Abstract
Nanocomposite films consisting of gold nanoparticles embedded in an yttria stabilized zirconia (YSZ) matrix were synthesized at room temperature by radio-frequency co-sputtering from YSZ and Au targets at a 5 mTorr working pressure. The films were subsequently annealed for 2 h in 1 atm argon, with the annealing temperature varied from 600 to 1000 °C in steps of 100 °C. The composition, microstructure, and optical properties of the films were characterized as a function of annealing temperature by Rutherford backscattering spectrometry, scanning electron microscopy, Auger electron spectroscopy, x-ray diffraction, and absorption spectroscopy. An optical absorption band due to the surface plasmon resonance (SPR) of the Au nanoparticles was observed around a wavelength of 600 nm. Furthermore, the SPR band full width at half-maximum exhibited an inverse linear dependence on the radius of the Au nanoparticle, with a slope parameter A = 0.18, indicating a weak interaction between the YSZ matrix and the Au nanoparticles. The experimentally observed SPR dependence on nanoparticle size is discussed within the context of the Mie theory and its size-dependent optical constants.
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C.B. Murray, C.R. Kegar and M.G. Bawendi: Synthesis and characterization of monodisperse nanocrystals and close-packed nanocrystal assemblies. Annu. Rev. Mater. Sci. 30, 545 (2000).
S. Link and M.A. El-Sayed: Optical properties and ultrafast dynamics of metallic nanocrystals. Annu. Rev. Phys. Chem. 54, 331 (2003).
A.D. MacFarland and R.P. Van Duyne: Single silver nanoparticles as real-time optical sensors with zeptomole sensitivity. Nano Lett. 3, 1057 (2003).
M. Ando, T. Kobayashi, S. Iijima and M. Haruta: Optical CO sensitivity of Au-CuO composite film by use of the plasmon absorption change. Sens. Actuators B 96, 589 (2003).
K. Fukumi, A. Chayahara, K. Kadono, T. Sakaguchi, Y. Horino, M. Miya, K. Fujii, J. Hayakawa and M. Satou: Gold nanoparticles ion implanted in glass with enhanced nonlinear optical properties. J. Appl. Phys. 75, 3075 (1994).
I. Tanahashi, Y. Manabe, T. Tohda, S. Sasaki and A. Nakamura: Optical nonlinearities of Au/SiO2 composite thin films prepared by a sputtering method. J. Appl. Phys. 79, 1244 (1996).
Y. Hosoya, T. Suga, T. Yanagawa and Y. Kurokawa: Linear and nonlinear optical properties of sol-gel-derived Au nanometer-particle-doped alumina. J. Appl. Phys. 81, 1475 (1997).
M. Boulouz, A. Boulouz, A. Giani and A. Boyer: Influence of substrate temperature and target composition on the properties of yttria-stabilized zirconia thin films grown by r.f. reactive magnetron sputtering. Thin Solid Films 323, 85 (1998).
G. Johner and J.K. Schweitzer: Thermal-barrier coatings for jet engine improvement. Thin Solid Films 119, 301 (1984).
S.C. Singhal: Advances in solid oxide fuel cell technology. Solid State Ionics 135, 305 (2000).
C.F. Bohren and D.R. Huffman: Absorption and Scattering of Light by Small Particles (Wiley, New York, 1983), p. 82.
B.D. Cullity and S.R. Stock: Elements of X-ray Diffraction, 3rd ed. (Prentice-Hall, Upper Saddle River, NJ, 2001), p. 388.
A.R.L. Thermo (private communication, 2003).
D.R. Lide: Handbook of Chemistry and Physics, 83rd ed. (CRC Press LLC, Boca Raton, FL, 2002).
G.L. Allen, R.A. Bayles, W.W. Gile and W.A. Jesser: Small particle melting of pure metals. Thin Solid Films 144, 297 (1986).
K. Dick, T. Dhanasekaran, Z. Zhang and D. Meisel: Size-dependent melting of silica- encapsulated gold nanoparticles. J. Am. Chem. Soc. 124, 2312 (2002).
G. De Marchi, G. Mattei, P. Mazzoldi, C. Sada and A. Miotello: Two stages in the kinetics of gold cluster growth in ion-implanted silica during isothermal annealing in oxidizing atmosphere. J. Appl. Phys. 92, 4249 (2002).
N.E. Christensen and B.O. Seraphin: Relativistic band calculation and the optical properties of gold. Phys. Rev. B 4, 3321 (1971).
H. Hövel, S. Fritz, A. Hilger, U. Kreibig and M. Vollmer: Width of cluster plasmon resonances: Bulk dielectric functions and chemical interface damping. Phys. Rev. B 48, 18178 (1993).
B.N.J. Persson: Polarizability of small spherical metal particles: Influence of the matrix environment. Surf. Sci. 281, 153 (1993).
U. Kreibig and M. Vollmer: Optical Properties of Metal Clusters (Springer, New York, 1995).
N.W. Ashcroft and N.D. Mermin: Solid State Physics (Saunders College Publishing, New York, NY, 1976), pp.10.
S. Zafeiratos and S. Kennou: A study of gold ultrathin film growth on yttria-stabilized ZrO2(100). Surf. Sci. 443, 238 (1999).
S. Zafeiratos, S. Neophytides and S. Kennou: A photoelectron spectroscopy study of Au thin films on ZrO2 (100). Thin Solid Films 386, 53 (2001).
V. Kresin: Collective resonances in silver clusters: Role of d electrons and the polarization-free surface layer. Phys. Rev. B 51, 1844 (1995).
B. Palpant, B. Prével, J. Lermé, E. Cottancin, M. Pellarin, M. Treilleux, A. Perez, J.L. Vialle and M. Broyer: Optical properties of gold clusters in the size range 2-4 nm. Phys. Rev. B 57, 1963 (1998).
S. Ferdigo, W. Harbich and J. Buttet: Collective dipole oscillations in small silver clusters embedded in rare-gas matrices. Phys. Rev. B 47, 10706 (1993).
P.B. Johnson and R.W. Christy: Optical constants of the noble metals. Phys. Rev. B 6, 4370 (1972).
D. Dalacu and L. Martinu: Spectroellipsometric characterization of plasma-deposited Au/SiO2 nanocomposite films. J. Appl. Phys. 87, 228 (2000).
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Sirinakis, G., Siddique, R., Monokroussos, C. et al. Microstructure and Optical Properties of Au-Y2O3-stabilized ZrO2 Nanocomposite Films. Journal of Materials Research 20, 2516–2522 (2005). https://doi.org/10.1557/jmr.2005.0300
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DOI: https://doi.org/10.1557/jmr.2005.0300