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Thermodynamic characteristics of the Pb-Bi alloys in the KCl-PbCl2 melt

  • Metallurgy of Nonferrous Metals
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Abstract

The thermodynamic properties of the Pb-Bi alloys containing from 1.5 to 95 mol % Pb are investigated in a molten mixture of potassium and lead chlorides in a temperature range of 723–873 K by measuring the equilibrium values of the electromotive force. The partial and integral thermodynamic characteristics of the system are calculated, and its small negative deviations from ideality are established.

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References

  1. Hultgren, R., Orr, R., Anderson, P., and Kellsy, K., Selected Values of Thermodynamic Properties of Metals and Alloys, New York-London, 1963.

  2. Mikula, A., Monatsh. Chem., 1986, vol. 117, no. 12, p. 1379.

    Article  CAS  Google Scholar 

  3. Moser, Z., Z. Metallkd., 1973, vol. 64, no. 1, p. 40.

    CAS  Google Scholar 

  4. Mehrotra, G.M., Frohberg, M.G., and Kapoor, M.L., Z. Metallkd., 1976, vol. 67, no. 3, p. 186.

    CAS  Google Scholar 

  5. Prasad, R., Venugopal, V., and Sood, D.D., J. Chem. Thermodyn., 1977, vol. 9, no. 6, p. 593.

    Article  CAS  Google Scholar 

  6. Prasad, R., Venugopal, V., and Sood, D.D., J. Chem. Thermodyn., no. 8, p. 765.

  7. Morachevskii, A.G., Voronin, G.F., Geiderikh, V.A., and Kutsenok, I.B., Elektrokhimicheskie metody issledovaniya v termodinamike metallicheskikh sistem (Electrochemical Methods of Investigation in Thermodynamic of Metal Systems), Moscow: Akademkniga, 2003.

    Google Scholar 

  8. Glazov, V.M. and Pavlova, L.M., Khimicheskaya termodinamika i fazovye ravnovesiya (Chemical Thermodynamics and Phase Equilibria), Moscow: Metallurgiya, 1981.

    Google Scholar 

  9. Zaikov, Yu.P., Arkhipov, P.A., Plekhanov, K.A., et al., Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 2007, no. 2, p. 11 [Russ. J. Non-Fer. Met. (Engl. Transl.), 2007, vol. 48, no. 2, p. 92.].

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Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Division, Russian Academy of Sciences, ul. Akademicheskaya 22, Yekaterinburg, 620990, Russia

    Yu. R. Khalimullina, P. A. Arkhipov, A. S. Kholkina & N. G. Molchanova

  2. OAO Uralelektromed’, ul. Lenina 1, Verkhnyaya Pyshma, Sverdlovsk oblast, 624091, Russia

    Yu. P. Zaikov & V. V. Ashikhin

  3. OOO UGMK-Kholding, ul. Lenina 1, Verkhnyaya Pyshma, Sverdlovsk oblast, 624091, Russia

    G. V. Skopov

Authors
  1. Yu. R. Khalimullina
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  2. Yu. P. Zaikov
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  3. P. A. Arkhipov
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  4. V. V. Ashikhin
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  5. G. V. Skopov
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  6. A. S. Kholkina
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  7. N. G. Molchanova
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Corresponding author

Correspondence to Yu. R. Khalimullina.

Additional information

Original Russian Text © Yu.R. Khalimullina, Yu.P. Zaikov, P.A. Arkhipov, V.V. Ashikhin, G.V. Skopov, A.S. Kholkina, N.G. Molchanova, 2011, published in Izvestiya VUZ. Tsvetnaya Metallurgiya, 2011, No. 3, pp. 3–9.

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Khalimullina, Y.R., Zaikov, Y.P., Arkhipov, P.A. et al. Thermodynamic characteristics of the Pb-Bi alloys in the KCl-PbCl2 melt. Russ. J. Non-ferrous Metals 52, 197–204 (2011). https://doi.org/10.3103/S1067821211030126

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  • DOI: https://doi.org/10.3103/S1067821211030126

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