Abstract
Mössbauer spectroscopy and X-ray powder diffractometry (XRD) phase analysis are used to study mixed vanadates with the composition Al x Fe3 − x V3O12, where x is 0, 0.3, 1.0, 1.5, 2.0, 2.7, and 3.0. Mössbauer spectroscopy is used to study the distribution of trivalent cations over different crystallographic positions. It is shown that the distribution of aluminum atoms differs from those expected from statistic and thermodynamic models.
Similar content being viewed by others
References
Häggblad, R., Wagner, J.B., Hansen, S., and Andersson, A., J. Catal., 2008, issue 2, vol. 258, pp. 345–355.
Gabr, R.M., El-Awad, A.M., and Girgis, M.M., Mater. Chem. Phys., 1991, vol. 30, pp. 69–75.
Wei Jin, Baitao Dong, Wen Chen, et al., Sensors Actuators B, 2010, vol. 145, pp. 211–215
Dedushenko, S.K., Perfiliev, Yu.D., Tcheboukov, D.E., et al., Mendeleev Commun., 1999, vol. 5, pp. 211–212.
Burzo, E. and Stänescu, L., Solid State Commun., 1976, vol. 20, pp. 653–655.
Fotiev, A.A., Cheshnitskii, S.M., and Surat, L.L., Russ. J. Inorg. Chem., 1983, vol. 28, p. 560.
Oka, Y., Yao, T., Yamamoto, N., et al., J. Solid State Chem., 1996, vol. 123, pp. 54–59.
Robertson, B. and Kostiner, E., J. Solid State Chem., 1972, vol. 4, pp. 29–37.
Li Zhaoa, Martin, P.Y., Wub, Kuo-Wei Yeha, and Maw-Kuen Wu, Solid State Commun., 2011, vol. 151, pp. 1728–1732.
Levinson, L.M. and Wanklyn, B.M., J. Solid State Chem., 1971, vol. 3, pp. 131–133.
Truflandier, L., Paris, M., Payen, C., and Boucher, F., J. Phys. Chem. Lett. B, 2006, vol. 110, no. 43, pp. 21403–21407.
Hansen, M.R., Madsen, G.K.H., Jakobsen, H.J., and Skibsted, J., J. Phys. Chem. B, 2006, vol. 110, pp. 5975–5983.
Arisi, E., Sa’nchez, S.A.P., Leccabue, F., et al., J. Mater. Sci., 2004, vol. 39, pp. 2107–2111.
Wells, A.F., Structural Inorganic Chemistry, Clarendon Press, 1962, vol. 2.
Pankratov, D.A. and Kiselev, Y.M., Russ. J. Inorg. Chem., 2009, vol. 54, no. 9, pp. 1451–1454.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © D.A. Pankratov, A.I. Yurev, 2013, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2013, Vol. 77, No. 6, pp. 834–840.
About this article
Cite this article
Pankratov, D.A., Yurev, A.I. Mössbauer diagnostics of the isomorphic substitution of iron for aluminum in triclinic iron vanadate. Bull. Russ. Acad. Sci. Phys. 77, 759–764 (2013). https://doi.org/10.3103/S1062873813060221
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1062873813060221