Abstract
Graft copolymerization technique was used to synthesize novel biopolymer based terpolymeric hydrogels of xanthan gum (Gx), acrylic acid and N-Isopropyl acrylamide (NIPAM) by using chemical crosslinker N,N′-methylene bisacrylamide (MBA), ammonium persulphate (APS) as a redox initiator and sodium dodecyl sulphate (SDS) for particle size stabilization. The synthesized hydrogels were characterized through FT-IR and SEM techniques, which confirmed the hydrogels formation. Detailed rheology was investigated through applying various rheological models like Bingham model, modified Bingham model and Ostwald power law model to the hydrogels which revealed that the hydrogels were appeared to have shear thinning, non-Newtonian behavior and more elastic. Modified Bingham model provided best fit understanding to our prepared materials. The maximum activation energy (Ea) 13.87 kJ/mol was obtained for composition having more Gx compared to others, showing a strong relationship with viscosity. The hydrogels has potential to find applications in food industry, cosmetics, degradation of dyes and removal of heavy metals from waste water.
Acknowledgement
The authors are highly thankful to Higher Education Commission of Pakistan for financial support.
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