Abstract
The 1 Miz dielectric constants of a variety of synthetic aluminate garnets: Y3Al5O12, Ho3A15O12, Y2.93Nd.07Sc2Al3O12 and Gd2.95Nd.05Sc1 98Cr .02A13O12 and several silicates: CaB2Si2O8 (danburite), Ca3Al2Si3O12 (grossular) and Mg2Al4Si5O18(cordierite) were determined using the two-terminal method with edge corrections. These data and polarizabilities derived from the published single crystal dielectric constants of simple oxides were used to compare compound polarizabilities obtained from the Clausius-Mosotti equation and the oxide additivity rule.
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References
R. Roberts, Phys. Rev. 76, 1215-1220 (1949); Phys. Rev. 77, 258-263 (1950); Phys. Rev. 81, 865-868 (1951).
B. Szigeti, Trans. Farad. Soc. 45, 155-166 (1949).
H.D. Megaw, Ferroelectricity in Crystals, (Methuen, London, 1975), pp. 165-178
D.A. Dunmur, Molec. Phys. 23, 109-115 (1972).
A.C. Lasaga and R.T. Cygan, Am. Mineral. 67, 328-334 (1982).
C.K. Cheng, Phil. Mag. 30, 505-515 (1940).
A. Heydweiller, Z. Phys. 3, 308-317 (1920).
G.H. Jonker and J.H. Van Santen, Chemisches Weekblad 43, 672-679 (1947).
D.A.A.S. Narayana Rao, Proc. Ind. Acad. Sci. 25A, 408-412 (1947); Proc. Ind. Acad. Sci. 30A, 82-86 (1949); Proc. Ind. Acad. Sci. 30A, 317-319 (1949).
J. T. Armstrong, in Microbeam Analysis, edited by D.E. Newbury (1988) pp. 239-246.
A. Brown and C. M. Foris, Adv. X-Ray Anal. 26, 53 (1982).
G. R. Rossman, F. Rauch, R. Livi, T. A. Tombrello, C. R. Shi, and Z. Y. Zhou, N. Jb. Mineral. Mh. 1988, 172-178 (1988); R. S. Aines and G. R. Rossman, Amer. Mineral. 69, 319-327 (1984).
M.A. Subramanian, R.D. Shannon, B.H.T. Chai, M.M. Abraham and M.C. Wintersgill, submitted to Phys. Chem. Minerals.
Hewlett-Packard, Operating Manual for 4275A Multi-Frequency LCR Meter, Yokogawa-Hewlett-Packard Ltd., Tokyo (1984).
R.F. Field, Proc. ASTEA, Am. Soc. Testing Mats. 54, 456-478 (1954).
H.E. Bussey, J.E. Gray, E.C. Bamberger, E. Rushton, G. Russell, B.W. Petley and D. Morris, IEEE Trans, on Instrumentation and Measurement, Vol. IM-13, 305-311 (1964).
H.E. Bussey, Proc. IEEE 55, 1046-1053 (1967).
C. Andeen, J. Fontanella and D. Schuele, Rev. Sci. Instr. 41, 1573-1576 (1970); J. Appl. Phys. 42, 2216-2219 (1971).
J.D.H. Donnay and H.M. Ondik, Crystal Data- Determinative Tables. Vol. II. Inorganic Compounds. U.S.Dept. of Commerce, National Bur. Stds., JCPDS (1973).
J. Fontanella, C. Andeen and D. Schuele, J. Appl. Phys. 45, 2852-2854 (1974).
V.I. Aleksandrov, V.V. Voronov, V.F. Kalabukhova, Y.S. Kuzminov, V.M. Tatarintsev, Sov. Phys., Lebedev Inst. Rep. (4) 21-26 (1975).
W.B. Westphal and A. Sils, U.S. National Technical Information Service AFML-TR-72-39 (1972).
E.V. Dulepov, S.S. Batsonov and G.N. Kustova, J. Struct. Chem. 13, 935-938 (1972).
R.D. Shannon and M.A. Subramanian, submitted to Phys. Chem. Minerals.
R.D. Shannon, M.A. Subramanian and G.R. Rossman, unpublished data.
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Shannon, R.D., Subramanian, M.A., Marian, A.N. et al. Mineral Dielectric Constants and the Oxide Additivity Rule. MRS Online Proceedings Library 150, 197–201 (1989). https://doi.org/10.1557/PROC-150-197
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DOI: https://doi.org/10.1557/PROC-150-197