Abstract
Conjugated polymers are largely intact by gamma exposure but can be energized in the presence of high-Z compounds. The resulting alteration of the polymer’s high optical density and photoluminescence efficiency can be exploited for the detection of gamma radiation with high sensitivity. Diiodobenzene and conjugated polymers mix on the molecular level in solid thin films. Composite films of various thicknesses were conveniently cast from solution and exposed to gamma radiation. The responses of the films to gamma dosage were observed with dramatic changes in ultraviolet-visible absorption and photoluminescence.
Similar content being viewed by others
References
G. F. Knoll, Radiation Detection and Measurement, 3rd Edition, J. Wiley and Sons, New York, 2000.
A. Owens, J. Synchrotron Rad. 2006, 13, 143.
A. Owens, A.G. Kozorezov, Nuclear Instruments and Methods in Physics Research A 2006, 563, 31.
K. Yoshino, S. Hayashi, and Y. Inuishi, Jpn. J. Appl. Phys., Part 1 1982, 21, L569
H. Kudoh, T. Sasuga, T. Seguchi, and Y. Katsumura, Polymer 1996, 37, 2903.
K. W. Lee, K. H. Mo, J. W. Jang and C. E. Lee, Journal of the Korean Physical Society, 2005, 47, 130.
P. Beckerle, H. Ströbele, Nuclear Instruments and Methods in Physics Research A 2000, 449, 302.
S.C. Graham, R.H. Friend, S. Fung, and S.C. Moratti, Synthetic Metals 1997, 84, 903.
M. Atreya, S. Li, E. T. Kang, K. G. Neoh, Z. H. Ma, K. L. Tan, W. Huang, Polymer Degradation and Stability 1999 65 287.
E. A. B. Silva, J. F. Borin, P. Nicolucci, C. F. O. Graeff, T. G. Netto, R. F. Bianchi, Appl. Phys. Lett. 2005, 86, 131902.
I. H. Campbell, B. K. Crone, Adv. Mater. 2006, 18, 77.
L. Chen, D. W. McBranch, H. L. Wang, R. Helgeson, F. Wudl, D. G. Whitten, Proceedings of the National Academy of Sciences of the United States of America, 1999, 96, 12287.
D. T. McQuade, A. E. Pullen, T. M.Swager, Chem. Rev. 2000, 100, 2537.
B.W. Van der Meer, G. Coker, S.-Y. Chen, Resonance Energy Transfer: Theory and Data, VCH Publishers, Inc., NewYork, 1994.
J. C. Scott, J. K. Kaufman, P. J. Brock, P. R. Di, J. Salem, J. A. Goiltia. J. Appl. Phys. 1996, 79, 2745.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Pei, Q., Zhao, Y. & Zhong, H. Polymer Composites for Radiation Detection: Diiodobenzene and light emitting polymer molecular solutions for gamma detection. MRS Online Proceedings Library 1038, 303 (2007). https://doi.org/10.1557/PROC-1038-O03-03
Received:
Accepted:
Published:
DOI: https://doi.org/10.1557/PROC-1038-O03-03