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Year 2019, Volume: 23 Issue: 5, 810 - 816, 01.10.2019

Tijen Ennil Bektas Filiz Eren

https://doi.org/10.16984/saufenbilder.538174

Abstract

References

  • REFERENCES [1] WHO, “Sulfate in drinking water,” Guidelines for Drinking Water Quality, 2004.
  • [2] US EPA, “Health effects from exposure to high levels of sulfate in drinking water study,”1999.
  • [3] Regulation For Water Pollution Control, Official Gazette Published, No: 25687, 31/12/2004.
  • [4] C. Namasivayam and D. Sangeetha, “Application of coconut coir pith for the removal of sulfate and other anions from water,” Desalination, vol. 219, no. 1, pp. 1-13, 2008.
  • [5] F. İncetan, “ Removal of natural organic matters and sulfate from surface from surface water sources by MIEX resin” Master Thesis, Erciyes University, Institute of Science, Department of Environmental Engineering, 2011.
  • [6] A. Karabacak, “Sulphate removal by nanofiltration from water” Master Thesis, Middle East Technical University, Institute of Science, Department of Environmental Engineering, 2010.
  • [7] X. Wang, Y. Song and J. Mai, “Combined fenton oxidation and aerobic biological processes for treating a surfactant wastewater containing abundant sulfate,” Journal of Hazardous Materials, vol. 160, pp. 344-348, 2008.
  • [8] D. Duranoğlu, “Sulfate removal from wastewater by chemical precipitation method,” Journal of Engineering and Natural Sciences, vol. 30, pp. 39-55, 2011.
  • [9] P. G. Klepetsanis and P.G. Koutsoukos, “Precipitation of calcium sulfate dehydrate at constant calcium activity,” J. Cryst. Growth, vol. 98, pp. 480-486, 1989.
  • [10] I. Kabdaşlı, A. Bilgin and O. Tünay, “Sulphate control by ettringite precipitation in textile industry wastewaters,” Environmental Technology, vol. 37, no.4, pp. 446-451, 2016.
  • [11] O. Levenspiel, "Chemical Reaction Engineering", 1 Edn, Wiley, New York, 1972.
  • [12] J. L. Cortina and A. Warshawsky, "Developments - in solid-liquid extraction by solvent impregınated resins,” lon Exchange and Solvent Extraction, L.A. Marinsky and Y. Marcus (Eds.), Vol. 13, Marcel Dekker, Inc, New York, 1997.
  • [13] J. L. Cortina, A. Warshawsky, N. Kahara, V. Kampel, C.H. Sampaio and R. M.Kautzmann, "Kinetics of gold cyanide extraction using ion-exchange resins containing piperazine functionality," React. Funct. Polym., vol. 54, pp. 25-35, 2003.
  • [14] M. Badruk, N. Kabay, M. Demircioglu, H. Mordoğan and U. Ipekoglu, "Removal ofboron from wastewater of geothermal power plant by selective ion-exchange resins. I. Batch sorption-elution studies," Separ. Sci. Technol., vol. 34, pp. 2553-2569, 1999.
  • [15] R. Boncukoğlu, A. E. Yılmaz, M. M. Kocakerim and M. Çopur, "An empirical model far kinetics of baron removal from boron-containing wastewaters by ion exchange in a batch reactor,” Desalination, vol. 160, pp. 159-166, 2004.
  • [16] Z. Aksu and F. Gönen, "Biosorption of phenol by immobilized activated sludge in continuous packed bed: prediction ofbreakthrough curves," Process Biochem., vol. 39, pp. 599-613, 2004.
  • [17] H. C. Thomas, “Heterogeneous ion exchange in a flowing system,” J. Am. Chem. Soc., vol. 66, pp. 1664-1666, 1944.
  • [18] Y. H. Yoon and J. H. Nelson, “Application of gas adsorption kinetics. I. A theoretical model for respirator cartridge service time,” Am. Ind, Hyg. Assoc. J., vol. 45, pp.509-516, 1984.

Batch and Column Studies for Removal of Sulphate from Real Wastewater Using Ion Exchange Resin

Year 2019, Volume: 23 Issue: 5, 810 - 816, 01.10.2019

Tijen Ennil Bektas Filiz Eren

https://doi.org/10.16984/saufenbilder.538174

Abstract

In this
study, sorption potential of anion exchange resin (Lewatit Monoplus M600) to
remove sulphate from real wastewater was investigated. Kinetic studies were
performed in batch experiments. A comparison of kinetic models applied to the
sorption of sulphate onto resin was evaluated for the "infinite solution volume model" and
"unreacted core model". Rate-determining step is the liquid film control
step of the unreacted core model. When pH values increased above 9, more than
80% sulphate removal was observed. Column sorption-elution experiments were
performed for the removal of the sulphate from the wastewater by resin. The
Thomas and the Yoon-Nelson models were applied to experimental data to
determine the characteristic column parameters.

Keywords

Sulphate anion-exchange resin wastewater kinetic models

References

  • REFERENCES [1] WHO, “Sulfate in drinking water,” Guidelines for Drinking Water Quality, 2004.
  • [2] US EPA, “Health effects from exposure to high levels of sulfate in drinking water study,”1999.
  • [3] Regulation For Water Pollution Control, Official Gazette Published, No: 25687, 31/12/2004.
  • [4] C. Namasivayam and D. Sangeetha, “Application of coconut coir pith for the removal of sulfate and other anions from water,” Desalination, vol. 219, no. 1, pp. 1-13, 2008.
  • [5] F. İncetan, “ Removal of natural organic matters and sulfate from surface from surface water sources by MIEX resin” Master Thesis, Erciyes University, Institute of Science, Department of Environmental Engineering, 2011.
  • [6] A. Karabacak, “Sulphate removal by nanofiltration from water” Master Thesis, Middle East Technical University, Institute of Science, Department of Environmental Engineering, 2010.
  • [7] X. Wang, Y. Song and J. Mai, “Combined fenton oxidation and aerobic biological processes for treating a surfactant wastewater containing abundant sulfate,” Journal of Hazardous Materials, vol. 160, pp. 344-348, 2008.
  • [8] D. Duranoğlu, “Sulfate removal from wastewater by chemical precipitation method,” Journal of Engineering and Natural Sciences, vol. 30, pp. 39-55, 2011.
  • [9] P. G. Klepetsanis and P.G. Koutsoukos, “Precipitation of calcium sulfate dehydrate at constant calcium activity,” J. Cryst. Growth, vol. 98, pp. 480-486, 1989.
  • [10] I. Kabdaşlı, A. Bilgin and O. Tünay, “Sulphate control by ettringite precipitation in textile industry wastewaters,” Environmental Technology, vol. 37, no.4, pp. 446-451, 2016.
  • [11] O. Levenspiel, "Chemical Reaction Engineering", 1 Edn, Wiley, New York, 1972.
  • [12] J. L. Cortina and A. Warshawsky, "Developments - in solid-liquid extraction by solvent impregınated resins,” lon Exchange and Solvent Extraction, L.A. Marinsky and Y. Marcus (Eds.), Vol. 13, Marcel Dekker, Inc, New York, 1997.
  • [13] J. L. Cortina, A. Warshawsky, N. Kahara, V. Kampel, C.H. Sampaio and R. M.Kautzmann, "Kinetics of gold cyanide extraction using ion-exchange resins containing piperazine functionality," React. Funct. Polym., vol. 54, pp. 25-35, 2003.
  • [14] M. Badruk, N. Kabay, M. Demircioglu, H. Mordoğan and U. Ipekoglu, "Removal ofboron from wastewater of geothermal power plant by selective ion-exchange resins. I. Batch sorption-elution studies," Separ. Sci. Technol., vol. 34, pp. 2553-2569, 1999.
  • [15] R. Boncukoğlu, A. E. Yılmaz, M. M. Kocakerim and M. Çopur, "An empirical model far kinetics of baron removal from boron-containing wastewaters by ion exchange in a batch reactor,” Desalination, vol. 160, pp. 159-166, 2004.
  • [16] Z. Aksu and F. Gönen, "Biosorption of phenol by immobilized activated sludge in continuous packed bed: prediction ofbreakthrough curves," Process Biochem., vol. 39, pp. 599-613, 2004.
  • [17] H. C. Thomas, “Heterogeneous ion exchange in a flowing system,” J. Am. Chem. Soc., vol. 66, pp. 1664-1666, 1944.
  • [18] Y. H. Yoon and J. H. Nelson, “Application of gas adsorption kinetics. I. A theoretical model for respirator cartridge service time,” Am. Ind, Hyg. Assoc. J., vol. 45, pp.509-516, 1984.
There are 18 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Research Articles
Authors

Tijen Ennil Bektas 0000-0001-9180-3623

Filiz Eren This is me 0000-0002-7302-8659

Publication Date October 1, 2019
Submission Date March 11, 2019
Acceptance Date March 27, 2019
Published in Issue Year 2019 Volume: 23 Issue: 5

Cite

APA Bektas, T. E., & Eren, F. (2019). Batch and Column Studies for Removal of Sulphate from Real Wastewater Using Ion Exchange Resin. Sakarya University Journal of Science, 23(5), 810-816. https://doi.org/10.16984/saufenbilder.538174
AMA Bektas TE, Eren F. Batch and Column Studies for Removal of Sulphate from Real Wastewater Using Ion Exchange Resin. SAUJS. October 2019;23(5):810-816. doi:10.16984/saufenbilder.538174
Chicago Bektas, Tijen Ennil, and Filiz Eren. “Batch and Column Studies for Removal of Sulphate from Real Wastewater Using Ion Exchange Resin”. Sakarya University Journal of Science 23, no. 5 (October 2019): 810-16. https://doi.org/10.16984/saufenbilder.538174.
EndNote Bektas TE, Eren F (October 1, 2019) Batch and Column Studies for Removal of Sulphate from Real Wastewater Using Ion Exchange Resin. Sakarya University Journal of Science 23 5 810–816.
IEEE T. E. Bektas and F. Eren, “Batch and Column Studies for Removal of Sulphate from Real Wastewater Using Ion Exchange Resin”, SAUJS, vol. 23, no. 5, pp. 810–816, 2019, doi: 10.16984/saufenbilder.538174.
ISNAD Bektas, Tijen Ennil - Eren, Filiz. “Batch and Column Studies for Removal of Sulphate from Real Wastewater Using Ion Exchange Resin”. Sakarya University Journal of Science 23/5 (October 2019), 810-816. https://doi.org/10.16984/saufenbilder.538174.
JAMA Bektas TE, Eren F. Batch and Column Studies for Removal of Sulphate from Real Wastewater Using Ion Exchange Resin. SAUJS. 2019;23:810–816.
MLA Bektas, Tijen Ennil and Filiz Eren. “Batch and Column Studies for Removal of Sulphate from Real Wastewater Using Ion Exchange Resin”. Sakarya University Journal of Science, vol. 23, no. 5, 2019, pp. 810-6, doi:10.16984/saufenbilder.538174.
Vancouver Bektas TE, Eren F. Batch and Column Studies for Removal of Sulphate from Real Wastewater Using Ion Exchange Resin. SAUJS. 2019;23(5):810-6.
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