Abstract
A study of the electrical resisitivity of (FexMn1-x)Si with 0 ≤ x ≤ 1 indicates a crossover from an almost semiconducting state in FeSi to a metallic one in MnSi. Optical measurements show that the electronic structure and the vibrational behaviour appears to be essentially uneffected by the Fe/Mn substitution. Instead, a change of the free carrier density occurs, yielding a temperature and stoichiometry dependent plasma frequency.
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Acknowledgments
Parts of the work have been supported by the HCM contract Nr.CHRX-CT930318 of the European Commission and by the Austrian Science Foundation FWF, project 10269.
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Bocelli, S., Marabelli, F., Spolenak, R. et al. Evolution of the Optical Response from a Very Narrow Gap Semiconductor to a Metallic Material in (FexMn,1-x)Si. MRS Online Proceedings Library 402, 361–366 (1995). https://doi.org/10.1557/PROC-402-361
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DOI: https://doi.org/10.1557/PROC-402-361