Skip to main content
SpringerLink
Log in

Cast NiAl/Ni20Al3B6 composites by centrifugal SHS

  • Published:
International Journal of Self-Propagating High-Temperature Synthesis Aims and scope Submit manuscript

Abstract

Cast NiAl/Ni20Al3B6 composites containing 2.3–3.5 wt % B have been prepared by centrifugal SHS for the first time. The composite materials comprised of a solid-solution matrix based on NiAl with inclusions of Ni20Al3B6 and complex boride (Mo, Cr)B. Best results were achieved at centrifugal accelerations 150–200 g in open air. Cast materials based on NiAl and τ-borides seem promising for use in turbine power units.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Superalloys II, Chester, Y. and Sims, C.Y., Eds., New York: Wiley, 1987.

    Google Scholar 

  2. Noebe, R.D., Bowman, R.R., and Nathal, M.V., in Physical Metallurgy and Processing of Intermetallic Compounds, Stoloff, N.S. and Sikka, V.K, Eds., New York: Chapman and Hall, 1996, pp. 212–296.

  3. Liu, E., Jia, J., Bai, Y., Wang, W., and Gao, Y., Study on preparation and mechanical properties of nanocrystalline NiAl intermetallic, Mater. Design, 2014, vol. 53, pp. 596–601.

    Article  Google Scholar 

  4. Povarova, K.B., Filin, S.A., and Maslenkov, S.B., Phase equilibrium in Ni-Al-Me systems (Me = Co, Fe, Mn, CuO) at 900 and 1100°C, Metally, 1993, no. 10, pp. 191–205.

    Google Scholar 

  5. Sheng, L.Y., Guo, J.T., Tian, Y.X., Zhou, L.Z., and Ye, H.Q., Microstructure and mechanical properties of rapidly solidified NiAl-Cr(Mo) eutectic alloy doped with trace Dy, J. Alloys Comp., 2009, vol. 475, nos. 1–2, pp. 730–734.

    Article  Google Scholar 

  6. Gao, Q., Guo, J.T., Huai, K.W., Microstructure and phase solubility extension in injection cast NiAl-28Cr-5.7Mo-0.3Hf alloy, Intermetallics, 2007, vol. 15, nos. 5–6, pp. 734–737.

    Article  Google Scholar 

  7. Li, H.T., Wang, Q., He, J.C., Guo, J.T., and Ye, H.Q., β-Ti(M) solid solution formation and its thermal stability in a NiAl-Cr(Mo)-(Hf,Ti) nearly eutectic alloy, Mater. Charact., 2008, vol. 59, no. 10, pp. 1395–1399.

    Article  Google Scholar 

  8. Frommeyer, G., Rablbauer, R., and Schäfer, H.J., Elastic properties of B2-ordered NiAl and NiAl-X (Cr, Mo, W) alloys, Intermetallics, 2010, vol. 18, no. 3, pp. 299–305.

    Article  Google Scholar 

  9. Deges, J., Schneider, A., Fischer, R., and Frommeyer, G., APFIM investigations on quasi-binary hypoeutectic NiAl-Re alloys, Mater. Sci. Eng. A, 2003, vol. 353, nos. 1–2, pp. 80–86.

    Article  Google Scholar 

  10. Bei, H. and George, E.P., Microstructures and mechanical properties of a directionally solidified NiAl-Mo eutectic alloy, Acta Mater., 2005, vol. 53, no. 1, pp. 69–77.

    Article  Google Scholar 

  11. Milenkovic, S., Schneider, A., and Frommeyer, G., Constitutional and microstructural investigation of the pseudobinary NiAl-W system, Intermetallics, 2011, vol. 19, no. 3, pp. 342–349.

    Article  Google Scholar 

  12. Nikolaev, A.G., Levashov, E.A., Povarova, K.B., Titova, T.F., and Fomina, O.N., Heat resistance of SHS-produced NiAl: Influence of alloying with TiC, NbC, and TiN, Fiz. Khim. Obrab. Mater., 1998, no. 3, pp. 78–81.

    Google Scholar 

  13. Povarova, K.B., Nikolaev, A.G., and Levashov, E.A., NiAl-Y2O3 and NiAl-TiN composites by SHS method, Fiz. Khim. Obrab. Mater., 1994, nos. 4–5, pp. 135–143.

    Google Scholar 

  14. Campbell, C. and Kattner, U., A thermodynamic assessment of the Ni-Al-B system, J. Phase Equil., 1999, vol. 20, no. 5, pp. 485–496.

    Article  Google Scholar 

  15. Sigworth, G.K., The grain refinement of aluminum and phase relationships in the Al-Ti-B system, Metall. Trans. A, 1984, vol. 15, no. 2, pp. 277–282.

    Article  Google Scholar 

  16. Kotzott, D., Ade, M., and Hillebrecht, H., Single crystal studies on boron-rich t-borides Ni3−x MxB6 (M = Zn, Ga, In, Sn, Ir): The surprising occurrence of B4 tetraheda as a normal case, J. Solid State Chem., 2010, vol. 183, no. 10, pp. 2281–2289.

    Article  Google Scholar 

  17. Hillebrecht, H. and Ade, M., B4 tetrahedra for aluminum atoms: A surprising substitution in t-borides Ni20Al3B6 and Ni20AlB14, Angew. Chem. Int. Ed., 1998, vol. 37, no. 7, pp. 935–938.

    Article  Google Scholar 

  18. Ade, M., Kotzott, D., and Hillebrecht, H., Synthesis and crystal structures of the new metal-richternary borides Ni12AlB8, Ni12GaB8, and Ni10.6Ga0.4B6: Examples for the first B5 zig-zag chain fragment, J. Solid State Chem., 2010, vol. 183, no. 8, pp. 1790–1797.

    Article  Google Scholar 

  19. Yukhvid, V.I., Sanin, V.N., and Merzhanov, A.G., The influence of high artificial gravity on SHS processes, in Processing by Centrifugation, Regel L.L. and Wilcox, W.R., Eds., Amsterdam: Kluwer Academic, 2001, pp. 185–200.

    Chapter  Google Scholar 

  20. Sanin, V., Andreev, D., Ikornikov, D., and Yukhvid. V., Cast intermetallic alloys and related composites by combined centrifugal casting SHS process, Open J. Met., 2013, no. 3, pp. 12–24 (DOI: 10.4236/ojmetal.2013.32A2003).

    Google Scholar 

  21. Sanin, V., Andreev, D., Ikornikov, D., and Yukhvid, V., Cast intermetallic alloys by SHS under high gravity, Acta Phys. Polonica A, 2011, vol. 120, no. 2, pp. 331–335.

    Google Scholar 

  22. Sanin, V.N., Ikornikov, D.M., Sachkova, N.V., and Yukhvid, V.I., Complex boride metal-matrix composites by SHS under high gravity, Int. J. Self-Propag. High-Temp. Synth., 2014, vol. 23, no. 3, pp. 151–160.

    Article  Google Scholar 

  23. Liu, C.T. and Pope, D.P., Ni3Al and its alloys, in Intermetallic Compounds Practice, Westbrook, J.H. and Fleischer, R.L., Eds., Chichester: Wiley, 1995, pp. 17–51.

    Google Scholar 

  24. Chiba, A. and Hanada, S., Ductilization of Ni3Al by alloying with substitutional elements, J. Mater. Sci. Technol., 1993, vol. 9, no. 9, pp. 391–399.

    Google Scholar 

  25. Wen. Y., Sun, J., and Huang, J., First-principles study of stacking fault energies in Ni3Al intermetallic alloys, Trans. Nonferrous Met. Soc. China, 2012, vol. 22, no. 3, pp. 661–664.

    Article  Google Scholar 

  26. Oryshich, I.V., High-temperature salt and gas corrosion of refractory alloys based on nickel, J. Mater. Sci., 2000, vol. 36, no. 1, pp. 104–110.

    Article  Google Scholar 

  27. Bloshenko, V.N., Bokii, V.A., and Borovinskaya, I.P., Regularities and mechanism for self-cleaning from impurity oxygen in obtaining molybdenum disilicide by SHS method, Combust. Explos. Shock Waves, 1985, vol. 21, no. 2, pp. 202–208.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, Moscow, 142432, Russia

    V. N. Sanin, D. M. Ikornikov, D. E. Andreev & V. I. Yukhvid

  2. National Technological Research University MISiS, Moscow, Russia

    E. A. Levashov & Yu. S. Pogozhev

Authors
  1. V. N. Sanin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. M. Ikornikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. E. Andreev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. I. Yukhvid
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. A. Levashov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Yu. S. Pogozhev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. N. Sanin.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sanin, V.N., Ikornikov, D.M., Andreev, D.E. et al. Cast NiAl/Ni20Al3B6 composites by centrifugal SHS. Int. J Self-Propag. High-Temp. Synth. 23, 232–239 (2014). https://doi.org/10.3103/S1061386214040098

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1061386214040098

Keywords

Search

Navigation