Abstract
Bamboo fibers (BFs) are abundant but underutilized as reinforcing fibers in wood plastic composites (WPCs). BFs were investigated as reinforcing fibers for unsaturated polyester (UPE) composites (BF-UPE). The UPE was prepared from condensation polymerization of propylene glycol (PG), isophthalic acid (IPA) and maleic anhydride (MA). Acrylated epoxidized soybean oil (AESO) was used instead of styrene which is usually applied as a diluent in most of the commercial UPE resins. The properties of BF-UPE were compared with those of kenaf fibers-UPE (KF-UPE). BF-AESO-UPE composites had tensile strengths (TSs), which were comparable to those of BF-styrene-UPE composites, while their flexural strength (FS) and impact strength (IS) were higher than those of BF-styrene-UPE composites. The glass transition temperature (Tg) of BF-AESO-UPE composites was lower than that of BF-styrene-UPE composites. BF-AESO-UPE composites had lower TS than KF-AESO-UPE composites, while their FS was comparable to that of KF-AESO-UPE composites.
Funding source: National Natural Science Foundation of China
Award Identifier / Grant number: 31670568
Funding source: Fujian Agriculture and Forestry University, China
Award Identifier / Grant number: KXB16007A
Funding statement: The authors thank for the funding granted to Qiu from the National Natural Science Foundation of China (Funder Id: 10.13039/501100001809, grant no. 31670568) and Fujian Agriculture and Forestry University, China (Funder Id: 10.13039/501100008766, grant no. KXB16007A).
Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Employment or leadership: None declared.
Honorarium: None declared.
References
Abdul Khalil, H.P.S., Bhat, I.U.H., Jawaid, M., Zaidon, A., Hermawan, D., Hadi, Y.S. (2012) Bamboo fibre reinforced biocomposites: a review. Mater. Design 42:353–368.10.1016/j.matdes.2012.06.015Search in Google Scholar
Akil, H.M., Santulli, C., Sarasini, F., Tirillò, J., Valente, T. (2014) Environmental effects on the mechanical behaviour of pultruded jute/glass fibre-reinforced polyester hybrid composites. Compos. Sci. Technol. 94:62–70.10.1016/j.compscitech.2014.01.017Search in Google Scholar
Alfrey, T., Price, C.C. (1947) Relative reactivities in vinyl copolymerization. J. Polym. Sci. 2:101–106.10.1002/pol.1947.120020112Search in Google Scholar
ASTM D3039/D3039M‒17 Standard test method for tensile properties of polymer matrix composite materials.Search in Google Scholar
ASTM D790‒03 Standard test methods for flexural properties of unreinforced and reinforced plastics and electrical insulating materials.Search in Google Scholar
ASTM D7028‒07 (2015) Standard test method for glass transition temperature (DMA Tg) of polymer matrix composites by dynamic mechanical analysis (DMA).Search in Google Scholar
Brostrom, J., Boss, A., Chronakis, I.S. (2004) Biodegradable films of partly branched poly(L-lactide)-co-poly(ε-caprolactone) copolymer: modulation of phase morphology, plasticization properties and thermal depolymerization. Biomacromolecules 5:1124–1134.10.1021/bm049920qSearch in Google Scholar PubMed
Chattopadhyay, S.K., Khandal, R., Uppaluri, R., Ghoshal, A.K. (2011) Bamboo fiber reinforced polypropylene composites and their mechanical, thermal, and morphological properties. J. Appl. Polym. Sci. 119:1619–1626.10.1002/app.32826Search in Google Scholar
Cousinet, S., Ghadban, A., Fleury, E., Lortie, F., Pascault, J.P., Portinha, D. (2015) Toward replacement of styrene by bio-based methacrylates in unsaturated polyester resins. Eur. Polym. J. 67:539–550.10.1016/j.eurpolymj.2015.02.016Search in Google Scholar
Fuentes, C.A., Ting, K.W., Dupont-Gillain, C., Steensma, M., Talma, A.G., Zuijderduin, R., Van Vuure, A.W. (2016) Effect of humidity during manufacturing on the interfacial strength of non-pre-dried flax fibre/unsaturated polyester composites. Compos. Part A 84:209–215.10.1016/j.compositesa.2016.01.023Search in Google Scholar
Hojo, T., Xu, Z., Yang, Y., Hamada, H. (2014) Tensile properties of bamboo, jute and kenaf mat-reinforced composite. Energy Procedia 56:72–79.10.1016/j.egypro.2014.07.133Search in Google Scholar
ISO 179-1 2010 Plastics‒Determination of Charpy impact properties. Part 1 Non-instrumented impact test.Search in Google Scholar
Johnson, K.G., Yang, L.S. (2004) Preparation, properties and applications of unsaturated polyesters. In: Modern Polyesters: Chemistry and Technology of Polyesters and Copolyesters. Eds. Scheirs, J., Long, T.E. John Wiley & Sons, Chichester, UK. pp. 697–713.10.1002/0470090685.ch21Search in Google Scholar
Kandelbauer, A., Tondi, G., Goodman, S.H. (2014) Unsaturated polyesters and vinyl esters. In: Handbook of Thermoset Plastics, 3rd edition. Eds. Hanna, D., Sydney, H.G. William Andrew Publications: San Diego, CA, USA. pp. 111–172.10.1016/B978-1-4557-3107-7.00006-3Search in Google Scholar
Kim, H., Okubo, K., Fujii, T., Takemura, K. (2013) Influence of fiber extraction and surface modification on mechanical properties of green composites with bamboo fiber. J. Adhes. Sci. Technol. 27:1348–1358.10.1080/01694243.2012.697363Search in Google Scholar
La Scala, J.J., Sands, J.M., Orlicki, J.A., Robinette, E.J., Palmese, G.R. (2004) Fatty acid-based monomers as styrene replacements for liquid molding resins. Polymer 45:7729–7737.10.1016/j.polymer.2004.08.056Search in Google Scholar
Liu, W., Chen, T., Wen, X., Qiu, R., Zhang, X. (2014) Enhanced mechanical properties and water resistance of bamboo fiber-unsaturated polyester composites coupled by isocyanatoethyl methacrylate. Wood Sci. Technol. 48:1241–1255.10.1007/s00226-014-0668-6Search in Google Scholar
Liu, W., Chen, T., Xie, T., Lai, F., Qiu, R. (2015a) Oxygen plasma treatment of bamboo fibers (BF) and its effects on the static and dynamic mechanical properties of BF-unsaturated polyester composites. Holzforschung 69:449–455.10.1515/hf-2014-0097Search in Google Scholar
Liu, W., Xie, T., Qiu, R., and Fan, M. (2015b) N-methylol acrylamide grafting bamboo fibers and their composites. Compos. Sci. Technol. 117:100–106.10.1016/j.compscitech.2015.06.005Search in Google Scholar
Liu, W., Xie, T., Qiu, R. (2015c) Styrene-free unsaturated polyesters for hemp fibre composites. Compos. Sci. Technol. 120:66–72.10.1016/j.compscitech.2015.10.017Search in Google Scholar
Liu, W., Xie, T., Qiu, R. (2017) Biobased thermosets prepared from rigid isosorbide and flexible soybean oil derivatives. ACS Sustain. Chem. Eng. 5:774–783.10.1021/acssuschemeng.6b02117Search in Google Scholar
Ma, Q., Liu, X., Zhang, R., Zhu, J., Jiang, Y. (2013) Synthesis and properties of full bio-based thermosetting resins from rosin acid and soybean oil: the role of rosin acid derivatives. Green Chem. 15:1300–1310.10.1039/c3gc00095hSearch in Google Scholar
Malik, M., Choudhary, V., Varma, I. (2000) Current status of unsaturated polyester resins. J. Macromol. Sci. Part C 40:139–165.10.1081/MC-100100582Search in Google Scholar
Qiu, R., Liu, W., Li, K. (2015) Investigation of bamboo pulp fiber-reinforced unsaturated polyester composites. Holzforschung 69:967–974.10.1515/hf-2014-0207Search in Google Scholar
Ratna, D. (2009) In: Handbook of Thermoset Resins. Smithers Rapra Technology. Shropshire, UK. pp. 83–99.Search in Google Scholar
Ratna Prasad, A., Mohana Rao, K. (2011) Mechanical properties of natural fibre reinforced polyester composites: jowar, sisal and bamboo. Mater. Design 32:4658–4663.10.1016/j.matdes.2011.03.015Search in Google Scholar
Sawpan, M.A., Pickering, K.L., Fernyhough, A. (2012) Flexural properties of hemp fibre reinforced polylactide and unsaturated polyester composites. Compos. Part A 43:519–526.10.1016/j.compositesa.2011.11.021Search in Google Scholar
Tran, D., Nguyen, D., Ha Thuc, C., Dang, T. (2013) Effect of coupling agents on the properties of bamboo fiber-reinforced unsaturated polyester resin composites. Compos. Interfaces 20:343–335.10.1080/15685543.2013.806100Search in Google Scholar
U.S. Department of Health and Human Services, Public Health Services. National Toxicology Program 12th Report on Carcinogens, 2011.Search in Google Scholar
Wong, K., Zahi, S., Low, K., Lim, C. (2010) Fracture characterisation of short bamboo fibre reinforced polyester composites. Mater. Design 31:4147–4154.10.1016/j.matdes.2010.04.029Search in Google Scholar
Wu, Y., Li, K. (2016) Replacement of styrene with acrylated epoxidized soybean oil in an unsaturated polyester resin from propylene glycol, isophthalic acid, and maleic anhydride. J. Appl. Polym. Sci. 133:43052.10.1002/app.43052Search in Google Scholar
Zamri, M.H., Md Akil, H., Mohd Ishak, Z., Abu Bakar, A. (2015) Effect of different fiber loadings and sizes on pultruded kenaf fiber reinforced unsaturated polyester composites. Polym. Compos. 36:1224–1229.10.1002/pc.23025Search in Google Scholar
©2019 Walter de Gruyter GmbH, Berlin/Boston