  13. Harada, T., Ikeda, S., Miyazaki, M., Sakata, T., Mori, H., and Matsumura, M., J. Mol. Catal. A: Chem., 2007, vol. 268, nos. 1–2, p. 59. https://doi.org/10.1016/j.molcata.2006.12.010

    Article  CAS  Google Scholar 

  14. Yakukhnov, S.A., Pentsak, E.O., Galkin, K.I., Mironenko, R.M., Drozdov, V.A., Likholobov, V.A., and Ananikov, V.P., ChemCatChem., 2018, vol. 10, no. 8, p. 1869. https://doi.org/10.1002/cctc.201700738

    Article  CAS  Google Scholar 

  15. Mironenko, R.M., Belskaya, O.B., Gulyaeva, T.I., Nizovskii, A.I., Kalinkin, A.V., Bukhtiyarov, V.I., Lavrenov, A.V., and Likholobov, V.A., Catal. Today, 2015, vol. 249, p. 145. https://doi.org/10.1016/j.cattod.2014.10.037

    Article  CAS  Google Scholar 

  16. Mironenko, R.M., Bel’skaya, O.B., Lavrenov, A.V., and Likholobov, V.A., Khim. Interesakh Ustoich. Razvit., 2015, vol. 23, no. 6, p. 645. https://doi.org/10.15372/KhUR20150603

    Article  CAS  Google Scholar 

  17. Mironenko, R.M. and Belskaya, O.B., AIP Conf. Proc., 2019, vol. 2141, no. 1, p. 020010. https://doi.org/10.1063/1.5122029

    Article  CAS  Google Scholar 

  18. Belskaya, O.B., Mironenko, R.M., and Likholobov V.A., Theor. Experim. Chem., 2013, vol. 48, no. 6, p. 381. https://doi.org/10.1007/s11237-013-9285-y

    Article  CAS  Google Scholar 

  19. Mironenko, R.M., Belskaya, O.B., Gulyaeva, T.I., Trenikhin, M.V., Nizovskii, A.I., Kalinkin, A.V., Bukhtiyarov, V.I., Lavrenov, A.V., and Likholobov, V.A., Catal. Today, 2017, vol. 279, p. 2. https://doi.org/10.1016/j.cattod.2016.07.022

    Article  CAS  Google Scholar 

  20. Mironenko, R.M., Belskaya, O.B., Gulyaeva, T.I., Trenikhin, M.V., and Likholobov, V.A., Catal. Commun., 2018, vol. 114, p. 46. https://doi.org/10.1016/j.catcom.2018.06.002

    Article  CAS  Google Scholar 

  21. Mironenko, R.M., Belskaya, O.B., Stepanova, L.N., Gulyaeva, T.I., Trenikhin, M.V., and Likholobov, V.A., Catal. Lett., 2020, vol. 150, no. 3, p. 888. https://doi.org/10.1007/s10562-019-02974-6

    Article  CAS  Google Scholar 

  22. Mironenko, R.M., Belskaya, O.B., and Likholobov, V.A., Russ. J. Gen. Chem., 2020, vol. 90, no. 3, p. 532. https://doi.org/10.1134/S1070363220030299

    Article  CAS  Google Scholar 

  23. Mironenko, R.M., Belskaya, O.B., and Likholobov, V.A., Catal. Today, 2020, vol. 357, p. 152.https://doi.org/10.1016/j.cattod.2019.03.023

Download references

Funding

The work was carried out in accordance with the State Program of Boreskov Institute of Catalysis (project AAAA-A19-119061490024-3).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to R. M. Mironenko, O. B. Belskaya or V. A. Likholobov.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mironenko, R.M., Belskaya, O.B. & Likholobov, V.A. Carbon Black as a Support in Palladium Catalysts for Hydrogenation of Organic Compounds. Solid Fuel Chem. 54, 362–367 (2020). https://doi.org/10.3103/S0361521920060087

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S0361521920060087

Keywords:

Navigation