Abstract
A novel analysis is presented to explain mechanistic aspects of the fracture of low molecular weight polymers. The fracture energy is calculated as a function of the mean interpenetration distance of a polymer chain which has been derived from the solution of the Fokker-Planck equation. Experimental results with monodisperse polystyrene have been used to validate the theory.
Similar content being viewed by others
References
R.P. Kusy and M.J. Kate, J. Mater. Sci. 11, 1475 (1976).
A.G. Mikos and N.A. Peppas, J. Chcm. Phys. 88,1337 (1988).
R.E. Robertson, in Toughness and Brittleness of Plastics, edited by R.D. Deanin and A.M. Crugnola, Advances in Chemistry Series (American Chemical Society, Washington, D.C., 1976), Vol. 154, Chap. 7, pp. 89–96.
E.J. Kramer, J. Mater. Sci. 14, 1381 (1978).
H.W. Kammer, Acta Polym. 34, 112 (1983).
C.W. Gardiner, Handbook of Stochastic Methods for Physics, Chemistry and the Natural Sciences, 2nd ed. (Springer, New York, 1985).
A.G. Mikos and N.A. Peppas, manuscript in preparation.
T.G. Fox and S. Loshaek, J. Polym. Sci. 15, 371 (1955).
P.J. Flory, Statistical Mechanics of Chain Molecules (Interscience, New York, 1969).
Polymer Handbook, 2nd ed., edited by J. Brandrup and E.H. Immergut (Wiley, New York, 1975).
J.D. Ferry, Viscoelastic Properties of Polymers, 3rd ed. (Wiley, New York, 1980).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Mikos, A.G., Peppas, N.A. Fracture Mechanics of Low Molecular Weight Polymers. MRS Online Proceedings Library 119, 63–68 (1988). https://doi.org/10.1557/PROC-119-63
Published:
Issue Date:
DOI: https://doi.org/10.1557/PROC-119-63