Abstract
Vectorial photoinduced electron transfer was studied in Langmuir-Blodgett films. The monolayers of polythiophene and phthalocyanine were used as secondary electron donors in multilayers together with the monolayer of porphyrin-fullerene donor-acceptor dyad molecules mixed with octadecylamine (1:9). Simultaneous utilization of all the three compounds in the preparation of three-layer samples allowed us to widen the range of the visible light absorption by the structure. The relative sensitivity of the sample to the excitation laser light increased by about 350 times compared with that of a dyad monolayer.
Similar content being viewed by others
References
H. Imahori, Y. Sakata, J. Org. Chem. 10, 2445 (1999).
H. Imahori, N. V. Tkachenko, V. Vehmanen, et al., J. Phys. Chem. A 105, 1750 (2001).
F. D’souza, G. R. Deviprasad, M. E. Zandler, et al., J. Phys. Chem. B 106, 4952 (2002).
V. Tkachenko, H. Lemmetyinen, J. Sonoda, et al., J. Phys. Chem. A 107, 8834 (2003).
Langmuir-Blodgett Films, Ed. by G. Roberts (Plenum Press, N. Y., 1990).
A. Marcus, Rev. Mod. Phys. 65, 599 (1993).
H. Imahori and Y. Sakata, Adv. Mater. 9, 537 (1997).
N. V. Tkachenko, E. Vuorimaa, T. Kesti, et al., J. Phys. Chem. B 104, 6371 (2000).
M. Ikonen, A. Sharonov, N. Tkachenko, and H. Lemmetyinen, Adv. Mater. Opt. Electron. 2, 115 (1993).
A. S. Alekseev, N. V. Tkachenko, A. Y. Tauber, et al., Chem. Phys. 275, 243 (2000).
A. S. Alekseev, I. N. Domnin, N. V. Tkachenko, et al., Kratkie Soobsheniya po Fizike FIAN, No. 5, 27 (2003) [Bulletin of the Lebedev Physics Institute, No. 5, 22 (2003)].
A. S. Alekseev, I. N. Domnin, N. V. Tkachenko, et al., Russ. J. Phys. Chem. 78, 453 (2004).
A. Efimov, P. Vainiotalo, N. V. Tkachenko, and H. Lemmetyinen, J. Porph. Phthaloc. 7, 610 (2003).
Author information
Authors and Affiliations
Additional information
Original Russian Text © A.S. Alekseev, A.V. Efimov, N.V. Tkachenko, P.A. Saltykov, H. Lemmetyinen, 2008, published in Kratkie Soobshcheniya po Fizike, 2008, Vol. 35, No. 4, pp. 36–42.
About this article
Cite this article
Alekseev, A.S., Efimov, A.V., Tkachenko, N.V. et al. Interlayer photoinduced electron transfer in Langmuir-Blodgett films based on porphyrin and phthalocyanine derivatives. Bull. Lebedev Phys. Inst. 35, 118–121 (2008). https://doi.org/10.3103/S1068335608040064
Received:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1068335608040064