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Current Organic Chemistry

Editor-in-Chief

ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

A Carbohydrate Based Total Synthesis of Xestodecalactone B and C: Revision of the Absolute Configuration

Author(s): Rita Pal, Hasibur Rahaman and Mukund K. Gurjar

Volume 16, Issue 9, 2012

Page: [1159 - 1168] Pages: 10

DOI: 10.2174/138527212800564321

Price: $65

Abstract

A convergent chiral pool approach for the total synthesis of xestodecalactones B and C was demonstrated in which intramolecular acylation reaction constituted the key step. Synthetic and spectroscopic studies reported herein, suggested that the previously assigned structures of xestodecalactone B and C be interchanged.

Keywords: Xestodecalactone B and C, Chiral pool, Intramolecular acylation, Hydroboration, Pinnick oxidation, Revision of absolute configuration


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