Skip to main content
Log in

A Study of Low-Temperature Grown GaP by Gas-Source Molecular Beam Epitaxy

  • Published:
MRS Online Proceedings Library Aims and scope

Abstract

We report the effects of growth conditions on the strain and crystalline quality of low-temperature (LT) grown GaP films by gas-source molecul1ar beam epitaxy. At temperatures below 160 °C, poly-crystalline GaP films are always obtained, regardless of the PH3 low rate used, while at temperatures above 160 °C, the material quality is affected by the PH3 flow rate. Contrary to compressively strained LT GaAs, high-resolution X-ray rocking curve measurement indicates a tensile strain of the LT GaP films, which is considered to be due to PGa antisite defects. The strain is found to be affected by the PH3 flow rate, the growth temperature, and post-growth annealing. Contrary to LT GaAs, no P precipitates are observed in cross-sectional transmission electron microscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. A. Puechner, D. A. Johnson, K. T. Shiralagi, D. S. Gerber, R. Droopad, and G. N. Maracas, J. Cryst. Growth 111,43(1991).

    Article  CAS  Google Scholar 

  2. F. W. Smith, A. R. Calawa, and C. Chen, IEEE Electron Device Lett. EDL-9,77 (1988).

    Article  Google Scholar 

  3. M. R. Melloch, K. Mahalingam, N. Otsuka, J. M. Woodall, and A. C. Warren, J. Cryst. Growth 111, 39(1991).

    Article  CAS  Google Scholar 

  4. A. C. Warren, N. Katzenellenbogen, D. Grischkowsky, J. M. Woodall, M. R. Melloch, and N. Otsuka, Appl. Phys. Lett. 58, 1512 (1991).

    Article  Google Scholar 

  5. F. W. Smith, H. W. Le, V. Diadiuk, M. A. Hollis, A. R. Calawa, S. Gupta, M. Frankel, D. R. Dykaar, and T. Y. Hsiang, Appl. Phys. Lett. 54, 890 (1989).

    Article  CAS  Google Scholar 

  6. F. W. Smith, Mater. Res. Soc. Symp. Proc. 241, 3 (1992).

    Article  CAS  Google Scholar 

  7. U. K. Mishra, R. M. Kolbas, Mater. Res. Soc. Symp. Proc. 241, 159 (1992).

    Article  CAS  Google Scholar 

  8. S. Gupta, G. Mourou, F. W. Smith, and A. R. Calawa, Mater. Res. Soc. Symp. Proc. 241, 205 (1992).

    Article  CAS  Google Scholar 

  9. W. M. Chen, I. A. Buyanova, A. V. Buyanov, W. G. Bi, and C. W. Tu, this volume.

  10. I. A. Buyanova, W. M. Chen, A. V. Buyanov, W. G. Bi, and C. W. Tu, unpublished.

  11. J. Ramdani, Y. He, M. Leonard, N. EI-Masry, and S. M. Bedair, Appl. Phys. Lett. 61, 1646 (1992).

    Article  CAS  Google Scholar 

  12. Y. He, N. A. EI-Masry, J. Ramdani, S. M. Bedair, T. L. McCormick, R. J. Nemanich, and E. R. Weber, Appl. Phys. Lett. 65, 1671 (1994).

    Article  CAS  Google Scholar 

  13. B. W. Liang, Y. He, and C. W. Tu, Mater. Res. Soc. Symp. Proc. 241, 283 (1992).

    Article  CAS  Google Scholar 

  14. M. Kaminska, Z. Liliental-Weber, E. R. Weber, T. George, J. B. Kortright, F. W. Smith, B. Y. Tsaur, and A. R. Calawa, Appl. Phys. Lett. 54, 1881 (1989).

    Article  CAS  Google Scholar 

  15. A. C. Warren, J. M. Woodall, J. L. Freeouf, D. Grischkowsky, D. T. Mcinturff, M. R. Melloch, and N. Otsuka, Appl. Phys. Lett. 57, 1331 (1990).

    Article  CAS  Google Scholar 

  16. W. G. Bi, F. Deng, S. S. Lau, and C. W. Tu, J. Vac, Sci. Technol. B13, 754 (1995).

    Google Scholar 

  17. F. W. Smith, C. L. Chen, G. W. Turner, M. C. Finn, L. J. Mahoney, M. J. Manfra, and A. R. Calawa, Proc. IEEE Int. Electron Devices Meeting (IEEE, New York, 1988), p. 838.

    Book  Google Scholar 

  18. M. Kaminska, E. R. Weber, Z. Liliental-Weber, R. Leon, and Z. U. Rek, J. Vac. Sci. Technol. B7, 710(1989).

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by NSF and AFOSR-AASERT.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to W. G. Bi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bi, W.G., Mei, X.B., Kavanagh, K.L. et al. A Study of Low-Temperature Grown GaP by Gas-Source Molecular Beam Epitaxy. MRS Online Proceedings Library 421, 293–298 (1996). https://doi.org/10.1557/PROC-421-293

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/PROC-421-293

Navigation