Abstract
The overview is focused on methods for the processing of kinetic curves (with and without models). The paper demonstrates that the kinetics of thermochemical conversion of solid fuels can be described by a great number of kinetic processing methods, which lead to inconsistent estimates of kinetic coefficients. They give a rather simple approximation of experimental thermogravimetric curves. However, the kinetic triplet to be determined (activation energy, order of reaction, and preexponential factor) depends on the conditions of thermoanalytical studies and (to a greater extent) on the reactivity of the test fuels.
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Di Blasi, C., Prog. Energy Combust. Sci., 2008, vol. 34, p. 47.
Biagini, E., Fantel, A., and Tognotti, L., Thermochim. Acta, 2008, vol. 472, p. 55.
De Micco, G., Nasjleti, A., and Bohe, A.E., Fuel, 2012, vol. 95, p. 537.
Fermoso, J., Arias, B., Pevida, C., Plaza, M.G., Rubiera, F., and Pis, J.J., Thermal Anal. Calorimetr., 2008, vol. 91, no. 3, p. 779.
Fang, X., Jia, L., and Yin, L., Biom. Bioenerg., 2013, vol. 48, p. 43.
Flammersheim, H.J. and Opfermann, J., Thermochim. Acta, 1999, vol. 337, p. 141.
Opfermann, J., Kaiserberger, E., and Flammersheim, H.J., Thermochim. Acta, 2002, vol. 391, p. 119.
House, J.E., Principles of Chemical Kinetics, London Elsevier, 2007.
Sestak, J., Thermochim. Acta, 2015, vol. 611, p. 26.
Moukhina, E., Thermal Anal. Calorimetr., 2012, vol. 109, no. 3, p. 1203.
Gallagher, P.K., Techniques and Applications, Amsterdam Elsevier, 2008.
Ozawa, T., Thermal Anal. Calorimetr., 2000, vol. 60, p. 887.
ASTM 698-05: Annual Book of ASTM Standards, West Conshohocken, PA.: ASTM International, 2005, vol. 14.02, p. 226.
Kissinger, H.E., Anal. Chem., 1957, vol. 29, no. 11, p. 1703.
Friedman, H.L., J. Polymer Sci.: Polymer Lett., 1969, vol. 7, no. 1, p. 41.
Flynn, J.H., Thermochim. Acta, 1997, vol. 300, p. 83.
Doyle, C.D., J. Appl. Pol. Sci., 1962, vol. 5, p. 285.
Koga, N., Thermal Anal. Calorimetr., 2013, vol. 113, p. 1527.
Flynn, J.H. and Wall, L.A., Polymer Lett., 1966, vol. 4, no. 5, p. 323.
Coats, A.W. and Redfern, J.P., Nature, 1964, vol. 201, p. 68.
Coats, A.W. and Redfern, J.P., Polymer Sci., 1965, vol. 3, p. 917.
Fisher, P.E., Jou, C.S., and Gokalgandchi, S.S., Industr. Eng. Chem. Res., 1987, vol. 26, p. 1037.
White, J.E., Cattalo, W.J., and Legendre, B.L., Anal. Appl. Pyr., 2011, vol. 91, p. 1.
Budrugeac, P., Petre, A.L., and Segal, E., Thermal Anal. Calorimetr., 1997, vol. 56, p. 123.
Senum, G.I. and Yang, R.T., Thermal Anal., 1977, vol. 11, p. 445.
Gao, Z., Wang, H., and Nakada, M., Polymer, 2006, vol. 47, p. 1590.
Vyazovkin, S. and Wight, C.A., Ann. Rev. Phys. Chem., 1997, vol. 4, p. 125.
Junpirom, S., Tangsathihulchai, C., and Tangsathihulchai, M., Korean Chem. Eng., 2010, vol. 27, p. 791.
Prakash, N. and Karunanithi, T., Appl. Sci. Res., vol. 12, no. 4, p. 1627.
Sadhukhan, A.K., Gupta, P., and Saha, R.K., Biores. Tech., 2009, vol. 100, p. 3134.
Sommariva, S., Maffei, E., Migliavacca, G., and Faravelli, T., Fuel, 2010, vol. 89, p. 318.
Opfermann, J., Thermal Anal. Calorimetr., 2000, vol. 60, p. 641.
Pomerantsev, A.L., Doctoral (Phys.–Math.) Dissertation, Moscow Inst. Chem. Phys., Russ. Acad. Sci., 2003.
Haixiang, C., Naian, L., and Weitao, Z., Solid State Sci., 2010, vol. 12, p. 455.
Hu, S., Jess, A., and Xu, M., Fuel, 2007, vol. 86, p. 2778.
El-Sayed, S.A. and Mostafa, M.E., Ener. Conver. Manag., 2014, vol. 85, p. 165.
Guangwei, W., Jianliang, Z., and Jiugang, S., Int. Minin. Sci. Tech., 2015, vol. 25, p. 15.
Shen, D.K., Gu, S., and Luo, K.H., Fuel, 2009, vol. 88, p. 1024.
Cai, J.M. and Bi, L.S., Thermal Anal. Calorimetr., 2009, vol. 98, no. 3, p. 325.
Mar’yandyshev, P.A., Chernov, A.A., and Lyubov, V.K., Khim. Tverd. Topl. (Moscow), 2015, no. 2, p. 59.
Aboyade, A.O., Hugo, T.J., Carrier, M., Meyer, E.L., Stahl, R., Knoetze, J.H., and Gorgens, J.F., Thermochimica Ac, 2011, vol. 517, p. 81.
Vyazovkin, S., Burnham, A.K., Criado, J.M., Perez-Maqueda, L.A., Popescu, C., and Sbirrazzuoli, N., Thermochim. Acta, 2011, vol. 520, p. 1.
Amutio, M., Lopez, G., and Aguado, R., Fuel, 2012, vol. 95, p. 305.
Chen, W.-H. and Kuo, P.-C., Energy, 2011, vol. 36, p. 6451.
Asadieraghi, M. and Wan, DaudW.M.A., Energy Convers. Manage., 2014, vol. 82, p. 71.
Boiko, E.A., Pachkovskii, S.V., and Didichin, D.G., Fiz. Goreniya Vzryva, 2005, vol. 41, p. 55.
Su, Y., Luo, Y., and Wu, W., Anal. App. Pyr., 2012, vol. 98, p. 137.
Watanabe, H., Tanno, K., Umetsu, H., and Umento, S., Fuel, 2015, vol. 142, p. 250.
Kramb, J., Konttinen, J., Gomez-Barea, A., Moilanen, A., and Umeki, K., Fuel, 2014, vol. 132, p. 107.
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Original Russian Text © A.N. Kozlov, D.A. Svishchev, G.I. Khudiakova, A.F. Ryzhkov, 2017, published in Khimiya Tverdogo Topliva, 2017, No. 4, pp. 12–21.
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Kozlov, A.N., Svishchev, D.A., Khudiakova, G.I. et al. A kinetic analysis of the thermochemical conversion of solid fuels (A review). Solid Fuel Chem. 51, 205–213 (2017). https://doi.org/10.3103/S0361521917040061
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DOI: https://doi.org/10.3103/S0361521917040061