Abstract
In the present paper, the authors investigated the microstructures and mechanical properties of dual-phase Co–Ti–V-based superalloys with different additions of Ru. The results showed that with the increase of Ru contents, the size of γ′ precipitates of the alloy gradually raised, the volume fraction of γ′ phase slightly, and the lattice misfit between γ/γ′ phases increased. Ru was enriched in the γ′ phase, and the elemental partition coefficients (KX = Cγ′/Cγ) of Ti and V increased with the increment of Ru. The Ru contents have no remarkable influence on the solvus temperatures of γ′ in the Co–Ti–V alloys. The yield strength at 1000 °C of the Co–10Ti–11V–0.5Ru alloy was the highest, while the yield strength of the 1Ru alloy was the smallest. Transmission electron microscopy and scanning electron microscopy observations showed that the γ′ shape in the compressed specimen containing 0.5Ru remain integrated, while the γ′ in other alloys were cut into several parts.
Similar content being viewed by others
References
T.M. Pollock and S. Tin: Nickel-based superalloys for advanced turbine engines: Chemistry, microstructure and properties. J. Propuls. Power 361, 22 (2006).
T.M. Pollock, J. Dibbern, M. Tsunekane, J. Zhu, and A. Suzuki: New Co-based γ/γ′ high-temperature alloys. JOM 58, 62 (2010).
W.J. Lin, J.F. Duan, and C.L. Wang: Study on precipitation enhancement of Ni-based superalloys. Foundry Technol. 607, 29 (2008).
X.H. Li, B. Gan, and Q. Feng: Co-Al-W ternary alloy heat treatment organization. J. Sci. Eng. 1369, 30 (2008) (in Chinese).
J.R. Davis: Nickel, Cobalt, and Their Alloys (ASM International, Materials Park, OH, USA, 2000).
H. Chinen, J. Sato, T. Omori, K. Oikawa, I. Ohnuma, R. Kainuma, and K. Ishida: New ternary compound Co3(Ge, W) with L12 structure. Scr. Mater. 141, 56 (2007).
A.V. Davydov, U.R. Kattner, D. Jossel, J.E. Blendell, R.M. Waterstrat, A.J. Shaprio, and W.J. Boettinger: Determination of the Co-Ti congruent Melting point and thermodynamic reassessment of the Co-Ti system. Metall. Mater. Trans. A 2175, 32 (2001).
K. Shinagawa, H. Chinen, T. Omori, K. Oikawa, I. Ohnuma, and R. Kainuma: Phase equilibria and thermodynamic calculation of the Co-Ta binary system. Intermetallics 87, 49 (2014).
L. Zhu, C. Wei, H. Qi, L. Jiang, Z. Jin, and J.C. Zhao: Experimental investigation of phase equilibria in the Co-rich part of the Co-Al-X (X = W, Mo, Nb, Ni, Ta) ternary systems using diffusion multiples. J. Alloy Compd. 110, 691 (2017).
A. Suzuki, H. Inui, and T.M. Pollock: L12-strengthened cobalt-base superalloys. Annu. Rev. Mater. Res. 345, 45 (2015).
K. Tanake, T. Ohashi, and K. Kishida: Single-crystal elastic constants of Co(Al,W) with the L12 structure. App. Phys. Lett. 307, 91 (2007).
M. Ooshima, K. Tanaka, N.L. Okamoto, K. Kishida, and H. Inui: Effects of quaternary alloying elements on the γ′ solvus temperature of Co-Al-W based alloys with fcc/L12 two-phase microstructures. J. Alloy Compd. 71, 508 (2010).
S. Akanes and T.M. Pollock: High-temperature strength and deformation of γ/γ′ two-phase Co-Al-W-base alloys. Scr. Mater. 1288, 56 (2008).
J. Sato, T. Tomori, and K. Oikawa: Cobalt-base high-temperature alloys. Science 90, 312 (2006).
A. Suzuki, G.C. DeNolf, and T.M. Pollock: Flow stress anomalies in γ/γ′ two-phase Co-Al-W-base alloys. Scr. Mater. 385, 56 (2007).
A. Bauer, S. Neumeier, F. Pyczak, and M. Göken: Microstructure and creep strength of different γ/γ′-strengthened Co-base superalloy variants. Scr. Mater. 1197, 63 (2010).
T. Omori, K. Oikawa, J. Sato, I. Ohnuma, U.R. Kattner, R. Kainuma, and K. Ishida: Partition behavior of alloying elements and phase transformation temperatures in Co-Al-W-base quaternary systems. Intermetallics 274, 32 (2013).
K. Shinagawa, T. Omori, K. Oikawa, R. Kainuma, and K. Ishida: Ductility enhancement by boron addition in Co-Al-W high-temperature alloys. Scr. Mater. 612, 61 (2009).
K. Shinagawa, T. Omori, J. Sato, K. Oikawa, I. Ohnuma, R. Kainuma, and K. Ishida: Phase equilibria and microstructure on γ′ phase in Co-Ni-Al-W system. Mater. Trans. 1474, 49 (2008).
Y. Tsukamoto, S. Kobayashi, and T. Takasugi: The stability of γ′-Co3(Al, W) phase in Co-Al-W ternary system. Mater. Sci. Forum 448, 654–656 (2010).
S. Kobayashi, Y. Tsukamoto, T. Takasugi, H. Chinen, T. Omori, K. Ishida, and S. Zaefferer: Determination of phase equilibria in the Co-rich Co-Al-W ternary system with a diffusion-couple technique. Intermetallics 1085, 17 (2009).
S. Kobayashi, Y. Tsukamoto, and T. Takasugi: The effects of alloying elements (Ta, Hf) on the thermodynamic stability of γ′-Co3 (Al, W) phase. Intermetallics 94, 31 (2012).
S. Neumeier, H.U. Rehman, J. Neuner, C.H. Zenk, S. Michel, S. Schuwalow, J. Rogal, R. Drautz, and M. Goken: Diffusion of solutes in fcc cobalt investigated by diffusion couples and first principles kinetic Monte Carlo. Acta Mater. 304, 106 (2016).
P.J. Bocchini, C.K. Sudbrack, R.D. Noebe, D.C. Dunand, and D.N. Seidman: Microstructural and creep properties of boron- and zirconium-containing cobalt-based superalloys. Mater. Sci. Eng. A 260, 682 (2017).
P.J. Bocchini, C.K. Sudbrack, R.D. Noebe, D.C. Dunand, and D.N. Seidman: Effects of titanium substitutions for aluminum and tungsten in Co-10Ni-9Al-9W (at.%) superalloys. Mater. Sci. Eng. A 122, 705 (2017).
P.J. Bocchini, C.K. Sudbrack, D.J. Sauza, R.D. Noebe, D.N. Seidman, and D.C. Dunand: Effect of tungsten concentration on microstructures of Co-10Ni-6Al-(0, 2, 4, 6) W-6Ti (at.%) cobalt-based superalloys. Mater. Sci. Eng. A 481, 700 (2017).
S.K. Makineni, B. Nithin, and K. Chattopadhyay: A new tungsten-free γ-γ′ Co-Al-Mo-Nb-based superalloy. Scr. Mater. 36, 98 (2015).
J.J. Ruan, C.P. Wang, and C.C. Zhao: Experimental investigation of phase equilibria and microstructure in the Co-Ti-V ternary system. Intermetallics 121, 49 (2014).
C.H. Zenk, I. Povstugar, R. Li, F. Rinaldi, S. Neumeier, D. Raabe, and M. Göken: A novel type of Co-Ti-Cr-based γ/γ′ superalloys with low mass density. Acta Mater. 244, 135 (2017).
J.J. Ruan, X.J. Liu, and S.Y. Yang: Novel Co-Ti-V-base superalloys reinforced by L12-ordered γ′ phase. Intermetallics 126, 92 (2018).
L.J. Carroll, Q. Feng, J.F. Mansfield, and T.M. Pollock: High refractory, low misfit Ru-containing single-crystal superalloys. Metall. Mater. Trans. A 2927, 37 (2006).
L.J. Carroll, Q. Feng, J.F. Mansfield, and T.M. Pollock: Elemental partitioning in Ru-containing nickel-base single crystal superalloys. Mater. Sci. Eng. A 292, 457 (2007).
S. Tin, A.C. Yeh, A.P. Ofori, R.C. Reed, S.S. Babu, and M.K. Miller: Atomic partitioning of Ruthenium in Ni-based superalloys. In Superalloys 2004, K.A. Green, T.M. Pollock, H. Harada, T.E. Howson, R.C. Reed, J.J. Schirra, and S. Walston eds. (Proceedings of the Tenth International Symposium on Superalloys, Champion, PA, 2004); p. 735.
Y. Zhou, Z.G. Mao, C.B. Morrison, and D.N. Seidman: The partitioning and site preference of rhenium or ruthenium in model nickel-based superalloys: An atom-probe tomographic and first-principles study. Appl. Phys. Lett. 171905, 93 (2008).
D.J. Sauza, P.J. Bocchini, D.C. Dunand, and D.N. Seidman: Influence of ruthenium on microstructural evolution in a model Co-Al-W superalloy. Acta Mater. 135, 117 (2016).
M. Chen and C-Y. Wang: First-principles study of the partitioning and site preference of Re or Ru in Co-based superalloys with interface. Phys. Lett. A 3238, 374 (2010).
H. Mughrabi: The importance of sign and magnitude of γ/γ′ lattice misfit in superalloys — With special reference to the new γ′-hardened cobalt-base superalloys. Acta Mater. 21, 81 (2014).
M. Chen and C-Y. Wang: First-principles investigation of the site preference and alloying effect of Mo, Ta and platinum group metals in γ′ -Co3(Al,W). Scr. Mater. 659, 60 (2009).
Y.L. Du, J.P. Niu, G.X. Wang, J.L. Liu, J.D. Liu, Y.Z. Zhou, T. Jin, and X.F. Sun: Effect of Ru on the microstructure of Ni-based single-crystal superalloys. Rare Metal Mater. Eng. 1248, 47 (2018) (in Chinese).
J.X. Zhang, H. Harada, Y. Koizumi, and T. Kobayashi: Dislocation motion in the early stages of high-temperature low-stress creep in a single-crystal superalloy with a small lattice misfit. J. Mater. Sci. 523, 45 (2010).
J.Y. Chen, B. Zhao, Q. Feng, L.M. Cao, and Z.Q. Sun: Effect of Ru and Cr on γ/γ′ microstructural evolution of Ni-based single-crystal superalloys during heat treatment. Acta Metall. Sin. 897, 46 (2010).
M.G. Wang, S.G. Tian, and X.F. Yu: Effects of Re and temperature on lattice constants and misfit of single crystal nickel-based alloys. Rare Metal Mater. Eng. 268, 39 (2010).
H. Mughrabi: The importance of sign and magnitude of γ/γ′ lattice misfit in superalloys-with special reference to the new γ′-hardened cobalt-base superalloys. Acta Mater. 21, 81 (2014).
P. Viatour, J.M. Drapier, and D. Coutsouradis: Stability of the gamma prime Co3Ti compound in simple and complex Co alloys. Cobalt 3, 67 (1973).
M. Titus, A. Suzuki, and T. Pollock: Creep and directional coarsening in single crystals of new γ/γ′ cobalt-base alloys. Scr. Mater. 574, 66 (2012).
C. Rogister, D. Coutsouradis, and L. Habraken: Improvement of heat-resisting cobalt-base alloys by precipitation hardening. Cobalt 3, 34 (1967).
A.C. Yeh: Effects of Ru and Re additions on the high temperature flow stresses of Ni-base single crystal superalloys. Scr. Mater. 519, 52 (2005).
M.R. Jahangiri, S.M.A. Boutorabi, and H. Arabi: Study on incipient melting in cast Ni base IN939 superalloy during solution annealing and its effect on hot workability. Mater. Sci. Technol. 1402, 28 (2012).
Acknowledgments
This research was financially supported from Project (51471079) by the National Natural Science Foundation of China and Project (BK20130464) by the Jiangsu Natural Science Foundation. The authors would also like to acknowledge the financial support from the Jiangsu Government scholarship for Oversea Studies. This work also supported by the State Key Laboratory of Powder Metallurgy, Central South University, Changsha, China; the Key Research and Development Program of Shaanxi (Program Nos. 2019GY-151, 2019GY-178, and 2020GY-251); the National Natural Science Foundation of China (51901193); and the Science and Technology Plan Project of Weiyang District in Xi'an City (201905).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhou, P., Gao, X., Song, D. et al. Role of Ru on the microstructure and property of novel Co–Ti–V Superalloy. Journal of Materials Research 35, 2737–2745 (2020). https://doi.org/10.1557/jmr.2020.251
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/jmr.2020.251