Abstract
Spectroscopic techniques such as IR and Raman are very powerful to understand guest-host interactions. Although these techniques are complementary, Raman spectroscopy has not been widely implemented as a tool to characterize these interactions. This study illustrates the use of Raman spectroscopy not only to probe the interactions experienced by a guest molecule but also to detect structural changes occurring in the framework upon loading. Weak interactions of adsorbed molecules with the framework are reflected in frequency and intensity variations in both Raman and IR absorption lines, as shown for the case of CO2, N2 and CH4 with Zn(bdc)(ted)0.5.
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Centrone, A.; Siberio-Pérez, D. Y.; Millward, A. R.; Yaghi, O. M.; Matzger, A. J.; Zerbi, G. Chemical Physics Letters 2005, 411, 516–519.
Nakamoto, K. Infrared and Raman Spectra of Inorganic and coordination compounds; Fifth ed.; John Wiley and Sons Inc.; Vol. B.
Siberio-Perez, D. Y.; Wong-Foy, A. G.; Yaghi, O. M.; Matzger, A. J. Chemistry of Materials 2007, 19, 3681–3685.
Vimont, A.; Travert, A.; Bazin, P.; Lavalley, J.-C.; Daturi, M.; Serre, C.; Ferey, G.; Bourrelly, S.; Llewellyn, P. L. Chemical Communications 2007, 3291–3293.
Kuppler, R. J.; Timmons, D. J.; Fang, Q.-R.; Li, J.-R.; Makal, T. A.; Young, M. D.; Yuan, D.; Zhao, D.; Zhuang, W.; Zhou, H.-C. Coordination Chemistry Reviews 2009, 253, 3042–3066.
Hamon, L.; et al. Journal of the American Chemical Society 2009, 131, 17490–17499.
Li, J.-R.; Kuppler, R. J.; Zhou, H.-C. Chemical Society Reviews 2009, 38, 1477–1504.
Nijem, N.; Veyan, J.-F. o.; Kong, L.; Wu, H.; Zhao, Y.; Li, J.; Langreth, D. C.; Chabal, Y. J. Journal of the American Chemical Society 2010, 132, 14834–14848.
Nijem, N.; Veyan, J.-F.; Kong, L.; Li, K.; Pramanik, S.; Zhao, Y.; Li, J.; Langreth, D.; Chabal, Y. J. Journal of the American Chemical Society 2010, 132, 1654–1664.
Nijem, N.; Kong, L.; Zhao, Y.; Wu, H.; Li, J.; Langreth, D. C.; Chabal, Y. J. Journal of the American Chemical Society 2011, 133, 4782–4784.
Lee, J. Y.; Olson, D. H.; Pan, L.; Emge, T. J.; Li, J. Advanced Functional Materials 2007, 17, 1255–1262.
Zhao, Y.; Wu, H.; Emge, T. J.; Gong, Q.; Nijem, N.; Chabal, Y. J.; Kong, L.; Langreth, D. C.; Liu, H.; Zeng, H.; Li, J. Chemistry – A European Journal, 17, 5101–5109.
Fenner, W. R.; Hyatt, H. A.; Kellam, J. M.; Porto, S. P. S. J. Opt. Soc. Am. 1973, 63, 73–77.
Dietzel, P. D. C.; Johnsen, R. E.; Fjellvag, H.; Bordiga, S.; Groppo, E.; Chavan, S.; Blom, R. Chemical Communications 2008, 5125–5127.
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Nijem, N., Roodenko, K., Zhao, Y. et al. Raman Spectroscopy for Probing guest-host interactions in Metal Organic Frameworks. MRS Online Proceedings Library 1334, 606 (2011). https://doi.org/10.1557/opl.2011.1311
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DOI: https://doi.org/10.1557/opl.2011.1311