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Fracture Mechanics of Low Molecular Weight Polymers

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Abstract

A novel analysis is presented to explain mechanistic aspects of the fracture of low molecular weight polymers. The fracture energy is calculated as a function of the mean interpenetration distance of a polymer chain which has been derived from the solution of the Fokker-Planck equation. Experimental results with monodisperse polystyrene have been used to validate the theory.

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References

  1. R.P. Kusy and M.J. Kate, J. Mater. Sci. 11, 1475 (1976).

    Article  CAS  Google Scholar 

  2. A.G. Mikos and N.A. Peppas, J. Chcm. Phys. 88,1337 (1988).

    Article  CAS  Google Scholar 

  3. R.E. Robertson, in Toughness and Brittleness of Plastics, edited by R.D. Deanin and A.M. Crugnola, Advances in Chemistry Series (American Chemical Society, Washington, D.C., 1976), Vol. 154, Chap. 7, pp. 89–96.

  4. E.J. Kramer, J. Mater. Sci. 14, 1381 (1978).

    Article  Google Scholar 

  5. H.W. Kammer, Acta Polym. 34, 112 (1983).

    Article  CAS  Google Scholar 

  6. C.W. Gardiner, Handbook of Stochastic Methods for Physics, Chemistry and the Natural Sciences, 2nd ed. (Springer, New York, 1985).

  7. A.G. Mikos and N.A. Peppas, manuscript in preparation.

  8. T.G. Fox and S. Loshaek, J. Polym. Sci. 15, 371 (1955).

    Article  CAS  Google Scholar 

  9. P.J. Flory, Statistical Mechanics of Chain Molecules (Interscience, New York, 1969).

    Book  Google Scholar 

  10. Polymer Handbook, 2nd ed., edited by J. Brandrup and E.H. Immergut (Wiley, New York, 1975).

  11. J.D. Ferry, Viscoelastic Properties of Polymers, 3rd ed. (Wiley, New York, 1980).

    Google Scholar 

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Mikos, A.G., Peppas, N.A. Fracture Mechanics of Low Molecular Weight Polymers. MRS Online Proceedings Library 119, 63–68 (1988). https://doi.org/10.1557/PROC-119-63

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  • DOI: https://doi.org/10.1557/PROC-119-63

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