Skip to main content
Log in

Fabrication and optical characterizations of gold nanoshell opal

  • Article
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

We fabricated three-dimensional photonic crystals by self-assembling gold nanoshells via forced sedimentation method. Gold nanoshells with a diameter of 458 nm (418-nm silica core and 20-nm gold shell) were synthesized and self-assembled into a 5-μm-thick opal structure. We observed reflection peaks at 710 and 1240 nm, which are believed to be from the complete three-dimensional photonic band gap and the (111) directional gap, respectively. Theses results were in good agreement with the photonic band-structure calculations done by the finite-difference time-domain method. Angle-resolved reflectivity measurements were also performed to investigate the existence of the complete three-dimensional photonic band gap.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J.D. Joannopoulos, P.R. Villeneuve, S. Fan: Photonic crystals: Putting a new twist on light. Nature 386, 143 (1997).

    Article  CAS  Google Scholar 

  2. Y. Akahane, T. Asano, B.S. Song, S. Noda: High-Q photonic nanocavity in a two-dimensional photonic crystal. Nature 425, 944 (2003).

    Article  CAS  Google Scholar 

  3. H.Y. Ryu, S.H. Kwon, Y.J. Lee, Y.H. Lee, J.S. Kim: Very-low-threshold photonic band edge lasers from free-standing triangular photonic crystal slabs. Appl. Phys. Lett. 80, 3476 (2002).

    Article  CAS  Google Scholar 

  4. J.G. Fleming, S.Y. Lin, I. El-Kady, R. Biswas, K.M. Ho: All-metallic three-dimensional photonic crystals with a large infrared bandgap. Nature 417, 52 (2002).

    Article  CAS  Google Scholar 

  5. M. Qi, E. Lidorikis, P.T. Rakich, S.G. Johnson, J.D. Joannopoulos, E.P. Ippen, H.I. Smith: A three-dimensional optical photonic crystal with designed point defects. Nature 429, 538 (2004).

    Article  CAS  Google Scholar 

  6. Y.A. Vlasov, X.Z. Bo, J.C. Sturm, D.J. Norris: On-chip natural assembly of silicon photonic bandgap crystals. Nature 414, 289 (2001).

    Article  CAS  Google Scholar 

  7. A. Blanco, E. Chomski, S. Grabtchak, M. Ibisate, S. John, S.W. Leonard, C. Lopez, F. Meseguer, H. Miguez, J.P. Mondia, G.A. Ozin, O. Toader, H.M. van Driel: Large-scale synthesis of a silicon photonic crystal with a complete three-dimensional bandgap near 1.5 micrometres. Nature 405, 437 (2000).

    Article  CAS  Google Scholar 

  8. M. Campbell, D.N. Sharp, M.T. Harrison, R.G. Denning, A.J. Turberfield: Fabrication of photonic crystals for the visible spectrum by holographic lithography. Nature 404, 53 (2000).

    Article  CAS  Google Scholar 

  9. Z. Wang, C.T. Chan, W. Zhang, N. Ming, P. Sheng: Three-dimensional self-assembly of metal nanoparticles: Possible photonic crystal with a complete gap below the plasma frequency. Phys. Rev. B 64, 113108 (2001).

    Article  Google Scholar 

  10. S.J. Oldenburg, R.D. Averitt, S.L. Westcott, N.J. Halas: Nanoengineering of optical resonances. Chem. Phys. Lett. 288, 243 (1998).

    Article  CAS  Google Scholar 

  11. E. Prodan, C. Radloff, N.J. Halas, P. Nordlander: A hybridization model for the plasmon response of complex nanostructures. Science 302, 419 (2003).

    Article  CAS  Google Scholar 

  12. C. Graf, A. van Blaaderen: Metallodielectric colloidal core-shell particles for photonic applications. Langmuir 18, 524 (2002).

    Article  CAS  Google Scholar 

  13. P.T. Miclea, A.S. Susha, Z. Liang, F. Caruso, C.M. Sotomayor Torres, S.G. Romanov: Reflectivity behavior of opals of gold nanoparticle coated spheres. Appl. Phys. Lett. 84, 3960 (2004).

    Article  CAS  Google Scholar 

  14. Z. Liang, A. Susha, F. Caruso: Gold nanoparticle-based core-shell and hollow spheres and ordered assemblies thereof. Chem. Mater. 15, 3176 (2003).

    Article  CAS  Google Scholar 

  15. W. Stöber, A. Fink: Controlled growth of monodisperse silica spheres in the micron size range. J. Colloid Interface Sci. 26, 62 (1968).

    Article  Google Scholar 

  16. D.G. Duff, A. Baiker: A new hydrosol of gold clusters. I. Formation and particle size variation. Langmuir 9, 2301 (1993).

    Article  CAS  Google Scholar 

  17. S.H. Park, Y. Xia: Assembly of mesoscale particles over large areas and its application in fabricating tunable optical filters. Langmuir 15, 266 (1999).

    Article  CAS  Google Scholar 

  18. C.F. Bohren, D.R. Huffman: Absorption and Scattering of Light by Small Particles (Wiley-VCH Verlag GmbH & Co, KgaA, Weinheim, 1998).

    Book  Google Scholar 

  19. Y. Jiang, C. Whitehouse, J. Li, W.Y. Tam, C.T. Chan, P. Sheng: Optical properties of metallo-dielectric microspheres in opal structures. J. Phys: Condens. Matter 15, 5871 (2003).

    CAS  Google Scholar 

  20. M.I. Mishchenko, D.W. Mackowski: Light scattering by randomly oriented bispheres. Opt. Lett. 19, 1604 (1994).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Wounjhang Park.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lee, J.H., Wu, Q. & Park, W. Fabrication and optical characterizations of gold nanoshell opal. Journal of Materials Research 21, 3215–3221 (2006). https://doi.org/10.1557/jmr.2006.0398

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/jmr.2006.0398

Navigation