Journal of Mining and Metallurgy, Section B: Metallurgy 2023 Volume 59, Issue 1, Pages: 77-90
https://doi.org/10.2298/JMMB220919007M
Full text ( 13172 KB)
Cited by
Effect of low aluminum additions in the microstructure and mechanical properties of hot forged high-manganese steels
Morales-Cruz E.U. (Universidad Autónoma del Estado de Hidalgo - UAEH, Área Académica de Ciencias de la Tierra y Materiales, Pachuca, México), connorerick@gmail.com
Vargas-Ramírez M. (Universidad Autónoma del Estado de Hidalgo - UAEH, Área Académica de Ciencias de la Tierra y Materiales, Pachuca, México), marissav@uaeh.edu.mx
Lobo-Guerrero A. (Universidad Autónoma del Estado de Hidalgo - UAEH, Área Académica de Ciencias de la Tierra y Materiales, Pachuca, México), azdrubal_guerrero@uaeh.edu.mx
Cruz-Ramírez A. (Instituto Politécnico Nacional - ESIQIE, Departamento de Ingeniería en Metalurgia y Materiales, Ciudad de México, México), alcruzr@ipn.mx
Colin-García E. (Instituto Politécnico Nacional - ESIQIE, Departamento de Ingeniería en Metalurgia y Materiales, Ciudad de México, México), ecoling1400@alumno.ipn.mx
Sánchez-Alvarado R.G. (Instituto Politécnico Nacional - ESIQIE, Departamento de Ingeniería en Metalurgia y Materiales, Ciudad de México, México), risanchez@ipn.mx
Gutiérrez-Pérez V.H. (Instituto Politécnico Nacional - UPIIZ, Departamento de Formación Profesional Específica. Zacatecas, México), vhgutierrez@ipn.mx
Martínez-Vázquez J.M. (Universidad Politécnica de Juventino Rosas - UPJR, Guanajuato, México), jmerced.martinez@gmail.com
In the present work, the effect of low aluminum additions and the hot forging process on the microstructure and non-metallic inclusions of high manganese steels is analyzed. Four high-manganese steels (HMnS) were prepared by adding low aluminum contents of 1.1 and 1.5 wt. % to four carbon austenitic steels with medium carbon content (0.3 - 0.4 wt% C) and manganese contents of 17 and 22 wt. Samples of the as-cast steels were hot forged to 1100°C to obtain an overall reduction of 70 %. Microstructural evolution was studied using microscopy techniques (OM, and SEM-EDS) and X-ray diffraction measurements for the as-cast and hot forged steels. A typical grain columnar zone formed during solidification of a cast ingot was obtained in the as-cast condition, where the microstructure consisted of nonmetallic inclusions in a fully austenitic matrix. The non-metallic inclusions were identified as Al2O3 and MnS particles. Thermomechanical treatment allows the formation of an austenitic microstructure characterized by twins in steels with high manganese content, while an austenitic-martensitic duplex microstructure was obtained in HMnS, which contained the lowest manganese contents. The highest tensile strength values were obtained for 17Mn-1Al steel, which had the smallest grain size and higher content of non-metallic inclusions. The hardness values were similar to those obtained in the as-cast condition.
Keywords: Steel, hot forging, manganese, Hadfield, microstructure
Show references
G. Frommeyer, U. Brux, P. Neumann, Supra-ductile and high-strength manganese-TRIP/TWIP steels for high energy absorption purposes, ISIJ International, 43 (2003) 438-446. https://doi.org/10.2355/ISIJINTERNATIONAL.43.438
G. Frommeyer, U. Brux, Microstructures and mechanical properties of high-strength Fe-Mn-Al-C light-weight TRIPLEX steels, Steel Research International, 77 (2006) 627-633. https://doi.org/10.1002/srin.200606440
A. Tomaszewska, M. Jablonska, G. Niewielsky, R. Kawalla, E. Hadasik, Research of selected properties of two types of high manganese steel wires. IOP Conference Series Materials Science and Engineering, 22 (2011) 012015. doi:10.1088/1757-899X/22/1/012015
O. Cobos O, A. Romero, M. Monsalve, Cooling kinetics effect on abrasive wear behavior of an ASTM A128 steel, Contemporary Engineering Sciences, 11 (71) (2018) 3531-3537. https://doi.org/10.12988/ces.2018.87362.
K. Panchal, Life improvement of Hadfield manganese steel castings. International Journal of Scientific Development and Research, 5 (1) (2016) 817-825. http://www.ijsdr.org/papers/IJSDR1605148.pdf.
A. Srivastava, K. Das, Microstructural characterization of Hadfield austenitic manganese steel, Journal of Materials Science, 43 (2008) 5654-5658. https://doi.org/10.4236/jmmce.2013.15042.
S. Ayadi, A. Hadji, Effect of chemical composition and heat treatments on the microstructure and wear behavior of manganese Steel, International Journal of Metalcasting, (2020). https://doi.org/10.1007/s40962- 020-00479-2.
J. Jin, Y. Lee Y, Effects of Al on microstructure and tensile properties of C-bearing high Mn TWIP Steel, Acta Materialia, 4 (60) (2012) 1680-1688. https://doi.org/10.1016/j.msea.2018.02.003.
A. Ghosh, Secondary steelmaking: principles and applications, CRC Press LLC: USA, 2001, p. 255.
D. Matlock, J. Speer, E. Moor, P. Gibbs, Recent developments in advanced high strength sheet steels for automotive: An overview, JESTECH, 15 (1) (2012) 1- 12.
S. Kim, G. Kim G, K. Chin, Development of high manganese TWIP steel with 980 MPa tensile strength, Procceedings of the International Conference of New Developments in Advanced High-Strength Sheet Steels, AIST, Orlando Fl. (2008) 249-256.
S. Lee, B. Cooman, Tensile behavior of intercritically annealed ultra-fine grained 8% Mn multi-phase steel, Steel Research International, 10 (8) (2015) 1170-1178. https://doi.org/10.1002/srin.201500038.
T. Brune T, D. Senk, R. Walpot, B. Steennken, Hot ductility behavior of Boron containing microalloyed steels with varying manganese contents, Metallurgical and Materials Transactions B, 46 (2015) 1400-1408. https://doi.org/10.1007/s11663-015-0306-1.
X. Yang, L. Zhang, C. Lai, S. Li S, M. Li, Z. Deng, A method to control the transverse corner cracks on a continuous casting slab by combining microstructure analysis with numerical simulation of the slab temperature field, Steel Research International, 1700480 (89) (2018) 1-8. https://doi.org/10.1002/srin.201700480.
S. Sant, R. Smith, A study in the work-hardening behaviour of austenitic manganese steels, Journal of Materials Science, 22 (1987) 1808-1814. https://doi.org/10.1007/BF01132410.
F. Chen, C. Chou C, P. Li, S. Chu, Effect of aluminium on TRIP Fe Mn Al alloy steels at room temperature, Materials Science and Engineering A, 160 (2) (1993) 261-270.
Y. Han, S. Hong, The effect of Al on mechanical properties and microstructures of Fe-32Mn-12Cr-xAl- 0.4C cryogenic alloys, Materials Science and Engineering A, 222 (1) (1997) 76-83.
S. Takaki, T. Furuya, Y. Tokunaga, Effect of Si and Al additions on the low temperature toughness and fracture mode of Fe-27Mn alloys, ISIJ International, 30 (1990) 632-638. https://doi.org/10.2355/isijinternational.30.632.
R. Gurumayum, L. Yi-Jyun, Ch. Wei-Chun, Evidence of martensitic transformation in Fe-Mn-Al steel similar to maraging Steel, Metallurgical and Materials Transactions A, 52 (2021) 26-32. https://doi.org/10.1007/s11661-020-06054-y.
L. Kučerová, H. Jirková, J. Volkmannová, J. Vrtáček, Effect of aluminium and manganese contents on the microstructure development of forged and annealed TRIP Steel, Manufacturing Technology, 18 (4) (2018) 605-610. https://doi.org/10.21062/ujep/146.2018/a/1213- 2489/MT/18/4/605.
V. Flaxa, J. Shaw, Material Application in ULSABAVC, Steel Grips, 1 (4) (2003) 255-261.
M. Mehrkens, J. Fröber, Modern multi-phase steels in the BMW of the Porsche Cayenne, Steel Grips, 1 (4) (2003) 249-251.
G. Frommeyer, O. Grässel, High strength TRIP-TWIP and superplastic steels development, properties, application, La Revue de Metallurgie-CIT, 10 (1998) 1299-1310.
S. Allain, J. Chateau, O. Bouaziz, S. Migot, N. Guelton, Correlations between the calculated stacking fault energy and the plasticity mechanisms in Fe-Mn-C alloys, Materials Science and Engineering A. 387-389 (2004) 158-162. https://doi.org/10.1016/j.msea.2004.01.059.
R. Ueji, N. Tsuchida, D. Terada, N. Tsuji, Y. Tanaka, A. Takemura, K. Kunishige, Tensile properties and twinning behavior of high manganese austenitic steel with fine-grained structure. Scripta Materialia, 59 (9) (2008) 963-966. https://doi.org/10.1016/j.scriptamat.2008.06.050.
Y. Estrin, H. Mecking, A unified phenomenological description of work hardening and 26 creep based on one-parameter models, Acta Metallurgica et Materialia, 32 (1984) 57-70.
O. Bouaziz, S. Allain, C. Scott, P. Cugy, D. Barbier, High manganese austenitic twinning induced plasticity steels: A review of the microstructure properties relationships, Solid State and Materials Science, 15 (2011) 141-168. https://doi.org/10.1016/j.cossms.2011.04.002.
T. Furuhara, N. Kimura, T. Maki, Proceedings 1st International Conference on High Mn steel, The Korean Institute of Metals and Materials, Seoul, Korea, May 2011.
K. Chin, Automotive-Circle, 12. Proceedings International Conference on Materials in car body engineering, Bad Nauheim, Germany, May 2010.
R. Van Tol, L. Zhao, J. Sietsma, Proceedings 1st International Conference on High Mn steel, The Korean Institute of Metals and Materials, Seoul, Korea, May 2011.
A. Hamada, L. Karjalainen, M. Somani, The influence of aluminium on hot deformation behaviour and tensile properties of high-Mn TWIP steels, Materials Science and Engineering A, 467 (1-2) (2007) 114-124. https://doi.org/10.1016/j.msea.2007.02.074.
C. Igathinathane, L. Pordesimo, E. Columbus, E. Batchelor, S. Methuku, Shape identification and particle size distribution from basic shape parameters using ImageJ. Computers and Electronics in Agriculture, 63 (2008) 168-182. https://doi.org/10.1016/j.compag.2008.02.007.
B. De Cooman, O. Kwon, K. Chin, State-of-theknowledge on TWIP Steel, Materials Science and Technology, 28(5) (2012) 513-527. https://doi.org/10.1179/1743284711Y.0000000095.
G. Reyes, A. Cruz, E. Colin, V. Gutiérrez, Thermodynamic analysis of the graphite flake formation of low manganese and sulfur gray cast iron, Archives of Metallurgy and Materials Science, 66 (1) (2021) 249-258. https://doi.org/10.24425/amm.2021.134782.
N. NguyenVan, K. Kato, H. Ono, Precipitation Behavior of AlN Inclusions in Fe-0.5Al-2.0Mn alloy under continuous unidirectional solidification process, Frontiers in Materials, 8 (736284) (2021) 1-8. https://doi.org/10.3389/fmats.2021.736284.
T. Allam, W. Bleck, C. Klinkenberg, B. Kintscher, U. Krupp, J. Rudnizki, The continuous casting behavior of medium manganese steels, Journal of Materials Research and Technology, 15 (2021) 292-305. https://doi.org/10.1016/j.jmrt.2021.08.019.
L. Zhang, B. Thomas, X. Wang, K. Cai, Evaluation and control of steel cleanliness - Review, 85th Steelmaking Conference Proceedings, ISS-AIME, Warrendale, PA, 2002.
Y. Lee, J. Han, Current opinion in medium manganese steel, Materials Science and Technology 31(7) (2015) 843-856. https://doi.org/10.1179/1743284714Y.0000000722.
G.S. Rohrer, Introduction to grains, phases, and interfaces-an interpretation of microstructure, Trans AIME, 175 (1948) 15-51. https://doi.org/10.1007/s11661-010-0215-5.
Z. Wu, W. Zheng, G. Li, H. Matsuura, F. Tsukihashi, Effect of inclusions behavior on the microstructure in Al-Ti deoxidized and Magnesium-Treated steel with different aluminum contents, Metallurgical and Materials Transactions B, 46 (2015) 1226-1241. https://doi.org/10.1007/s11663-015-0311-4.
L. Qian, X. Feng, F. Zhang, Deformed microstructure and hardness of Hadfield high manganese steel, Materials Transactions 52 (8) (2011) 1623-1628. https://doi.org/10.2320/matertrans.M2011121.
Y. Wen, H. Peng, H. Si, R. Xiong, D. Raabe, A novel high manganese austenitic steel with higher work hardening capacity and much lower impact deformation than Hadfield manganese Steel, Materials & Design, 55 (2014) 798-804. https://doi.org/10.1016/j.matdes.2013.09.057.
B. Wietbrock, M. Bambach, S. Seuren, G. Hirt, Homogenization strategy and material characterization of high-manganese TRIP and TWIP steels, Materials Science Forum, 638-642 (2010) 3134-3139. https://doi.org/10.4028/www.scientific.net/MSF.638- 642.3134.
O. Grässel, G. Frommeyer, C. Derder, H. Hofmann, Phase transformations and mechanical properties of Fe- Mn-Si-A1 TRIP-Steels, Journal of Phyics: IV Proceedings, EDP Sciences, 7 (C5) (1997) 383-388. https://hal.archives-ouvertes.fr/jpa-00255657.
J. Kowalska, J. Ryś, G. Cempura, Complex structural effects in deformed high-manganese Steel, Materials, 14 (6935) (2021) 1-19. https://doi.org/10.3390/ma14226935.
U. Gürol, S. Can Kurnaz, Effect of carbon and manganese content on the microstructure and mechanical properties of high manganese austenitic steel, Journal of Mining and Metallurgy Section BMetallurgy 56 (2) (2020) 171-182. https://doi.org/10.2298/JMMB191111009G.
R. Arreola, A. Cruz, J. Rivera, A. Romero, R. Sánchez, The effect of non-metallic inclusions on the mechanical properties of 32 CDV 13 steel and their mechanical stress analysis by numerical simulation, Theoretical and Applied Fracture Mechanics, 94 (2018) 134-146. https://doi.org/10.1016/j.tafmec.2018.01.013.
F. Bahfie, B. Aji, F. Nurjaman, A. Junaedi, E. Sururiah, The effect of aluminum on the microstructure and hardness of high austenitic manganese Steel, IOP Conference Series Materials Science and Engineering, 285 (012020) (2018) 1-4. https://doi.org/10.1088/1757- 899X/285/1/012020.
G. Dini, A. Najafizadeh, R. Ueji, S. Monirvaghefi, Improved tensile properties of partially recrystallized submicron grained TWIP Steel, Materials Letters, 64 (1) (2011) 15-18. https://doi.org/10.1016/J.MATLET.2009.09.057.
J. Hajšman, L. Kucerová, K. Burdová, The Influence of varying aluminium and manganese content on the corrosion resistance and mechanical properties of high strength steels, Metals, 11 (9) (2021) 1-16. https://doi.org/10.3390/met11091446.
George E. Dieter, Mechanical metallurgy, Mc-Graw Hill, Boston, Massachusetts, 1986, 185-188 and 227- 229.