Abstract
The AC force modulation technique in nano indentation has been extended to study the dynamic viscoelastic properties of polymer materials. The frequency and temperature dependent loss and storage modulus, the time-temperature superposition, the mechanical relaxation and the activation energy for the relaxation process can all be directly measured from nano scale contact. The results obtained for PMMA and Polyisoprene are in good agreement with the reported literature results obtained from conventional dynamic testing. The technique is likely to be of particular value for polymer thin films.
Similar content being viewed by others
References
J. B. Pethica, R. Hutchings and W. C. Oliver, Philos.Mag. A 48,593, (1983).
W. C. Oliver and G. M. Phar, J.Mater.Res, 7 (6), 1654, (1992).
M. J. Mayo and W. D. Nix, Acta Met, 6,2183, (1988).
B. J. Briscoe, and K. S. Sebastin, Pro. R. Soc. London A, 452, 439, (1996).
N. G. MacCrum, B. E. Read and G. Williams, Anelastic and Dielectric effects in Polymer solids, John Wiely, London, 1967.
J. L Loubet, B. N. Lucas and W.C. Oliver, NIST Special Publication No.896, 1996.
J. B. Petica and W. C. Oliver, Physica Scripta, T19, 61, (1987).
S. A. Syed Asif, D.Phil thesis, University of Oxford, 1997
A. R. Pyne, Rheology of Elastomer, Eds P. Mason, N Wookey, Pregmen, London, 1958
M. L. William, R. F. Landel and J. D. Ferry, J.Am. Chem. Soc. 77, 370, (1955).
K. Schmieder and K. Wolf, Kolloid Z, 134, 149, (1953).
J. Heijboer, Killoid Z, 148, 36, (1956); 171,7, (1960).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Asif, S.A.S., Pethica, J.B. Nano-Scale Viscoelastic Properties of Polymer Materials. MRS Online Proceedings Library 505, 103–108 (1997). https://doi.org/10.1557/PROC-505-103
Published:
Issue Date:
DOI: https://doi.org/10.1557/PROC-505-103