Skip to main content
SpringerLink
Log in

Co-precipitative Preparation of a Sulfonated Cellulose-magnetite Hybrid Sorbent for the Removal of Cu2+ Ions

  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

A novel sulfonated cellulose-magnetite (Fe3O4) composite sorbent was prepared and applied for the removal of Cu2+ ions from an aqueous solution. It was characterized by infrared spectroscopy, X-ray fluorescence, elemental analysis, SEM, VSM and X-ray photoelectron spectroscopy. The effect of the sorbent dose, initial solution pH, and temperature on Cu2+ removal were studied. The removal of the Cu2+ was completed in 15 min, and the sorption kinetics of Cu2+ was found to follow a pseudo-second-order kinetic model. An equilibrium test demonstrated that sorption of Cu2+ onto a hybrid sorbent agreed well with the Langmuir adsorption model for a maximum adsorption capacity of 4.2 mg/g. Moreover, the optimum pH for Cu2+ removal was found to be ≥4. Furthermore, the thermodynamic parameters reveal the feasibility, spontaneity and endothermic nature of the sorption process. In addition, Cu2+ ions can be desorbed from the sorbent with a 0.5 M H2SO4 solution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Z.F. Yang, L.Y. Li, C. Te Hsieh, R.S. Juang, J. Taiwan Inst. Chem. Eng., 2018, 82, 56.

    Article  CAS  Google Scholar 

  2. H. Aydin, Y. Bulut, Ç. Yerlikaya, J. Environ. Manage., 2008, 87, 37.

    Article  CAS  PubMed  Google Scholar 

  3. Z. Aksu and I.A. I§oglu, Process Biochem., 2005, 40, 3031.

    Article  Google Scholar 

  4. WHO, 2004, 03.4/88.

  5. E. Parlak and Ö. Arar, J. Dispers. Sci. Technol., 2018, 39, 1403.

    Article  Google Scholar 

  6. D.Y. Zhang, N. Zhang, P. Song, J.Y. Hao, Y. Wan, X.H. Yao, T. Chen, L. Li, Carbohydr. Polym., 2018, 787, 560.

    Article  Google Scholar 

  7. M. Zirak, A. Abdollahiyan, B. Eftekhari-Sis, M. Saraei, Cellulose, 2018, 25, 503.

    Article  CAS  Google Scholar 

  8. E. Özbunar, S. Kirca, Ö. Arar, Ü. Yüksel, Anal. Lett., 2017, 50, 1657.

    Article  Google Scholar 

  9. O. Yayayürük, E. Henden, N. Bicak, Anal. Sci., 2011, 27, 833.

    Article  PubMed  Google Scholar 

  10. Q. Wu and Z. Xiong, J. Dispers. Sci. Technol., 2015, 36, 821.

    Article  CAS  Google Scholar 

  11. X. Yu, S. Tong, M. Ge, J. Zuo, C. Cao, W. Song, J. Mater. Chem. A, 2013, 7, 959.

    Article  Google Scholar 

  12. M. Alfe, P. Ammendola, V. Gargiulo, F. Raganati, R. Chirone, Proc. Combust. Inst., 2015, 35, 2801.

    Article  CAS  Google Scholar 

  13. T. Yamashita and P. Hayes, Appl. Surf. Sci., 2008, 254, 2441.

    Article  Google Scholar 

  14. A.C. Small and J.H. Johnston, J. Colloid Interface Sci., 2009, 337, 122.

    Article  Google Scholar 

  15. S.E.-S. Ghazy, S.E.-S. Samra, A.E.-F.M. Mahdy, S.M. El-Morsy, Anal. Sci., 2006, 22, 377.

    Article  PubMed  Google Scholar 

  16. N.A. Fakhre and B.M. Ibrahim, J. Hazard. Mater., 2018, 343, 324.

    Article  PubMed  Google Scholar 

  17. M.A. Güngör, Ö. Özalp, Ö. Arar, Desalin. Water Treat., 2017, 88, 279.

    Article  Google Scholar 

  18. W. Rieman and H.F. Walton, "Ion Exchange in Analytical Chemistry", 1970, Pergamon Press, Oxford.

    Google Scholar 

  19. G. McKay, Y.S. Ho, J.C.Y. Ng, Sep. Purif. Rev., 1999, 28, 87.

    Article  CAS  Google Scholar 

  20. Y.S. Ho and G. McKay, Process Biochem., 1999, 34, 451.

    Article  Google Scholar 

  21. A.Z.M. Badruddoza, A.S.H. Tay, P.Y. Tan, K. Hidajat, M.S. Uddin, J. Hazard. Mater., 2011, 785, 1177.

    Article  Google Scholar 

  22. X. Yi, J. He, Y. Guo, Z. Han, M. Yang, J. Jin, J. Gu, M. Ou, X. Xu, Ecotoxicol. Environ. Saf., 2018, 747, 699.

    Article  Google Scholar 

  23. A. Asthana, R. Verma, A.K. Singh, M.A.B.H. Susan, J. Environ. Chem. Eng., 2016, 4, 1985.

    Article  CAS  Google Scholar 

  24. A. Mittal, R. Ahmad, I. Hasan, Desalin. Water Treat., 2016, 57, 19820.

    Article  CAS  Google Scholar 

  25. G. Neeraj, S. Krishnan, P. Senthil Kumar, K.R. Shriaishvarya, V. Vinoth Kumar, J. Mol. Liq., 2016, 274, 335.

    Article  Google Scholar 

  26. M.J. Slater, "Principles of Ion Exchange Technology", 1st ed., 1991, Butterworth-Heinemann, London.

    Google Scholar 

  27. V.S. Bagotsky, "Fundamentals of Electrochemistry", 2nd ed., 2005, John Wiley & Sons, NJ.

    Book  Google Scholar 

  28. F.L. Slejko, "Adsorption Technology: A Step-by-Step Approach To Process Evaluation and Application", 1985, Marcel Dekker, New York

    Google Scholar 

  29. B. Alyüz and S. Veli, J. Hazard. Mater., 2009, 767, 482.

    Google Scholar 

  30. C. Marchioni, F.M. de Oliveira, C.S. de Magalhaes, P.O. Luccas, Anal. Sci., 2015, 37, 165.

    Article  Google Scholar 

  31. N.M. El-Mallah and H.M. Hassouba, J. Dispers. Sci. Technol., 2014, 35, 130.

    Article  Google Scholar 

  32. H. Hu, J. Zhang, K. Lu, Y. Tian, J. Environ. Chem. Eng., 2015, 3, 357.

    Article  CAS  Google Scholar 

  33. A. Mahapatra, B.G. Mishra, G. Hota, J. Hazard. Mater., 2013, 258-259, 116.

    Article  PubMed  Google Scholar 

  34. M. Bystrzejewski, K. Pyrzyfiska, A. Huczko, H. Lange, Carbon, 2009, 47, 1201.

    Article  CAS  Google Scholar 

  35. A.M. Donia, A.A. Atia, F.I. Abouzayed, Chem. Eng. J., 2012, 797, 22.

    Article  Google Scholar 

  36. Y.-T. Zhou, H.-L. Nie, C. Branford-White, Z.-Y. He, L.-M. Zhu, J. Colloid Interface Sci., 2009, 330, 29.

    Article  CAS  PubMed  Google Scholar 

  37. S.S. Banerjee and D.H. Chen, J. Hazard. Mater., 2007, 747, 792.

    Article  Google Scholar 

  38. J.F. Liu, Z.S. Zhao, G. Bin Jiang, Environ. Sci. Technol., 2008, 42, 6949.

    Article  CAS  PubMed  Google Scholar 

  39. B. Asçi, E. Kövenc, Ö. Arar, M. Arda, Glob. NESTJ., 2018, 20, 368.

    Article  Google Scholar 

  40. M. Duran, Ö. Arar, M. Arda, J. Chil. Chem. Soc., 2019, 64, 4399.

    Article  CAS  Google Scholar 

  41. Ö. Arar, Anadolu Univ. J. Sci. Technol. Appl. Sci. Eng., 2016, 77, 530.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ege University, Izmir, 35040, Turkey

    Özgür Arar

Authors
  1. Özgür Arar
    View author publications

    You can also search for this author in PubMed Google Scholar

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Arar, Ö. Co-precipitative Preparation of a Sulfonated Cellulose-magnetite Hybrid Sorbent for the Removal of Cu2+ Ions. ANAL. SCI. 36, 81–85 (2020). https://doi.org/10.2116/analsci.19SAP01

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.19SAP01

Keywords

Search

Navigation