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Zinc-Selective Membrane Electrode Using Tetrabutyl Thiuram Disulfide Neutral Carrier

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Abstract

A poly(vinyl chloride) membrane electrode that is highly sensitive and selective for zinc ions has been developed by using tetrabutyl thiuram disulfide neutral carrier. This electrode incorporated the ionophore along with o-nitrophenyloctyl ether as a plasticizing solvent mediator and potassium tetrakis(p-chlorophenyl)borate as anion excluder; it exhibited a linearity range of 10-1 - 10-6 M with a Nernstian slope of 28.0 mV per decade at 25±1°C. The membrane electrode showed a good response to zinc ions in the useful pH range of 3.5 to 6.5, where interferences arise only from a few transition metals such as Cu11 and Pb11.

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Authors and Affiliations

  1. Central Research Laboratories, Nihon Parkerizing Co., Ltd., Ogami, Hiratsuka, 254, Japan

    Ryuji Kojima

  2. Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Kagoshima University, Korimoto, Kagoshima, 890, Japan

    Satsuo Kamata

Authors
  1. Ryuji Kojima
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  2. Satsuo Kamata
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Kojima, R., Kamata, S. Zinc-Selective Membrane Electrode Using Tetrabutyl Thiuram Disulfide Neutral Carrier. ANAL. SCI. 10, 409–412 (1994). https://doi.org/10.2116/analsci.10.409

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  • DOI: https://doi.org/10.2116/analsci.10.409

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