Abstract
This paper compares the luminescence spectra of Eu3+ in sol-gel derived silica samples heated at different temperatures, following the densification process from wet gel to compact silica glass. Lifetimes, linewidths, and Stark splittings of the transitions were used to study the structural evolution of the gel network.
Similar content being viewed by others
References
A. Wold, J. Chem. Educ. 57, 531 (1980).
A. Rousset, F. Chassagneux, and J. Paris, J. Mater. Sci. 21, 3111 (1986).
C. N. R. Rao and J. Gopalakrishnan, Acc. Chem. Res. 20, 228 (1987).
S. Yajima, Y. Hasegawa, J. Hayashi, and M. Iimura, J. Mater. Sci. 13, 2569 (1978).
F. Aldinger and H. J. Kalz, Angew. Chem. Int. Ed. Engl. 26, 371 (1987).
Sol-gel Technology for Thin Films, Fibers, Preforms, Electronics, and Speciality Shapes, edited by L. C. Klein (Noyes, Park Ridge, NJ, 1988).
C. J. Brinker and G. W. Scherer, Sol-gel Science (Academic Press, San Diego, CA, 1990).
D. R. Ulrich, Chemtech., 242 (1988).
S. Sakka, in Sol-gel Technology for Thin Films, Fibers, Preforms, Electronics, and Speciality Shapes, edited by L. C. Klein (Noyes, Park Ridge, NJ, 1988), p. 140; H. G. Sowman, ibid. p. 162; W. C. La Course, ibid. p. 184.
U. Brenna, G. Carturan, G. Del Felice, M. Mozzon, and R. Dal Maschio, European Patent Application no. 0383 051, 21.01. ‘90.
R. Dal Maschio, G. M. Del Felice, M. Filipponi, G. D. Sorarú, and G. Carturan, Am. Ceram. Soc. Bull, (in press).
H. Dislich, in Sol-gel Technology for Thin Films, Fibers, Preforms, Electronics, and Speciality Shapes, edited by L. C. Klein (Noyes, Park Ridge, NJ, 1988), p. 50; H. Dislich and E. Hussmann, Thin Solid Films 77, 129 (1981).
A. Duran, J. M. Fernández Navarro, P. Mazon, and A. Joglar, J. Non-Cryst. Solids 82, 391 (1986).
F. Orgaz and H. Rawson, J. Non-Cryst. Solids 82, 378 (1986).
R. Dal Maschio, A. Pegoretti, C. Rizzo, G. D. Sorarú, and G. Carturan, J. Am. Ceram. Soc. 72, 2388 (1989).
G. D. Sorarú, Μ. Guglielmi, and R. Dal Maschio, J. Non-Cryst. Solids 100, 440 (1988).
G. Carturan, G. Delia Mea, A. Paccagnella, G. D. Sorarú, and C. Rizzo, J. Non-Cryst. Solids 111, 91 (1989).
A. Maddalena, M. Guglielmi, V. Gottardi, and A. Raccanelli, J. Non-Cryst. Solids 82, 356 (1986).
G. D. Sorarú, A. Ravagni, R. Campostrini, and F. Babonneau, J. Am. Ceram. Soc. (in press).
E. Matijević, Acc. Chem. Res. 14, 22 (1981).
E. Matijević, infrastructure Processing of Ceramics, Glass and Composites, edited by L. L. Hench and D. R. Ulrich (J. Wiley and Sons, New York, 1984), p. 334.
R. Bauer, European Patent Application no. 85 106 752,0 May 31 (1985).
C. J. Gonzales-Oliver, M. Schneider, K. Nawata, and H. Kusano, J. Non-Cryst. Solids 100, 274 (1988).
L. C. Klein, in Sol-gel Technology for Thin Films, Fibers, Preforms, Electronics, and Speciality Shapes (Noyes, Park Ridge, NJ, 1988), p. 382.
S. J. Teichner, Aerogels, edited by J. Fricke (Springer-Verlag, Berlin-Heidelberg, 1986), p. 22.
G. Carturan, G. Facchin, V. Gottardi, and G. Navazio, J. Non-Cryst. Solids 63, 273 (1984).
G. Carturan, R. Campostrini, S. Diré, V. Scardi, and E. De Alteriis, J. Mol. Catal. 57, L13 (1989).
Η. Dislich, P. Hinz, and R. Kaufmann, U. S. Patent no. 3 759 683 and no. 3 847 583, Jender Glasswerk Schott and Gen., Mainz, FRG (1969).
R. Reisfeld, J. Non-Cryst. Solids 121, 254 (1990).
E. J. A. Pope and J. D. Mackenzie, J. Non-Cryst. Solids 106, 236 (1988).
“Glasses and Ceramics from Gels”, Proc 5th Int. Workshop on Glasses and Ceramics from Gels, J. Non Cryst. Solids, 121 (1990).
D. W. Shaefer and K. D. Keefer, Phys. Rev. Lett. 56, 2199 (1986).
R. Vacher, T. Woignier, J. Pelous, and E. Courtens, Phys. Rev. Β 37, 6500 (1988).
J. Dumas, J. Serughetti, J. L. Rousset, A. Boukenter, B. Cham-pagnon, E. Duval, and J. F. Quinson, J. Non-Cryst. Solids 121, 128 (1990).
R. Orbach, Annu. Rev. Mater. Sci. 19, 497 (1989).
A. Boukenter, B. Champagnon, E. Duval, J. Dumas, J. F. Quinson, and J. Serughetti, Phys. Rev. Lett. 57, 2391 (1986).
E. Courtens, J. Pelous, J. Phalippou, R. Vacher, and T. Woignier, Phys. Rev. Lett. 58, 128 (1987).
B. Champagnon, J. L. Rousset, A. Monteil, M. Ferrari, E. Duval, and A. Boukenter, J. de Phys. C7, 48, 529 (1987).
J. Zschokke, Optical Spectroscopy of Glasses (D. Reidel Publ. Company, Dordrecht, The Netherlands, 1986).
A. A. Kaplyanskii and R. M. Macfarlane, Spectroscopy of Solids Containing Rare Earth Ions (North-Holland, Amsterdam, 1987).
M. F. Hanzenkamp and G. Blasse, Chem. Mater. 2, 105 (1990).
D. Levy, R. Reisfeld, and D. Avnir, Chem. Phys. Lett. 109, 593 (1984).
C. Brecher and L. A. Riseberg, Phys. Rev. Β 13, 81 (1976).
J. A. Capobianco, P. P. Proulx, N. Raspa, D. J. Simkin, and D. J. Krashkewich, J. Chem. Phys. 90, 2856 (1989).
G. W. Scherer, S. A. Pardenev, and R. M. Swiateck, J. Non-Cryst. Solids 107, 14 (1988).
G. W. Scherer, J. Non-Cryst. Solids 92, 122 (1987).
J. G. Lierop, A. Huizing, W. C. P. Μ. Meerman, and C. A. M. Mulder, J. Non-Cryst. Solids 82, 265 (1986).
T. Woignier, J. Phalippou, and J. Zarzycki, J. Non-Cryst. Solids 63, 117 (1984).
F. Babonneau, K. Thoerne, and J. D. Mackenzie, Chem. Mater. 1, 554 (1989).
P. Porcher and P. Caro, J. Lumin. 21, 207 (1980).
M. C. Downer, G. W. Burdick, and D. K. Sardar, J. Chem. Phys. 89, 1787 (1988).
G. Blasse, G. J. Dirksen, D. Van Der Voort, Ν. Sabbatini, S. Perathoner, J. M. Lehn, and B. Alpha, Chem. Phys. Lett. 146, 347 (1988).
R. Reisfeld, S. Nathanson, and E. Greenberg, J. Phys. Chem. 80, 2538 (1976).
W. De W. Horrocks, Jr. and D. R. Sudnick, Acc. Chem. Res. 14, 384 (1981).
R. Reisfeld, R. A. Velapoldi, L. Boehm, and M. Ish Shalom, J. Phys. Chem. 75, 3980 (1971).
J. L. Kropp and M. W. Windsor, J. Chem. Phys. 42, 1599 (1965).
R. Dal Maschio, S. Dirè, G. Carturan, S. Enzo, and L. Battezzati, J. Mater. Res. 7, 435 (1992).
T. F. Belliveau and D. J. Simkin, J. Non-Cryst. Solids 110, 127 (1989).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Campostrini, R., Carturan, G., Ferrari, M. et al. Luminescence of Eu3+ ions during thermal densification of SiO2 gel. Journal of Materials Research 7, 745–753 (1992). https://doi.org/10.1557/JMR.1992.0745
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.1992.0745