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Ultrasonic and Densimetric Titration Applied for Acid-base Reactions

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Abstract

Classical acoustic acid-base titration was monitored using sound speed and density measurements. Plots of these parameters, as well as of the adiabatic compressibility coefficient calculated from them, exhibit changes with the volume of added titrant. Compressibility changes can be explained and quantitatively predicted theoretically in terms of Pasynski theory of non-compressible hydrates combined with that of the additivity of the hydration numbers with the amount and type of ions and molecules present in solution. It also seems that this development could be applied in chemical engineering for monitoring the course of chemical processes, since the applied experimental methods can be carried out almost independently on the medium under test (harmful, aggressive, etc.).

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Authors and Affiliations

  1. Faculty of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383, Wrocław, Poland

    Andrzej Burakowski & Jacek Gliński

Authors
  1. Andrzej Burakowski
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  2. Jacek Gliński
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Correspondence to Andrzej Burakowski.

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Burakowski, A., Gliński, J. Ultrasonic and Densimetric Titration Applied for Acid-base Reactions. ANAL. SCI. 30, 793–798 (2014). https://doi.org/10.2116/analsci.30.793

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  • DOI: https://doi.org/10.2116/analsci.30.793

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