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Synthesis of New Multiple Layered Dion-Jacobson Perovskites

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Abstract

New multiple layered perovskites with general formula RbLaNaxNb2+xO7+3x, x = 1 and 2, were synthesized via a ceramic method. While the triple layered compound could be obtained by simple direct reaction, the quadruple layered one was synthesized using a two-step solid state approach. The compounds were characterized by X-ray powder diffraction; the newly obtained compounds appear to be isostructural with the previously reported RbCa2Nb3O10 and RbCa2NaNb4O13 for RbLaNaNb3O10 and RbLaNa2Nb4O13, respectively. Preliminary results show that the new compounds can undergo ion exchange reactions involving alkali metals and transition metal chlorides.

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Authors and Affiliations

  1. Department of Chemistry and Advanced Materials Research Institute, University of New Orleans, New Orleans, LA, 70148, USA

    Léa Gustin, Jérôme Lefebvre, Clare Davis-Wheeler, Amy K. Pressley & John B. Wiley

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  1. Léa Gustin
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  2. Jérôme Lefebvre
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  3. Clare Davis-Wheeler
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  4. Amy K. Pressley
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  5. John B. Wiley
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Correspondence to Léa Gustin.

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Gustin, L., Lefebvre, J., Davis-Wheeler, C. et al. Synthesis of New Multiple Layered Dion-Jacobson Perovskites. MRS Online Proceedings Library 1655, 605 (2014). https://doi.org/10.1557/opl.2014.410

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