Abstract
We report an experimental (infrared reflectance spectroscopy) and theoretical study of the polar optical phonons in hexagonal ternary nitride compounds: AlNm/GaNn (n=2-8, m=4, 8) superlattices (SL) and spontaneously ordered AlxGa1−xN (x=0.08-0.55) alloys. In infrared (IR) reflectivity spectra we revealed two modes having strong LO-TO splitting (20-150 cm−1), and several modes, having a small (1-3 cm−1) LO-TO splitting. All modes have a very high damping parameter ≥20 cm−1. The unusual observation is the negative value of the oscillator strength for the weak IR mode at ~690 cm−1, suggesting possible lattice instability, consistent with high damping observed. We found from lattice dynamical calculations that weak IR active modes correspond to modes localized at GaN-AlN interfaces. Our analysis has shown that an anomalous mode is induced by the disorder effects and arises due to strong overlapping of the LO-TO phonon branches of the bulk GaN and AlN. In SL samples the anomalous mode corresponds to phonons localized on interface inhomogenities.
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M. Asif Khan, J. N. Kuzina, D. T. Olson, T. George, and W. T. Pike, Appl. Phys. Lett., 63, 3471, (1993)
D. Korakakis, K. F. Ludwig Jr, and T. D. Moustakas, Appl. Phys. Lett, 71, 72 (1997).
Yu. E. Kitaev, M. F. Limonov, P. Tronc, and G. N. Yushin, Phys. Rev. B57, (1998).
C. T. Kirk, Phys. Rev. B38, 1255, 1988
A. S. Barker Jr and M. Ilegems, Phys.Rev. B7, 743, 1973
A. S. Barker Jr, Phys. Rev. 132, 1474 (1963)
M. Cardona, Superlattices and Microstructures, 7, 180, 1990
V. Yu. Daviidov, Yu. V. Kitaev, I. N. Goncharuk, A. N. Smirnov, J. Graul, O. Seminchinova, D. Uffmann, M. B. Smirnov, A. P. Mirgorodsky and R. A. Evarestov, Phys. Rev. B58, 12899 1998.
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Mintairov, A.M., Vlasov, A.S., Merz, J.L. et al. Disorder Induced IR Anomaly in Hexagonal AlGaN Short-Period Superlattices and Alloys. MRS Online Proceedings Library 572, 427 (1999). https://doi.org/10.1557/PROC-572-427
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DOI: https://doi.org/10.1557/PROC-572-427