Abstract
We demonstrate that two-phase CrO2 and Cr2O3 thin films can be grown by using selective organometallic chemical vapor deposition through the oxidation of Cr(CO)6 in an oxygen environment. While the magnetization measurements show that both chromium oxides are present, the relative weight of each phase depends on the oxygen partial pressure. Changes of the Curie temperature, Tc and the saturation magnetization field may be possible by controlling the stoichiometry.
Similar content being viewed by others
Bibliography
A.M. Bratkovsky, Phys. Rev. B. 56 (1997) p. 2344.
S.S. Manoharan, D. Elefant, G. Reiss and J.B. Goodenough, Appl. Phys. Lett. 72 (1998) p. 984
X.W. Li, A. Gupta, T.R. McGuire, P.R. Duncombe, and Gang Xiao, J. Appl. Phys. 85 (1999) p. 5585
K. Suzuki and P.M. Tedrow, Phys. Rev. B. 58 (1998) p. 11597.
J.D.M. Coey, A.E. Berkowitz, Ll Balcells, F.F. Putris and A. Barry, Phys. Rev. Lett. 80 (1998) p. 3815.
J. S. Kouvel and D. S. Rodbell, J. Appl. Phys. 38 (1967) p. 979.
K. Schwarz, J. Phys. 16 (1986) p. L211.
S. Matar, G. Demazeau, J. Sticht, V. Eyert, and J. Käbler, J. de Physique I 2 (1992) p. 315.
M.A. Korotin, V.I. Anisimov, D.I. Khomskii and G.A. Sawatzky, Phys. Rev. Lett. 80 (1998) p. 4305.
S.P. Lewis, P.B. Allen, T. Sasaki, Phy. Rev. B 55 (1997) p. 10–253.
H. van Lueken and R.A. de Groot, Phys. Rev. B 51 (1995) p. 7176.
E. Kulatov and I.I. Mazin, J. Phys. Condens. Matter, 2 (1990) p. 343.
K.P. Kämper, W. Schmitt, G. Güntherodt, R.J. Gambino, and R. Ruf. Phys. Rev. Lett., 59 (1987) p. 2788.
R. Weisendanger, H.-J. Güntherodt, G. Güntherodt, R.J. Gambino, and R. Ruf. Phys. Rev. Lett., 65 (1990) p. 247.
R.J. Soulen, et al., Science, 282 (1998) p. 85
R.J. Soulen, M.S. Osofsky, B. Nadgorny, T. Ambrose, P. Boussard, S.F. Cheng, C.T. Tanaka, J. Nowack, J.S. Moodera, G. Laprade, A. Barry and M.D. Coey, J. Appl. Phys., 85 (1999) p. 4589.
P. A. Dowben, Yoon Gi Kim, S. Baral-tosh, G. O. Ramseyer, Chanyong Hwang and M. Onellion, J. Appl. Phys., 67 (1990) p. 5658.
K. Perkins, C. Hwang, M. Onellion, Yoon-Gi Kim, and P.A. Dowben, Thin Solid Films 198 (1991) p. 317–329.
D.C. Mancini, S. Varma, J.K. Simons, R.A. Rosenberg, and P.A. Dowben, J. Vac. Sci. Technol. B8 (1990) p. 1804–1807.
P.A. Dowben and M. Onellion, “Fabrication of CrO2 and Cobalt Doped CrO2 Films from Organometallic Complexes”, U.S. Patent Number 4,980,198 issued December 25, 1990.
D. Welipitiya, C. N. Borca, P. A. Dowben, I. Gobulukoglu, H. Jiang, B. W. Robertson and J.D. Zhang, Mat. Res. Soc. Symp. Proc., 475 (1997) p. 257.
C. N. Borca, D. Welipitiya, S. Adenwalla and P. A. Dowben, Phys. Low-Dim. Struct., 11/12 (1997) p. 173.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Cheng, R., Borca, C.N. & Dowben, P.A. Selective Area Chemical Vapor Deposition of Chromium Oxides. MRS Online Proceedings Library 614, 1041 (2000). https://doi.org/10.1557/PROC-614-F10.4.1
Published:
DOI: https://doi.org/10.1557/PROC-614-F10.4.1