Abstract
The removal of Methylene blue (MB) from aqueous medium using alkaline modified Maclura pomifera (NaOH-MMP) has been studied in this work. Results showed that a pH value of 6 was favorable for the adsorption of MB. Rate constants of pseudo-first-order, pseudo-second-order and nth kinetic model were determined to analyze the dynamic of the adsorption process; they showed that adsorption kinetics followed a pseudo-second-order and nth kinetic models. The Sips isotherm model was found to be the most relevant to describe MB sorption onto NaOH-MMP with a correlation factor R2 > 0.999. The adsorption capacity of NaOH-MMP was found to be 160 mg g−1 at 25 °C, confirming its biosorbent efficiency for the removal of MB dye from aqueous solutions. Thermodynamic parameters indicated that the MB adsorption onto adsorbent was feasible in nature, spontaneous, and exothermique.
References
Aharoni, C., and F. Tompkins. 1970. “Advances in Catalysis and Related Subjects.,” edited by D. D. Eley, H. Pines, and P. B. Weisz, Vol. 21, 1–49. New York: Academic Press.Search in Google Scholar
Akkaya, G., and F. Güzel. 2014. “Application of Some Domestic Wastes as New Low-Cost Biosorbents for Removal of Methylene Blue: Kinetic and Equilibrium Studies.” Chemical Engineering Communication 201: 557–78.10.1080/00986445.2013.780166Search in Google Scholar
Aksu, Z., and S. Tezer. 2005. “Application of Biosorption for the Removal of Organic Pollutants. A Review.” Process Biochemestry 40: 1347–67.10.1016/j.procbio.2004.04.008Search in Google Scholar
Azizian, S., and H. Bashiri. 2008. “Adsorption Kinetics at the Solid/Solution Interface: Statistical Rate Theory at Initial Times of Adsorption and Close to Equilibrium.” Langmuir 24 (20): 11669–76.10.1021/la802288pSearch in Google Scholar
Baban, A., A. Yediler, and N.K. Ciliz. 2010. “Integrated Water Management and CP Implementation for Wool and Textile Blend Processes.” Clean – Soil, Air, Water 38 (1): 84–90.10.1002/clen.200900102Search in Google Scholar
Banat, I.M., P. Nigam, D. Singh, and R. Merchant. 1996. “Microbial Decolorization of Textile Dye Containing Effluents: A Review.” Bioresource Technology 58: 217–27.10.1016/S0960-8524(96)00113-7Search in Google Scholar
Bland, J.M., and D.G. Altman. 1996. “Statistics Notes: Measurement Error.” BMJ 312 (7047): 1654.10.1136/bmj.312.7047.1654Search in Google Scholar PubMed PubMed Central
Bouguettoucha, A., D. Chebli, T. Mekhalef, A. Noui, and A. Amrane. 2015. “The Use of a Forest Waste Biomass, Cone of Pinus Brutia for the Removal of an Anionic Azo Dye Congo Red from Aqueous Medium.” Desalination and Water Treatment 55: 1956–65.10.1080/19443994.2014.928235Search in Google Scholar
Bouguettoucha, A., A. Reffas, D. Chebli, T. Mekhalif, and A. Amrane. 2016. “Novel Activated Carbon Prepared from an Agricultural Waste, Stipa Tenacissima, Based on ZnCl2 Activation—Characterization and Application to the Removal of Methylene Blue.” Desalination and Water Treatment 57: 24056–69.10.1080/19443994.2015.1137231Search in Google Scholar
Bounaas, M., A. Bouguettoucha, D. Chebli, A. Reffas, I. Harizi, F. Rouabah, and A. Amrane. 2018. “High Efficiency of Methylene Blue Removal Using a Novel Low Cost Acid Treated Forest Wastes, Cupressus Semperirens Cones: Experimental Results and Modeling.” Particulate Science and Technology. https://doi.org/10.1080/02726351.2017.1401569.Search in Google Scholar
Brdar, M.M., A.A. TakacˇI, M.B. Sˇc´Iban, and D.Z. Rakic. 2012. “Isotherms for the Adsorption of Cu(II) onto Lignin-Comparison of Linear and Non-Linear Methods.” Hemijiska Industrija 66: 497–503.10.2298/HEMIND111114003BSearch in Google Scholar
Çelekli, A., and F. Geyik. 2011. “Artificial Neural Networks (ANN) Approach for Modeling of Removal of Lanaset Red G on Characontraria.” Bioresource Technology 102: 5634–38.10.1016/j.biortech.2011.02.052Search in Google Scholar
Chebli, D., A. Bouguettoucha, T. Mekhalif, S. Nacef, and A. Amrane. 2015. “Valorization of Agricultural Waste, Stipa Tenacissima Fibers, by Biosorption of an Anionic Azo-Dye Congo Red.” Desalination and Water Treatment. 54: 245–54.10.1080/19443994.2014.880154Search in Google Scholar
Chebli, D., A. Bouguettoucha, A. Reffas, C. Tiar, M. Boutahala, H. Gulyas, and A. Amrane. 2016. “Removal of the Anionic Dye Biebrich Scarlet from Water by Adsorption to Calcined and Non-Calcined MgAl Layered Double Hydroxides.” Desalination and Water Treatment 57 (46): 22061–73.10.1080/19443994.2015.1128365Search in Google Scholar
Cheng, S., L. Zhang, H. Xia, J. Peng, J. Shu, C. Li, X. Jiang, and Q. Zhang. 2017. “Adsorption Behavior of Methylene Blue onto Waste Derived Adsorbent and Exhaust Gases Recycling.” RSC Advances 7: 27331–41.10.1039/C7RA01482ASearch in Google Scholar
Chowdhury, S., and P. Saha. 2010. “Sea Shell Powder as a New Adsorbent to Remove Basic Green 4 (Malachite Green) from Aqueous Solutions: Equilibrium, Kinetic and Thermodynamic Studies.” Chemical Engineering Journal 164: 168–77.10.1016/j.cej.2010.08.050Search in Google Scholar
Chung, K.T., and C.E. Cerniglia. 1992. “Mutagenicity of Azo Dyes: Structure–Activity Relationship.” Mutation Research 77: 201–20.10.1016/0165-1110(92)90044-ASearch in Google Scholar
Crini, G. 2006. “Non-Conventional Low-Cost Adsorbents for Dye Removal: A Review.” Bioresource Technology 97: 1061–85.10.1016/j.biortech.2005.05.001Search in Google Scholar PubMed
Demirbas, A. 2009. “Agricultural Based Activated Carbons for the Removal of Dyes from Aqueous Solutions: A Review.” Journal of Hazardous Materials 167: 1–9.10.1016/j.jhazmat.2008.12.114Search in Google Scholar PubMed
Dotto, G.L., E.C. Lima, and L.A.A. Pinto. 2012. “Biosorption of Food Dyes onto Spirulina Platensis Nanoparticles: Equilibrium Isotherm and Thermodynamic Analysis.” Bioresource Technology 103: 123–30.10.1016/j.biortech.2011.10.038Search in Google Scholar PubMed
Dotto, G.L., and L.A.A. Pinto. 2011. “Adsorption of Food Dyes onto Chitosan: Optimization Process and Kinetic.” Carbohydrate Polymers 84: 231–38.10.1016/j.carbpol.2010.11.028Search in Google Scholar
Dotto, G.L., M.L.G. Vieira, V.M. Esquerdo, and L.A.A. Pinto. 2013. “Equilibrium and Thermodynamics of Azo Dyes Biosorption onto Spirulina Platensis.” Brazilian Journal of Chemical Engineering 30: 13–21.10.1590/S0104-66322013000100003Search in Google Scholar
Enamul, H., W.J. Jong, and H.J. Sung. 2011. “Adsorptive Removal of Methyl Orange and Methylene Blue from Aqueous Solution with a Metal-Organic Framework Material, Iron Terephthalate (MOF-235).” Journal of Hazardous Materials 11: 185–507.Search in Google Scholar
Freundlich, H.M.F. 1906. “Ober Dies Adsorption in Losungen (About Adsorption in Solution).” Zeitschrift für Physikalische Chemie 57: 385–470.Search in Google Scholar
Gorzin, F., and MM B. R. Abadi. 2017. “Adsorption of Cr(VI) from Aqueous Solution by Adsorbent Prepared from Paper Mill Sludge: Kinetics and Thermodynamics Studies.” Adsorption Science and Technology 0 (0): 1–21.10.1177/0263617416686976Search in Google Scholar
Gündüz, F., and B. Bayrak. 2017. “Biosorption of Malachite Green from an Aqueous Solution Using Pomegranate Peel: Equilibrium Modelling, Kinetic and Thermodynamic Studies.” Journal of Molecular Liquid. https://doi.org/10.1016/j.molliq.2017.08.095.Search in Google Scholar
Hameed, B.H., and A.A. Ahmad. 2009. “Batch Adsorption of Methylene Blue from Aqueous Solution by Garlic Peel, an Agricultural Waste Biomass.” Journal of Hazardous Materials 164: 870–75.10.1016/j.jhazmat.2008.08.084Search in Google Scholar PubMed
Hameed, B.H., I.A.W. Tan, and A.L. Ahmad. 2008. “Adsorption Isotherm, Kinetic Modeling and Mechanism of 2,4,6-Trichlorophenol on Coconut Husk-Based Activated Carbon.” Chemical Engineering Journal 144: 235–44.10.1016/j.cej.2008.01.028Search in Google Scholar
Jayaranjan, M., R. Arunachalam, and G. Annadurai. 2011. “Use of Low Cost Nano –Porous Materials of Pamelo Fruit Peel Wastes in Removal of Textile Dye.” Research Journal of Environmental Science China 55: 434–43.10.3923/rjes.2011.434.443Search in Google Scholar
Kaur, H., and A. Thakur. 2014. “Adsorption of Congo Red Dye from Aqueous Solution onto Ash of Cassia Fistula Seeds: Kinetic and Thermodynamic Studies.” Chemical Science Review and Letters 3 (11S): 159–69.Search in Google Scholar
Kolekar, Y.M., S.P. Pawar, K.R. Gawai, P.D. Lokhande, Y.S. Schouche, and K.M. Kodam. 2008. “Decolorization and Degradation of Disperse Blue 79 and Acid Orange 10 by Bacillus Fusiformis KMK5 Isolated from the Textile Dye Contaminated Soil.” Bioresource Technology 99: 8999–9003.10.1016/j.biortech.2008.04.073Search in Google Scholar PubMed
Kumar, K.V. 2006. “Linear and Non-Linear Regression Analysis for the Sorption Kinetics of Methylene Blue onto Activated Carbon.” Journal of Hazardous Materials B 137: 1538–44.10.1016/j.jhazmat.2006.04.036Search in Google Scholar PubMed
Lagergren, S. 1898. “Zur Theorie Der Sogenannten Adsorption Gelo ¨Ster Stoffe (On the Theory of So-Called Adsorption of Solutes), K. Sven. Vetenskapsakad.” Handlingar 24: 1–39.Search in Google Scholar
Langmuir, I. 1918. “The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum.” Journal of American Chemical Society 40: 1361–403.10.1021/ja02242a004Search in Google Scholar
Liu, C.H., J.S. Wu, H.C. Chiu, S.Y. Suen, and K.H. Chu. 2007. “Removal of Anionic Reactive Dyes from Water Using Anion Exchange Membranes as Adsorbers.” Water Research 41: 1491–500.10.1016/j.watres.2007.01.023Search in Google Scholar PubMed
Ma, J., Y. Jia, Y. Jing, Y. Yao, and J. Sun. 2011. “Kinetics and Thermodynamics of Methylene Blue Adsorption by Cobalt-Hectorite Composite.” Dyes and Pigments 93 (1-3): 1441–46.10.1016/j.dyepig.2011.08.010Search in Google Scholar
Mahadeva Swamy, M., B.M. Nagabhushana, R. Hari Krishna, Nagaraju Kottam, R.S. Raveendra, and P.A. Prashanth. 2017. “Fast Adsorptive Removal of Methylene Blue Dye from Aqueous Solution onto a Wild Carrot Flower Activated Carbon: Isotherms and Kinetics Studies.” Desalination and Water Treatment 71: 399–405.10.5004/dwt.2017.20520Search in Google Scholar
Marofi, S., M. A. Zare, and Y. Krimi. 2017. “Methylene Blue Removal from Aqueous Media Using Tassel Adsorbent.” Water Science and Technology. https://doi.org/10.2166/wst.2017.347. in press 2017.Search in Google Scholar
Milonjic, S. K. 2007. “A Consideration of the Correct Calculation of Thermodynamic Parameters of Adsorption.” Journal of Serbeian Chemical Society 72: 1363–67.10.2298/JSC0712363MSearch in Google Scholar
Miyah, Y., A. Lahrichi, M. Idrissi, S. Boujraf, H. Taouda, and F. Zerrouq. 2017. “Assessment of Adsorption Kinetics for Removal Potential of Crystal Violet Dye from Aqueous Solutions Using Moroccan Pyrophyllite.” Journal of the Association of Arab Universities for Basic and Applied Sciences 23: 20–28.10.1016/j.jaubas.2016.06.001Search in Google Scholar
Mohammed, M.A., A. Shitu, and A. Ibrahim. 2014. “Removal of Methylene Blue Using Low Cost Adsorbent. A Review.” Research Journal of Chemical Science 4 (1): 91–102.Search in Google Scholar
Myers, D. 1999. Surfaces, Interfaces, and Colloids: Principles and Applications, 2nd ed., 187–90. New York: John Wiley & Sons, Inc.10.1002/0471234990Search in Google Scholar
Nasuha, N., and B.H. Hameed. 2011. “Adsorption of Methylene Blue from Aqueous Solution onto NaOH-modified Rejected Tea.” Chemical Engineering Journal 166: 783–86.10.1016/j.cej.2010.11.012Search in Google Scholar
Oladipo, A.A., M. Gazi, and S. Saber-Samandari. 2014. “Adsorption of Anthraquinone Dye onto Ecofriendly semi-IPN Biocomposite Hydrogel: Equilibrium Isotherms, Kinetic Studies and Optimization.” Journal of Taiwan Institute of Chemical Engineering 45: 653–64.10.1016/j.jtice.2013.07.013Search in Google Scholar
Özcan, A.S., E. M. Öncü, and A. Özcan. 2005. “Kinetics, Isotherm and Thermodynamic Studies of Adsorption of Acid Blue 193 from Aqueous Solutions onto BTMA–Bentonite.” Colloids and Surfaces A: Physicochemical and Engineering Aspects 266: 73–81.10.1016/j.colsurfa.2005.06.001Search in Google Scholar
Patel, R., and S. Suresh. 2008. “Kinetic and Equilibrium Studies on the Biosorption of Reactive Black 5 Dye by Aspergillus Foetidus.” Bioresource Technology 99: 51–58.10.1016/j.biortech.2006.12.003Search in Google Scholar PubMed
Pavan, F. A., E. S. Camacho, E. C. Lima, G. L. Dotto, V. T. A. Branco, and S. L. P. Dias. 2014. “Formosa Papaya Seed Powder (FPSP): Preparation, Characterization and Application as an Alternative Adsorbent for the Removal of Crystal Violet from Aqueous Phase.” Journal of Environmental Chemical Engineering 2: 230–38.10.1016/j.jece.2013.12.017Search in Google Scholar
Petrova, B., T. Budinova, B. Tsyntsarski, V. Kochkodan, Z. Shkavro, and N. Petrov. 2010. “Removal of Aromatic Hydrocarbons from Water by Activated Carbon from Apricot Stones.” The Chemical Engineering Journal 165: 258–64.10.1016/j.cej.2010.09.026Search in Google Scholar
Rahchamani, J., H.Z. Mousavi, and M. Behzad. 2011. “Adsorption of Methyl Violet from Aqueous Solution by Polyacrylamide as an Adsorbent: Isotherm and Kinetic Studies.” Desalination 267: 256–60.10.1016/j.desal.2010.09.036Search in Google Scholar
Ramakrishnaiahand, C. R., and D.N. Arpitha. 2014. “Removal of Colour from Textile Effluent by Adsorption Using Low Cost Adsorbents.” International Research Journal of Pure and Applied Chemistry 4 (5): 568–77.10.9734/IRJPAC/2014/5772Search in Google Scholar
Ramaraju, B., P. Manoj, K. Reddy, and C. Subrahmanyam. 2014. “Low Cost Adsorbents from Agricultural Waste for Removal of Dyes.” Environmental Progress and Sustainable Energy 33 (1): 38–46.10.1002/ep.11742Search in Google Scholar
Reddy, M. C. S. 2006. “Removal of Direct Dye from Aqueous Solutions with an Adsorbent Made from Tamarind Fruit Shell, an Agricultural Solid Waste.” The American Journal of Scientific and Industrial Research 65: 443–46.Search in Google Scholar
Reffas, A., A. Bouguettoucha, D. Chebli, and A. Amrane. 2016. “Adsorption of Ethyl Violet Dye in Aqueous Solution by Forest Wastes, Wild Carob.” Desalination and Water Treatment 57: 9859–70.10.1080/19443994.2015.1031707Search in Google Scholar
Richard, D., M. de Lourdes Delgado Nú˜nez, and D. Schweich. 2009. “Adsorption of Complex Phenolic Compounds on Active Charcoal: Adsorption Capacity and Isotherms.” Chemical Engineering Journal 148: 1–7.10.1016/j.cej.2008.07.023Search in Google Scholar
Robinson, T., G. McMullan, R. Marchant, and P. Nigam. 2001. “Remediation of Dyes in Textile Effluent: A Critical Review on Current Treatment Technologies with a Proposed Alternative.” Bioresource Technology 77: 247–55.10.1016/S0960-8524(00)00080-8Search in Google Scholar
Russo, M.E., F. Natale Di, V. Prigione, V. Tigini, A. Marzocchella, and G.C. Varese. 2010. “Adsorption of Acid Dyes on Fungal Biomass: Equilibrium and Kinetics Characterization.” The Chemical Engineering Journal 162: 537–45.10.1016/j.cej.2010.05.058Search in Google Scholar
Saha, P., S. Chowdhury, S. Gupta, and I. Kumar. 2010. “Insight into Adsorption Equilibrium, Kinetics and Thermodynamics of Malachite Green onto Clayey Soil of Indian Origin.” Chemical Engineering Journal 165: 874–82.10.1016/j.cej.2010.10.048Search in Google Scholar
Saygili, H., G. Akkaya Saygili, and F. Güzel. 2014. “Using Grape Pulp as a New Alternative Biosorbent for Removal of a Model Basic Dye.” Asia-Pacific Journal of Chemical Engineering 9: 214–25.10.1002/apj.1761Search in Google Scholar
Soloman, P.A., C.A. Basha, V. Ramamurthi, K. Koteeswaran, and N. Balasubramanian. 2009. “Electrochemical Degradation of Remazol Black B Dye Effluent.” Clean – Soil, Air, Water 37 (11): 889–900.10.1002/clen.200900055Search in Google Scholar
Srivastava, V. C., I. D. Mall, and I. M. Mishra. 2008. “Characterization of Mesoporous Rice Husk Ash (RHA) and Adsorption Kinetics of Metal Ions from Aqueous Solution onto RHA.” Journal of Hazardous Materials 134: 257–67.10.1016/j.jhazmat.2005.11.052Search in Google Scholar PubMed
Tan, I. A.W., B.H. Hameed, and A.L Ahmad. 2007. “Equilibrium and Kinetic Studies on Basic Dye Adsorption by Oil Palm Fibre Activated Carbon.” Chemical Engineering Journal 127: 111–19.10.1016/j.cej.2006.09.010Search in Google Scholar
Ting, L., L.Guobin, W. Haijun, and D. Sun. 2016. “Experimental Observation of Cross Correlation between Tangential Friction Vibration and Normal Friction Vibration in a Running-In Process.” Tribiology international. https://doi.org/10.1016/j.triboint.2016.01.018.Search in Google Scholar
Tseng, R.L., P. H. Wu, F.C. Wu, and R.S. Juang. 2014. “A Convenient Method to Determine Kinetic Parameters of Adsorption Processes by Nonlinear Regression of Pseudo-Nth-Order Equation.” Chemical Engineering Journal 237: 153–61.10.1016/j.cej.2013.10.013Search in Google Scholar
Venkat, S.M., and B.P.V. Vijay. 2013. “Kinetic and Equilibrium Studies on the Removal of Congo Red from Aqueous Solution Using Eucalyptus Wood (Eucalyptus Globulus) Sawdust.” Journal of Taiwan Institute of Chemical Engineering 8: 44–81.Search in Google Scholar
Vieira, S.S., Z.M. Magriotis, N.A.V. Santos, M. Das Gracas Cardoso, and A.A. Saczk. 2012. “Macauba Palm (Acrocomia Aculeata) Cake from Biodiesel Processing: An Efficient and Low Cost Substrate for the Adsorption of Dyes.” Chemical Engineering Journal 183: 152–61.10.1016/j.cej.2011.12.047Search in Google Scholar
Vmonses, V., Lei, S., B. Jin, C.W.K. Chow, and C. Saint. 2009. “Kinetic study and equilibrium isotherm analysis of Congo Red adsorption by clay materials.” Chem. Eng. J. 148: 354–364.10.1016/j.cej.2008.09.009Search in Google Scholar
Yang, Y., G. Wang, B. Wang, Z. Li, X. Jia, Q. Zhou, and Y. Zhao. 2011. “Biosorption of Acid Black 172 and Congo Red from Aqueous Solution by Nonviable Penicillium YW 01: Kinetic Study, Equilibrium Isotherm and Artificial Neural Network Modeling.” Bioresource Technology 102: 828–34.10.1016/j.biortech.2010.08.125Search in Google Scholar PubMed
Yao, Z., L. Wang, and J. Qi. 2009. “Biosorption of Methylene Blue from Aqueous Solution Using a Bioenergy Forest Waste: Xanthoceras Sorbifolia Seed Coat.” Clean Soil Air Water 37: 642–48.10.1002/clen.200900093Search in Google Scholar
Yasemin, B., and A. Haluk. 2006. “A Kinetics and Thermodynamics Study of Methylene Blue Adsorption on Wheat Shells.” Desalination 194: 259–67.10.1016/j.desal.2005.10.032Search in Google Scholar
Yu, D., and L. Sparks. 2010. Kinetics of Soil Chemical Processes. New York: (1989) Academic Press.Search in Google Scholar
© 2019 Walter de Gruyter GmbH, Berlin/Boston