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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Zur Reaktion von Trimethylsilyl-difluorophosphat, Trimethylsilyl-dimethylphosphinat und Difluorophosphorsäureanhydrid mit TiCl4 bzw. SbCl5 / On the Reactions of Trimethylsilyl Difluorophosphate, Trimethylsilyl Dimethylphosphinate and Difluorophosphoric Acid Anhydride with TiCl4 and SbCl5, respectively

  • Abdel-Fattah Shihada and Abdulalah T. Mohammed
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1980-0114
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Abstract

TiCl4 reacts with trimethylsilyl difluorophosphate (Me3SiPO2F2) and with trimethylsilyl dimethylphosphinate (Me3SiPO2Me2) at room temperature under cleavage of the Si-O bond to give the principal products Cl2Ti(PO2F2)2 and Cl2Ti(PO2Me2)2, respectively. The former product has also been obtained from the reaction of P2O3F4 with TiCl4-SbCl5 is capable of cleaving the P-O bond in P2O3F4 to give Cl4SbPO2F2, but forms addition compounds with Me3SiPO2F2 and Me3SiPO2Me2 in which the terminal oxygen atoms of the esters are bound to antimony. IR spectra have been used to elucidate the structures of the prepared compounds.

: Cleavage Reactions; Preparations IR Spectra
Received: 1979-9-6
Published Online: 2014-6-2
Published in Print: 1980-1-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 35 Issue 1

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Articles in the same Issue

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Contents
Zur Darstellung und Struktur von CaMnBi2 / On the Preparation and Crystal Structure of CaMnBi2
Oxotitanate mit gemischter Valenz, II Zur Kenntnis von Sr2Ti6O13 / Oxotitanates with Mixed Valence, II About Sr2Ti6O13
Darstellung und Kristallstruktur von Barium-Quecksilber-Thiostannat(IV), BaHgSnS4 / Preparation and Crystal Structure of Barium-Mercury-Thiostannate(IV), BaHgSnS4
Darstellung, Struktur und Eigenschaften einer neuen Modifikation von NbI5 / Preparation, Structure and Properties of a New Modification of NbI5
Reaktionen von SbCl5 mit Acetoaeetanilid / Reactions of SbCl5 with Acetoacetanilide
Cyclische Diazastannylene, VIII [1]. Die Kristall- und Molekülstruktur eines Iminostannylens: Sn3(NC(CH3 )3)4H2 / Cyclic Diazastannylenes, VIII [1]. The Crystal and Molecular Structure of an Iminostannylene: Sn3(NC(CH3 )3)4H2
The Topochemical Reaction of CaSi2 to a Two-Dimensional Subsiliceous Acid Si6H3(OH)3 ( = Kautskys’ Siloxene)
Siliciumverbindungen mit starken intramolekularen sterischen Wechselwirkungen, IX [1]. tert-Butylsubstituierte Di- und Trisiloxane / Silicon Compounds with Strong Intramolecular Steric Interactions, IX [1]. tert-Butyl Substituted Di- and Trisiloxane s
29Si-Kernresonanzuntersuchiingeii an Polysilanen 1. Perchlorpolysilane / 29Si NMR Investigations on Polysilanes 1. Perchloropolysilanes
Di-μ-iodo-bis [dicarbonyl(di-tert-butylphosphin)ruthenium(I)] (Ru-Ru) und Bis(tri-tert-butylphosphonium)-di-μ-iodo-bis[carbonyl-diiodo- (di-tert-butylphosphin)ruthenium(II)] / Di-μ-iodo-bis[dicarbonyl(di-tert–butylphosphine)ruthenium(I)](Ru-Ru) and Bis(tri-tert–butylphosphonium)di-μ-iodo-bis[carbonyl-diiodo- (di–tert-butylphosphine)ruthenium(II)]
Die Isopolymolybdationen in wäßrigen Medien im Bereich Z ≦ 1,14 / Concerning Isopolymolybdate Ions in Aqueous Media in the Range Z ≦ 1.14
Die Spaltung von Tetrahydrofuran mit Trimethylchlorsilan und Dialkylantimoniodid / Cleavage of Tetrahydrofurane by Trimethylchlorosilane and Dialkylantimonyiodide
Zur Reaktion von Trimethylsilyl-difluorophosphat, Trimethylsilyl-dimethylphosphinat und Difluorophosphorsäureanhydrid mit TiCl4 bzw. SbCl5 / On the Reactions of Trimethylsilyl Difluorophosphate, Trimethylsilyl Dimethylphosphinate and Difluorophosphoric Acid Anhydride with TiCl4 and SbCl5, respectively
Chemie polyfunktioneller Liganden, 56 [1]. Darstellung von N-Deutero-bis(diphenylphosphino)amin, sowie schwingungsspektroskopischer Vergleich mit Bis(diphenylphosphino)amin und Lithium-bis(diphenylphosphino)amid / Chemistry of Polyfunctional Ligands, 56 [1]. Preparation of N-Deutero-bis(diphenylphosphino)amine, as well as the Vibrational Spectroscopic Comparison with Bis(diphenylphosphino)amine and Lithium-bis(diphenylphosphino)amid
Kupfer(II)-Komplexe mit dia- und paramagnetischen Carboxylatliganden / Copper(II) Complexes with Dia- and Paramagnetic Carboxylate Ligands
Darstellung und Eigenschaften von trans-Dihalogeno-tetrakis(pyridin)osmium(II)-Komplexen / Preparation and Properties of trans-Dihalo-tetrakis(pyridine)osmium(II) Complexes
Reaktionen koordinierter Liganden, VI [1] Substituenteneinflüsse bei der Bildung von Tri- und Tetraphosphinen in der Koordinationssphäre von Übergangsmetallen / Reactions of Coordinated Ligands, VI [1]. Influence of Substituents on the Formation of Tri- and Tetraphosphines in the Coordination Sphere of Transition Metals
Übergangsmetall-Carbin-Komplexe, LVI [1]. Umsetzung eines kationischen Carbin-Komplexes mit einem Carbonylmetallat. Der Phenylketenyl-Rest als Briickenhgand / Transition Metal Carbyne Complexes, LVI [1]. Reaction of a Cationic Carbyne Complex with a Carbonylmetalate. The Phenylketenyl Group as a Bridging Ligand
Reaktionen von Dicarbonyl (η-cyclopentadienyl)(propiolsäuremethylester)niangan(I) mit Basen. Isolierung von Vinyliden- und Carbenkomplexen / Reactions of Dicarbonyl(η-cyclopentadienyl)(methylpropiolate)manganese(I) with Bases The Isolation of Vinylidene and Carbene Complexes
Reactions with the Arylhydrazones of some α-Cyanoketones
Studies on Betaine Decomposition of Arsonium Ylides
Transylidation Reactions in Arsonium Ylides
Hydroxylation of ⊿5-Steroids with N-Bromosuccinimide to 5α,6β-Diols
Fluorescein-photosensitized Furan Oxidation in Methanolic and Reversed Micellar Solutions, Part II Kinetic Analysis
Some New One-dimensional Compounds: Preparation and Optical Properties
KHgAs (Sb) und KZnAs - Ternäre Verbindungen mit modifizierter Ni2In-Struktur/ KHgAs (Sb) and KZnAs - Ternary Compounds in a Modified Ni2In-Structure
Tetrachloroaluminate, -ferrate und -gallate: AIMIIICl4 (AI = Li-Cs, NH4, Tl, In; MiIII = Al, Fe, Ga) / Tetrachloroaluminates, -ferrates and -gallates: AIMIIICl4 (AI = Li-Cs, NH4, Tl, In; MIII = Al, Fe, Ga)
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