Abstract
Using a “macro-trench” technique, the surface reaction probabilities β of the a-Si:H growth precursors for remote hollow cathode silane discharge (HC) and reactive magnetron sputter deposition (RMS) are measured. Both deposition methods produce state of the art photo-electronic quality a-Si:H. For the HC case, β= 0.28 ± 0.05, whereas for RMS deposition β ≈ 0.97 ± 0.05. We conclude that β is not universally correlated with film quality, and discuss mitigating factors present in RMS deposition that permit high quality film to be deposited despite the high film precursor reactivity.
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M. Pinarbasi, N. Maley, A. Myers and J. R. Abelson, Thin Solid Films 171, 217 (1989).
C. C. Tsai, J. C. Knights, G. Chang, and B. Wacker, J. Appl. Phys. 59 (8), 2998 (1986).
A. Matsuda, K. Nomoto, Y. Takeuchi, A. Suzuki, A. Yuuki, and J. Perrin, Surf. Sci. 227, 50 (1990).
D. A. Doughty, J. R. Doyle, G. H. Lin, and A. Gallagher, J. Appl. Phys. 67 (10), 6220 (1990).
A. Nuruddin, J. R. Doyle, and J. R. Abelson, to be published.
J. C. Knights, in Plasma Synthesis and Etching of Electronic Materials, ed. R. P. H. Chang and B. Abeles (MRS Proc. 38, Pittsburg, PA, 1985), p. 371.
A. M. Myers, D. N. Ruzic, N. Maley, J. Doyle, and J. R. Abelson, in Amorphous Silicon Technology - 1990. ed. A. Madan et al. (MRS Proc. 192, 1990), p. 595.
P. Ho, W. G. Breiland, and R. J. Buss, J. Chem. Phys. 91, 2627 (1989).
J. R. Abelson, N. Maley, J. R. Doyle, G. F. Feng, M. Fitzner, M. Katiyar, L. Mandreli, A. M. Myers, A. Nuruddin, D. N. Ruzic, and S. Yang, in Amorphous Silicon Technology - 1991, ed. A. Madan et al. (cnMRS Proc. 219, Pittsburg PA 1991), p. 619.
D. A. Doughty, and A. Gallagher, J. Appl. Phys. 67, 139 (1990).
AcknowledgmentS
This work was supported by the Electric Power Research Institute and World Bank Project XVII.
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Nuruddin, A., Doyle, J.R. & Abelson, J.R. Macro-Trench Studies of Surface Reaction Probability of a-Si:H Film Growth. MRS Online Proceedings Library 258, 33–37 (1992). https://doi.org/10.1557/PROC-258-33
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DOI: https://doi.org/10.1557/PROC-258-33