Abstract
A cadmium–mercury mixed-metal complex of cis-2-((2-((2-hydroxyethyl)amino)ethyl)amino)cyclohexan-1-ol (HEAC), [Cd(HEAC)2][HgI4] (1), was prepared and identified by elemental analysis, FT-IR, 1H NMR spectroscopy, and single-crystal X-ray diffraction. The X-ray analysis revealed an ionic structure for 1 in which the cadmium and mercury atoms have CdN4O2 and HgI4 environments, with distorted octahedral and tetrahedral geometries, respectively. The packing of the components in the crystal of 1 is supported by O–H···I hydrogen bonds, and these interactions lead to the formation of an
Acknowledgment
This study was supported financially by the Iran National Science Foundation (INSF).
References
[1] R. Yendapally, R. E. Lee, Bioorg. Med. Chem. Lett.2008, 18, 1607.10.1016/j.bmcl.2008.01.065Search in Google Scholar
[2] I. Declerck, B. Himpens, G. Droogmans, R. Casteels, Pfluegers Arch.1990, 417, 117.10.1007/BF00370780Search in Google Scholar
[3] M. M. Weinberger, Pediatr. Clin. North Am.1975, 22, 121.10.1016/S0031-3955(16)33107-8Search in Google Scholar
[4] S. J. Kwon, S. Y. Ko, Tetrahedron Lett.2002, 43, 639.10.1016/S0040-4039(01)02206-7Search in Google Scholar
[5] D. J. Ager, I. Prakash, D. R. Schaad, Chem. Rev.1996, 96, 835.10.1021/cr9500038Search in Google Scholar PubMed
[6] A. G. Myers, B. H. Yang, H. Chen, L. Mckinstry, D. J. Kopecky, J. L. Gleason, J. Am. Chem. Soc.1997, 119, 6496.10.1021/ja970402fSearch in Google Scholar
[7] A. J. Hunt, E. H. Sin, R. Marriott, J. H. Clark, ChemSusChem2010, 3, 306.10.1002/cssc.200900169Search in Google Scholar PubMed
[8] J. E. Rainbolt, P. K. Koech, C. R. Yonker, F. Zheng, D. Main, M. L. Weaver, J. C. Linehan, D. J. Heldebrant, Energ. Environ. Sci.2011, 4, 480.10.1039/C0EE00506ASearch in Google Scholar
[9] T. Werner, N. Tenhumberg, J. CO2 Util.2014, 7, 39.10.1016/j.jcou.2014.04.002Search in Google Scholar
[10] F. H. Allen, Acta Crystallogr.2002, B58, 380.10.1107/S0108768102003890Search in Google Scholar PubMed
[11] M. Hakimi, Z. Mardani, K. Moeini, F. Mohr, M. A. Fernandes, Polyhedron2014, 67, 27.10.1016/j.poly.2013.08.065Search in Google Scholar
[12] M. Hakimi, Z. Mardani, K. Moeini, M. A. Fernandes, J. Coord. Chem.2012, 65, 2221.10.1080/00958972.2012.690145Search in Google Scholar
[13] R. Kuroda, Inorg. Nucl. Chem. Lett.1973, 9, 13.10.1016/0020-1650(73)80078-9Search in Google Scholar
[14] T. Iwamoto, D. F. Shriver, Inorg. Chem.1972, 11, 2570.10.1021/ic50116a064Search in Google Scholar
[15] X.-Y. Tang, H. Yu, B.-B. Gao, J.-P. Lang, Dalton Trans.2017, 46, 14724.10.1039/C7DT02679JSearch in Google Scholar
[16] S. Chattopadhyay, K. Bhar, S. Das, S. Khan, P. Mitra, J. Ribas, B. K. Ghosh, Polyhedron2012, 39, 48.10.1016/j.poly.2012.03.031Search in Google Scholar
[17] I.-H. Park, J.-Y. Kim, K. Kim, S. S. Lee, Cryst. Growth Des.2014, 14, 6012.10.1021/cg501194nSearch in Google Scholar
[18] S.-L. Li, J.-Y. Wu, Y.-P. Tian, H. Ming, P. Wang, M.-H. Jiang, H.-K. Fun, Eur. J. Inorg. Chem.2006, 2006, 2900.10.1002/ejic.200500906Search in Google Scholar
[19] X.-Q. Wang, W.-T. Yu, X.-Q. Hou, D. Xu, Y.-L. Geng, Acta Crystallogr.2006, E62, m2333.Search in Google Scholar
[20] X. Q. Wang, W. T. Yu, D. Xu, G. H. Zhang, Acta Crystallogr.2005, E61, m1147.Search in Google Scholar
[21] X. Q. Wang, W. T. Yu, D. Xu, H. Q. Sun, Acta Crystallogr.2005, E61, m548.Search in Google Scholar
[22] T. S. Basu Baul, I. Longkumer, A. Linden, J. Organomet. Chem.2014, 761, 156.10.1016/j.jorganchem.2014.03.025Search in Google Scholar
[23] X. Liu, X. Wang, X. Yin, S. Zhang, L. Wang, L. Zhu, G. Zhang, D. Xu, J. Mater. Chem.2014, C2, 723.Search in Google Scholar
[24] X. Q. Wang, L. Y. Zhu, J. D. Fan, W. T. Yu, G. Yu, D. Xu, J. Chem. Crystallogr.2010, 40, 93.10.1007/s10870-009-9607-zSearch in Google Scholar
[25] D. Li, Q. Zhang, X. Wang, S. Li, H. Zhou, J. Wu, Y. Tian, Dyes Pigm.2015, 120, 175.10.1016/j.dyepig.2015.03.039Search in Google Scholar
[26] S. Kumar, R. P. Sharma, P. Venugopalan, T. Aree, Polyhedron2018, 139, 178.10.1016/j.poly.2017.09.053Search in Google Scholar
[27] M. Hakimi, Z. Mardani, K. Moeini, E. Schuh, F. Mohr, Z. Naturforsch.2013, 68b, 267.10.5560/znb.2013-2294Search in Google Scholar
[28] M. Hakimi, K. Moeini, Z. Mardani, F. Khorrami, J. Korean Chem. Soc.2013, 57, 352.10.5012/jkcs.2013.57.3.352Search in Google Scholar
[29] M. Hakimi, Z. Mardani, K. Moeini, F. Mohr, Polyhedron2015, 102, 569.10.1016/j.poly.2015.10.038Search in Google Scholar
[30] İ. Uçar, B. Karabulut, A. Bulut, O. Büyükgüngör, J. Phys. Chem. Solids2007, 68, 45.10.1016/j.jpcs.2006.09.008Search in Google Scholar
[31] I. Uçar, A. Bulut, Acta Crystallogr.2005, E61, m2730.Search in Google Scholar
[32] R. Azadbakht, H. Amiri Rudbari, G. Bruno, Acta Crystallogr.2011, E67, m1203.Search in Google Scholar
[33] A. Pajunen, E. Nasakkala, S. Pajunen, Cryst. Struct. Commun.1978, 7, 63.Search in Google Scholar
[34] R. V. Chastain, T. L. Dominick, Inorg. Chem.1973, 12, 2621.10.1021/ic50129a026Search in Google Scholar
[35] Y. Qu, Z.-L. You, Z.-D. Liu, H.-L. Zhu, M.-Y. Tan, Acta Crystallogr.2004, E60, m1187.Search in Google Scholar
[36] A. Pajunen, S. Pajunen, Contribution from Department of Chemistry, University of Helsinki, Finland presented at the Eur Cryst Meeting, Conference1998.Search in Google Scholar
[37] M. Hakimi, Z. Mardani, K. Moeini, N. Feizi, F. Mohr, J. Coord. Chem.2017, 70, 1247.10.1080/00958972.2017.1302581Search in Google Scholar
[38] M. Hakimi, Z. Mardani, K. Moeini, F. Mohr, E. Schuh, H. Vahedi, Z. Naturforsch.2012, 67b, 452.10.5560/znb.2012-0064Search in Google Scholar
[39] M. Hakimi, K. Moeini, Z. Mardani, F. Mohr, Polyhedron2014, 70, 92.10.1016/j.poly.2013.12.033Search in Google Scholar
[40] Z. Mardani, V. Golsanamlou, S. Khodavandegar, K. Moeini, A. M. Z. Slawin, J. D. Woollins, J. Coord. Chem.2018, 71, 120.10.1080/00958972.2018.1426852Search in Google Scholar
[41] Z. Mardani, V. Golsanamlou, S. Khodavandegar, K. Moeini, A. M. Z. Slawin, J. D. Woollins, Z. Naturforsch.2017, 72b, 335.10.1515/znb-2016-0222Search in Google Scholar
[42] G. Mahmoudi, A. Morsali, A. D. Hunter, M. Zeller, CrystEngComm2007, 9, 704.10.1039/b702569fSearch in Google Scholar
[43] F. Marandi, F. Amoopour, I. Pantenburg, G. Meyer, J. Mol. Struct.2010, 973, 124.10.1016/j.molstruc.2010.03.056Search in Google Scholar
[44] A. K. Abu Al-Nasr, R. M. Ramadan, Spectrochim. Acta2013, A105, 14.10.1016/j.saa.2012.12.008Search in Google Scholar PubMed
[45] G. Sheldrick, Acta Crystallogr.2015, A71, 3.Search in Google Scholar
[46] G. Sheldrick, Acta Crystallogr.2015, C71, 3.Search in Google Scholar
[47] CrystalStructure (version 4.2), Rigaku Americas, The Woodlands, Texas (USA), and Rigaku Corporation, Tokyo (Japan) 2015.Search in Google Scholar
[48] M. N. Burnett, C. K. Johnson, Ortep-III, Report ORNL-6895 Oak Ridge National Laboratory, Oak Ridge, Tennessee (USA) 1996.Search in Google Scholar
[49] L. J. Farrugia, J. Appl. Crystallogr.1997, 30, 565.10.1107/S0021889897003117Search in Google Scholar
[50] G. Bergerhof, M. Berndt, K. Brandenburg, J. Res. Natl. Stand. Technol.1996, 101, 221.10.6028/jres.101.023Search in Google Scholar PubMed PubMed Central
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