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The Effect of Silver Ion Occupancy on Hollandite Lattice Structure

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Abstract

The effect of tunnel cations on tunnel size in α-MnO2 structured (hollandite, cryptomelane) materials has long been of interest, as the tunnel size effects catalytic and transport properties. Previous research on the tunnel size has focused on potassium cryptomelane (KxMn8O16). This paper uses synthetic control of silver content in AgxMn8O16 to investigate the effect that tunnel silver occupancy has on the lattice parameters. Materials with silver (x) content between 1.14 and 1.66 were synthesized, synchrotron diffraction and Rietveld Refinement was used to determine lattice parameters. The lattice parameters were found to contract as silver content increases (from 9.774 Å to 9.738 Å), in contrast to previous investigations of other tunnel cations.

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Authors and Affiliations

  1. Department of Materials Science and Chemical Engineering, Stony Brook University, N.Y., 11794, Stony Brook, United Kingdom

    Alexander B. Brady, Esther S. Takeuchi, Amy C. Marschilok & Kenneth J. Takeuchi

  2. Department of Chemistry, Stony Brook University, N.Y., 11794, Stony Brook, United Kingdom

    Jianping Huang, Jessica L. Durham, Esther S. Takeuchi, Amy C. Marschilok & Kenneth J. Takeuchi

  3. National Synchrotron Light Source II, Brookhaven National Laboratory, New York, 11973, Upton, United Kingdom

    Paul F. Smith

  4. Energy and Photon Sciences Directorate, Brookhaven National Laboratory, N. Y., 11973, Upton, United Kingdom

    Jianming Bai, Esther S. Takeuchi & Amy C. Marschilok

Authors
  1. Alexander B. Brady
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  2. Jianping Huang
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  3. Jessica L. Durham
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  4. Paul F. Smith
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  5. Jianming Bai
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  6. Esther S. Takeuchi
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  7. Amy C. Marschilok
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  8. Kenneth J. Takeuchi
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Corresponding authors

Correspondence to Amy C. Marschilok or Kenneth J. Takeuchi.

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Brady, A.B., Huang, J., Durham, J.L. et al. The Effect of Silver Ion Occupancy on Hollandite Lattice Structure. MRS Advances 3, 547–552 (2018). https://doi.org/10.1557/adv.2018.238

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