Abstract
Gold nanorods 100 nm in diameter were grown within polycarbonate membranes as templates by the electrodeposition technique. A low-temperature sulfidation process was used to make gold sulfide nanoshells around the nanorods with a thickness of 7 nm. Optical absorption measurements were carried out on sulfide-coated gold nanorods obtained by dissolving the polycarbonate membrane. Several peaks were observed. These were analyzed on the basis of longitudinal and transverse modes of gold nanorods, the core-shell structure of gold-gold sulfide, and the presence of nanoparticles of gold. Theoretical analysis was carried out using a modified Mie scattering formalism. Satisfactory agreement between experimental results and theoretical fits were obtained.
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J.M. Weissman, H.B. Sunkara, A.S. Tse and S.A. Asher: Thermally switchable periodicities and diffraction from mesoscopically ordered materials. Science 274, 959 (1996).
R. Elghanian, J.J. Storhoff, R.C. Mucic, R.L. Letsinger and C.A. Mirkin: Selective colorimetric detection of polynucleotides based on the distance-dependent optical properties of gold nanoparticles. Science 277, 1078 (1997).
C.A. Mirkin, R.L. Letsinger, R.C. Mucic and J.J. Storhoff: A DNA-based method for rationally assembling nanoparticles into macroscopic materials. Nature (London) 382, 607 (1996).
C.L. Haynes and R.P. Van Duyne: Nanosphere lithography: A versatile nanofabrication tool for studies of size-dependent nanoparticle optic. J. Phys. Chem. B 105, 5599 (2001).
E.F. Schubert, N.E.J. Hunt, M. Micovic, R.J. Malik, D.L. Sivco, A.Y. Cho and G.J. Zydzik: Highly efficient light-emitting diodes with microcavities. Science 265, 943 (1994).
M.C. Wanke, O. Lehmann, K. Muller, Q. Wen and M. Stuke: Laser rapid prototyping of photonic band-gap microstructures Science 275, 1284 (1997).
J.D. Joannopoulous, P.R. Villeneuve and S. Fan: Photonic crystals: Putting a new twist on light. Nature (London) 386, 143 (1997).
F. Hache, D. Ricard and C. Flytzanis: Optical nonlinearities of small metal particles: Surface-mediated resonance and quantum-size effects. J. Opt. Soc. Am. B 3, 1647 (1986).
D.S. Wang and M. Kerker: Enhanced Raman scattering by molecules adsorbed at the surface of colloidal spheroids. Phys. Rev. B 24, 1777 (1981).
Z.S. Li, C.X. Kan and W.P. Cai: Tunable optical properties of nanostructured-gold/mesoporous-silica assembly. Appl. Phys. Lett. 82, 1392 (2003).
G. Mie: Contribution to the optics of turbid media specifically colloidal metal particles. Ann. Phys. (Leipzig) 25, 377 (1908).
C.G. Granqvist, N. Clander and O. Hunderi: Optical properties of ultrafine silver particles. Solid State Commun. 31, 249 (1979).
C. Sonnichsen, T. Franzl, T. Wilk, Von G. Plessen, J. Feldmann, O. Wilson and P. Mulvaney: Drastic reduction of plasmon damping in gold nanorods phys. Rev. Lett. 88, 077402 (2002).
A.E. Neeves and M.H. Birnboim: Composite structures for the enhancement of nonlinear optical materials. Opt. Lett. 134, 1087 (1988).
J.W. Haus, H.S. Zhou, I. Honma and H. Komiyama: Enhanced optical properties of metal-coated nanoparticles. J. Appl. Phys. 73, 1043 (1993).
K. Chatterjee, S. Banerjee and D. Chakravorty: Plasmon resonance shifts in oxide-coated silver nanoparticles. Phys. Rev. B66, 085421 (2002).
S. Banerjee, S. Banerjee, A. Datta and D. Chakravorty: Nanocomposite gel-derived films by fractal growth of silver. Europhys. Lett. 46, 346 (1999).
S. Bhattacharyya, S.K. Saha and D. Chakravorty: Silver nanowires grown in the pores of a silica gel. Appl. Phys. Lett. 77, 3770 (2000).
A. Dan, B. Satpati, P.V. Satyam and D. Chakravorty: Diodelike behavior in glass-metal nanocomposites. J. Appl. Phys. 93, 4794 (2003).
Handbook of Chemistry and Physics, edited by C.D. Hodgman (The Chemical Rubber Publishing Co., Cleveland, OH, 1962), p. 2672.
R. Gans: Form of ultramicroscopic particles of silver. Ann. Physik. 47, 270 (1915).
G.C. Papavassiliou: Optical properties of small inorganic and organic metal particles. Prog. Solid State Chem. 12, 185 (1980).
P.B. Johnson and R.W. Christy: Optical constants of the noble metals. Phys. Rev. B 6, 4370 (1972).
S. Link, M.B. Mohamed and M.A. El-Sayed: Simulation of the optical absorption spectra of gold nanorods as a function of their aspect ratio and the effect of the medium dielectric constant. J. Phys. Chem. B 103, 3073 (1999).
H.S. Zhou, I. Honma, H. Komiyama and J.W. Hous: Controlled synthesis and quantum-size effect in gold-coated nanoparticles. Phys. Rev. B 50, 12052 (1994).
U. Kreibig: Electronic properties of small silver particles: The optical constants and their temperature dependence. J. Phys. F: Met. Phys. 4, 999 (1974).
C. Kittel: Introduction to Solid State Physics (Wiley, New York, London, 1961), p. 374.
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Chatterjee, K., Basu, S. & Chakravorty, D. Plasmon resonance absorption in sulfide-coated gold nanorods. Journal of Materials Research 21, 34–40 (2006). https://doi.org/10.1557/JMR.2006.0032
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DOI: https://doi.org/10.1557/JMR.2006.0032