Abstract
The room-temperature dependences of the electrical conductivity σ, Seebeck coefficient S, Hall coefficient RH, and the thermoelectric power factor P on the thickness (d=10–300 nm) of the thin films grown on mica substrates by thermal evaporation in vacuum of Bi-Sb solid solutions crystals with 4.5 at.% Sb were obtained. It was established that an increase in d up to ~ 200 nm leads to a change in kinetic coefficients and that in the thickness dependences of the thermoelectric properties, quantum oscillations were observed. It was shown that the monotonic component of the σ(T) dependence can be satisfactorily approximated by theoretical calculations based on the classical Fuchs - Sondheimer theory. The theoretically estimated period of oscillations is in a good agreement with the experimentally observed period.
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References
D.M. Rowe, CRC Handbook of Thermoelectrics, CRC Press (Boca Raton, London, New York, Washington, 1995) p.701.
M.S. Dresselhaus, Yu-Ming Lin, T. Koga, S.B. Cronin, O. Rabin, M.R. Black, and G. Dresselhaus, In Semiconductors and Semimetals: Recent Trends in Thermoelectric Materials Research III, ed. by T.M. Tritt (Academic Press, San Diego, CA, 2001), pp. 1–121.
Yu.F. Komnik, Physics of Metal Films. Size and Structure Effects [in Russian] (Nauka, Moscow, 1979) p. 270.
M. Subotowicz, M. Jalochowski, B. Mikolajczak, P. Mikolajczak, Phys. Stat. Sol. A. 17(1), 79 (1973).
S.M. Akhtar, E.E. Khawaja . Phys. Stat. Sol. A. 87, 335–340, (1985).
S. Kochowski and A. Opilski, Thin Solid Films 48, 345 (1978).
V. Damodara Das and N. Soundararajan, Phys. Rev. B 35(12), 5990 (1987).
K. Fuchs . Proc. Cambridge Philos. Soc. 34, 100–108 (1938).
E.H. Sondheimer . Adv. Phys., 1(1), 1 (1952).
R. C. Mallik and V. Damodara Das . J..Appl. Phys., 98, 02371 (2005).
R. C. Mallik and V. Damodara Das . Vacuum 77(3), 275–285 (2005).
F. Volklein and E. Kessler . Phys. Stat. Sol. (b) 143, 121 (1987).
Yu.F. Komnik, Yu.V. Nikitin, and E.I. Bukhshtab, Fiz. Nizk. Temp. 4(9), 1143 (1978) [Sov. J. Low Temp. Phys. 4 (9), 538 (1978)].
Yu.F. Ogrin V.N. Lutskii, and M.I. Elinson, Sov. Phys. JETP Letters 3, 71 (1966)
V.B. Sandomirskii . Soviet Phys. JETP 25, 101 (1967)].
B.A. Tavger and V.Ya. Demikhovskii, Uspekhi Fiz Nauk 96, 61 (1968).
M.M.E. Favennec, M. Le Contellec, J.Y. Le Traon . Thin Solid Films, 13(1), 73 (1972).
M.P. Favennec et M. Le Contellec . Solid State Communications. 13(2), 141 (1973).
Yu.F. Komnik, Yu.V. Nikitin, E.I. Bukhshtab, Fiz. Nizk. Temp. 1(2), 243 (1975).
Yu.V. Nikitin, E. I. Bukhshtab, and Yu. F. Komnik, Fiz. Nizk. Temp. 4(11), 1440 (1978) [ Sov. J. Low Temp. Phys. 4 (11), 679 (1978)].
E. I. Bukhshtab, Yu.F. Komnik, Yu. Nikitin V. Sov. J. Low Temp. Phys. 4(8), 474 (1978).
Yu. F. Komnik, Yu.V. Nikitin, E. I. Bukhshtab Sov. J. Low Temp. Phys. 4(10), 591 (1978)].
N. Eisenberg and B.T. Tavger . Thin Solid Films, 89(1), 57 (1982)
N.B. Brandt and S.M. Chudinov, Zh. Eksper. Teor. Fiz. 59(5), 1494 (1970).
J.Y. Traon J.Y., H.A. Combet J. Phys. 30, 419 (1969).
J-P. Michenaud and J.-P. Issi . J. Phys. C: Solid State Phys. 5, 3061 (1972).
E.I. Rogacheva, S. N. Grigorov, O.N. Nashchekina, and S. Lyubchenko . Appl. Phys. Let. 82(15), 2628 (2003).
J.P. Issi . Austr. J. Phys., 32(6), 585 (1979).
V.I. Petrosyan, V.N. Molin, E.I. Dagman, B.A. Tavger, P.A. Skripkina, and L.N. Alexandrov . Fizika metalov i metalovedenie. 31, 725 (1971)
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Elena, I.R., Dar’ya, S.O., Mildred, S.D. et al. Size Effects in Bi-Sb Solid Solutions Thin Films. MRS Online Proceedings Library 1314, 1002 (2011). https://doi.org/10.1557/opl.2011.516
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DOI: https://doi.org/10.1557/opl.2011.516