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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Synthese und Struktur des ersten Cyclophosphazens mit einer Metall—Metall-Bindung im Ringgerüst / Synthesis and Structure of the First Cyclophosphazene Containing a Metal —Metal Bond within the Ring Skeleton

  • Regine Herbst , Kattesh V. Katti , Herbert W . Roesky and George M. Sheldrick

The reaction of [H2NPPh2NPPh2NH2]Cl (1) with WClft (2) proceeds with formation of (3) and HCl5N6P4Ph8W2 (4). 3 is the main product of this reaction. 4 was characterized by an X-ray structure determination. 4 contains a seven and a six-membered phosphorus-nitrogen ring with a W-W bond of 269.2 pm.

Received: 1987-6-22
Revised: 1987-8-6
Published Online: 2014-6-2
Published in Print: 1987-11-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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