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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

1.2λ3.3λ3-Azadiphosphiridine − Synthese, Kristallstruktur und Eigenschaften / 1,2λ3,3λ3-Azadiphosphiridines − Synthesis, Crystal Structure and Proj)erties

  • Edgar Niecke , Anke Nickloweit-Lüke and Reinhold Rüger
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1981-1216
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Abstract

1,2λ3,3λ3-Azadiphosphiridines are available by elimination of hydrogenhalide from β-and γ-functional molecular frameworks and by 1+2 cycloaddition of phosphinidenes towards aminoiminophosphanes. In contrast to other three-membered phosphorus compounds, azadiphosphiridines decompose by 2+1 cycloreversion to aminoiminophosphanes and phosphinidenes. The molecular structure of an azadiphosphiridine demonstrates the trans arrangement of the exocyclic ligands and the planarity of the endocyclic nitrogen.

Keywords: Azadiphosphiridines; Cyclisation; Thermal Decomposition; NMR Spectra; Crystal Structure
Received: 1981-7-13
Published Online: 2014-6-2
Published in Print: 1981-12-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 36 Issue 12

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Authors Index / Autorenverzeichnis
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