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Separation of Metal Complexes with Counter Ions by Tube Radial Distribution Chromatography Using a Ternary Solvent Containing 8-quinolinol

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Abstract

An open-tubular capillary chromatography system (tube radial distribution chromatography, TRDC) was developed using a ternary solvent (water-acetonitrile-ethyl acetate; volume ratio, 3:8:4) containing 10 mmol L−1 8-quinolinol for the separation of nitrate, chloride, and sulfate compounds of Ni(II), Al(III), and Fe(III). When a mixed solution of the Ni(II) compounds was injected into an untreated fused-silica capillary tube (90 cm × 75 μm i.d.) with a ternary solvent flow rate of 0.8 μL min−1, the compounds were eluted in the following order: [Ni(II)-(8-quinolinol)3] complex, [Ni(II)-(8-quinolinol)]-nitrate ion interaction complex, [Ni(II)-(8-quinolinol)]-chloride ion interaction complex, and [Ni(II)-(8-quinolinol)]-sulfate ion interaction complex. The elution of mixtures of the Al(III) and Fe(III) compounds showed similar trends.

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Authors and Affiliations

  1. Department of Chemical Engineering and Materials Science, Faculty of Science and Engineering, Doshisha University, 610-0321, Kyotanabe, Kyoto, Japan

    Yuji Kawai, Satoshi Fujinaga, Masahiko Hashimoto & Kazuhiko Tsukagoshi

  2. Tube Radial Distribution Phenomenon Research Center, Doshisha University, 610-0321, Kyotanabe, Kyoto, Japan

    Kazuhiko Tsukagoshi

Authors
  1. Yuji Kawai
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  2. Satoshi Fujinaga
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  3. Masahiko Hashimoto
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  4. Kazuhiko Tsukagoshi
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Correspondence to Kazuhiko Tsukagoshi.

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Kawai, Y., Fujinaga, S., Hashimoto, M. et al. Separation of Metal Complexes with Counter Ions by Tube Radial Distribution Chromatography Using a Ternary Solvent Containing 8-quinolinol. ANAL. SCI. 31, 1177–1182 (2015). https://doi.org/10.2116/analsci.31.1177

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  • DOI: https://doi.org/10.2116/analsci.31.1177

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