Crystal Structures of [XnE]+[(η7-C7H7)Mo(CO)2GaI3]- (XnE = (thf)4Li, Cy3PH)

Natalie D. COOMBS; Simon ALDRIDGE; Amber L. THOMPSON; Louise MALE; Michael B. HURSTHOUSE

doi:10.2116/analscix.23.x213

Part 11

Crystal Structures of [X_nE]⁺[(η⁷-C₇H₇)Mo(CO)₂GaI₃]^- (X_nE = (thf)₄Li, Cy₃PH)

Natalie D. COOMBS, Simon ALDRIDGE, Amber L. THOMPSON, Louise MALE, Michael B. HURSTHOUSE

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JOURNAL FREE ACCESS

2007 Volume 23 Pages x213-x214

DOI https://doi.org/10.2116/analscix.23.x213

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Abstract

The crystal structures of [X_nE]⁺[(η⁷-C₇H₇)Mo(CO)₂GaI₃]^- [X_nE = (C₄H₈O)₄Li (1), (C₆H₁₁)₃PH (2)] are reported, revealing: (1) monoclinic, P2₁/c, a = 11.2388(1), b = 17.3201(3), c = 17.5473(2)Å, β = 101.623(1)°, Z = 4, R = 0.038 and wR2 = 0.090 for 7614 observed reflections [I > 2σ(I)]; (2) monoclinic, P2₁/n, a = 9.2979(5), b = 18.4632(8), c = 19.9789(9)Å, σ = 99.325(3)°, Z = 4, R = 0.073 and wR2 = 0.184 for 5554 observed reflections [I > 2σ(I)].

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