Abstract
Pure and modified polyethyleneimines with molecular weights of up to about 400 were characterized using gas chromatography (GC)/chemical ionization mass spectrometry (CI-MS) and GC with a flame ionization detector (FID). Relatively stable molecular ions produced by CI-MS provided information for identifying each polyethyleneimine homolog. FID-GC provided more accurate quantitative information on the distribution of the homologs identified by GC/CI-MS. The levels of various ethyleneamines, potential genotoxicants, could be simultaneously obtained by this approach, providing information used to evaluate the human safety of polyethyleneimines from various sources and synthetic routes.
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Ogura, I., Kawakami, S., DuVal, D.L. et al. Characterization of Low-Molecular-Weight Polyethyleneimines Using GC/CI-MS and GC. ANAL. SCI. 12, 97–102 (1996). https://doi.org/10.2116/analsci.12.97
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DOI: https://doi.org/10.2116/analsci.12.97